Network of semiconductor structures with fused insulator coating
View Patent ↗Networks of semiconductor structures with fused insulator coatings and methods of fabricating networks of semiconductor structures with fused insulator coatings are described. In an example, a method of fabricating a semiconductor structure involves forming a mixture including a plurality of discrete semiconductor nanocrystals. Each of the plurality of discrete semiconductor nanocrystals is discretely coated by an insulator shell. The method also involves adding a base to the mixture to fuse the insulator shells of each of the plurality of discrete nanocrystals, providing an insulator network. Each of the plurality of discrete semiconductor nanocrystals is spaced apart from one another by the insulator network. The base one such as, but not limited to, LiOH, RbOH, CsOH, MgOH, Ca(OH) 2 , Sr(OH) 2 , Ba(OH) 2 , (Me) 4 NOH, (Et) 4 NOH, or (Bu) 4 NOH.
1. A method of fabricating a semiconductor structure, the method comprising:
forming a mixture comprising a plurality of discrete semiconductor nanocrystals, each of the plurality of discrete semiconductor nanocrystals discretely coated by an insulator shell; and
adding a base to the mixture to fuse the insulator shells of each of the plurality of discrete nanocrystals, providing an insulator network, wherein each of the plurality of discrete semiconductor nanocrystals is spaced apart from one another by the insulator network, and wherein the base is selected from the group consisting of LiOH, RbOH, CsOH, MgOH, Ca(OH) 2 , Sr(OH) 2 , Ba(OH) 2 , (Me) 4 NOH, (Et) 4 NOH, and (Bu) 4 NOH.
2. The method of claim 1 , wherein the base is selected from the group consisting of LiOH, RbOH, CsOH, MgOH, (Me) 4 NOH, (Et) 4 NOH, and (Bu) 4 NOH, and adding the base to the mixture comprises adding one mole of the base for every two moles of material of the insulator shells.
3. The method of claim 1 , wherein the base is selected from the group consisting of Ca(OH) 2 , Sr(OH) 2 and Ba(OH) 2 , and adding the base to the mixture comprises adding one mole of the base for every four moles of material of the insulator shells.
4. The method of claim 1 , further comprising:
adding free silica to the mixture.
5. The method of claim 4 , wherein adding free silica to the mixture comprises adding the free silica after adding the base to the mixture.
6. The method of claim 4 , wherein adding free silica to the mixture comprises adding the free silica prior to adding the base to the mixture.
7. The method of claim 1 , wherein forming the mixture comprises using tetraethylorthosilicate to form the insulator shell for each of the discrete semiconductor nanocrystals discretely coated by the insulator shell.
8. The method of claim 1 , wherein the insulator shells of each of the plurality of discrete nanocrystals and the resulting insulator network comprise silica.