IP Library Granted Patent US 9,568,375
Granted Patent B2
US 9,568,375 · App. 14/105,323 · Granted Feb 14, 2017

Method and apparatus for estimating fouling factor and/or inverse soluble scale thickness in heat transfer equipment

Inventors: Terry Lynn Bliss (Wilmington, DE); Timothy Frederick Patterson (Wilmington, DE)
Assignee: Solenis Technologies, L.P.
G01K1/16F28G15/003G01N17/008G01N25/18
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Quick Facts
Patent No.
US 9,568,375
App. No.
14/105,323
Granted
Feb 14, 2017
Kind
B2
Abstract

Scale deposition on a heat transfer surface in a liquid system such as a heat exchanger is estimated by directing of small portion of the liquid flow through a test cell, consisting of a sensor positioned on and projecting through a conduit wall. The sensor consists of a conductive block containing a heater and having a heated wetted test surface that is flush with the inside of the conduit wall and in contact with the flow through the conduit. Within the conductive block are two temperature sensors which are at different distances from the heated wetted test surface and the heater. The periphery of the apparatus is designed to reduce heat flow through the periphery and allow greater heat flow through the heated wetted test surface. By comparing the temperature differential between the two temperature sensors to the differential when no scale is present, the presence of and amount of scale can be determined, based on reduced heat transfer through the heated wetted surface caused by the accumulated scale. The change in the temperature differential is directly proportional to the scale thickness for a given type of scale. When the thickness of the scale is determined by another means, the nature of the scale can be implied. The sensitivity of the measurement can be adjusted to accommodate a very wide range of bulk liquid or ambient temperature via adjustment of the heat flux through the provided secondary heat flux path.

Claims (41)

1. A method of detecting fouling or scaling of a heated wetted test surface comprising heating a conductive block using a heater;

said conductive block having a first end comprising said heated wetted test surface, and a second end opposite said first end;

contacting said heated wetted test surface with a first liquid;

measuring the temperatures at first and second positions along said conductive block wherein said first position is closer to said heated wetted test surface than said second position to obtain first and second temperature measurements;

comparing first and second temperature measurements at said first and second positions to establish a reference temperature difference with no fouling or scaling on said heated wetted test surface;

determining fouling or scaling on said surface by subsequently measuring temperatures at said first and second positions and detecting changes in temperature differences between said temperatures at said first and second positions relative to said reference temperature difference.

2. The method claimed in claim 1 wherein said first and second positions are between said heater and said heated wetted test surface.

3. The method claimed in claim 1 , wherein said first and second positions arc between said heater and said second end opposite said first end.

4. The method claimed in claim 1 , further comprising providing a first material around a peripheral surface of said conductor and providing a second material at said second end wherein said first and second materials have different heat conduction coefficients.

5. The method claimed in claim 1 , wherein a flow rate of scale control chemicals is adjusted in response to changes in heat conductivity of accumulating scale on said heated wetted test surface.

6. The method claimed in claim 1 , further comprising measuring the thickness of deposits on said wetted surface.

7. The method claimed in claim 6 , wherein said thickness is measured using sound waves.

8. The method claimed in claim 1 , further comprising providing insulation around a peripheral surface of said conductive block whereby heat resistance is greater radially outward from said conductor than from said conductive block than through said second end.

9. The method claimed in claim 8 , further comprising adjusting a temperature of said exterior surfaces utilizing a heat exchange fluid surrounding said exterior surfaces.

10. The method claimed in claim 9 , further comprising controlling the temperature of said exterior surfaces by adjusting the flow or temperature of said heat exchange fluid.

11. The method claimed in claim 10 , wherein said heat exchange fluid is the same as said first liquid.

12. The method claimed in claim 1 , further comprising at least partially surrounding said first and second materials with a heat sink.

13. The method claimed in claim 12 , further comprising projecting a heat exchange fluid over said heat sink to control the temperature of said exterior surfaces.

14. The method claimed in claim 13 , further comprising controlling said heat exchange fluid to establish a desired temperature of said exterior surface.

15. The method claimed in claim 13 , wherein said heat exchange fluid comprises at least one of air and a water mist.

16. An apparatus to detect fouling or scale on a heated wetted test surface wherein said heated wetted test surface is in a liquid flow path in contact with a bulk liquid comprising;

a heater;

a conductive block having a first end comprising said heated wetted test surface and a second end opposite said first end and a peripheral surface;

a first temperature sensor within said conductive block at a first position close to said heated wetted test surface;

a second temperature sensor within said conductive block at a second position close to said heater and further from said heated wetted test surface than said first temperature sensor;

wherein said second end has a higher heat conductivity than said peripheral surface.

17. The apparatus claimed in claim 16 , wherein said first and second positions are offset sufficiently to avoid interference with heat flux.

18. The apparatus claimed in claim 16 , wherein said apparatus further includes a device operable to measure scale thickness on said heated wetted test surface by directing wave energy against said wetted surface.

19. The apparatus claimed in claim 16 , wherein said apparatus is at least partially surrounded by heat exchange fluid.

20. The apparatus claimed in claim 16 , further comprising a second heater at said second end.

21. The apparatus claimed in claim 16 , further comprising a third heater in contact with at least a portion of said peripheral surface.

22. The apparatus claimed in claim 16 , wherein at least one of said peripheral surface and said second end includes insulation.

23. The apparatus claimed in claim 22 , wherein said peripheral surface is at least partially surrounded by a heat sink.

24. The apparatus claimed in claim 16 , wherein said conductive block comprises a first material and has a thin layer of a second material bonded to said first end wherein said layer of second material comprises said heated wetted test surface.

25. The apparatus claimed in claim 24 , wherein said second material comprises a corrosion resistant material.

26. The apparatus claimed in claim 16 , wherein said conductive block is a layer of a third material at said second end wherein said third material has a different thermal conductivity than a thermal conductivity of said first mate.

27. An apparatus to detect fouling or scale on a heated welted test surface wherein said heated wetted test surface is in a fluid flow path comprising;

a heater;

a conductive block having a first end comprising said heated wetted test surface and a second end opposite said first end and a peripheral surface;

a first temperature sensor within said conductive block close to said heater and between said heater and said second end;

a second temperature sensor within said conductive block at a second position between said heater and said second end and close to said second end but further from said heater than said first temperature sensor.

Assignments (19)
SECURITY INTEREST Recorded Nov 14, 2025
From: CHEM-AQUA, INC.; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; NCH CORPORATION; NCH LIFE SCIENCES LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073570/0838 →
RELEASE OF SECURITY INTEREST Recorded Nov 14, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073564/0864 →
SECURITY AGREEMENT (NOTES) Recorded Oct 10, 2025
From: DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073061/0885 →
RELEASE OF 2023 NOTES PATENT SECURITY INTERESTS Recorded Oct 10, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073074/0198 →
SECURITY AGREEMENT (2024 NOTES) Recorded Jun 24, 2024
From: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 067824/0278 →
2023 NOTES PATENT SECURITY AGREEMENT Recorded Jul 7, 2023
From: BIRKO CORPORATION; SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE GLOBAL CORPORATION
To: BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 064225/0170 →
SECURITY AGREEMENT (NOTES) Recorded Sep 14, 2022
From: SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A. AS COLLATERAL AGENT
Reel/Frame 061432/0821 →
TERM LOAN PATENT SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: GOLDMAN SACHS BANK USA
Reel/Frame 058102/0407 →
NOTES SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 058103/0066 →
RELEASE OF SECURITY INTEREST Recorded Nov 10, 2021
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 058856/0724 →
RELEASE OF SECURITY INTEREST Recorded Nov 10, 2021
From: CITIBANK, N.A.
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 058848/0636 →
ABL PATENT SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: BANK OF AMERICA, N.A.
Reel/Frame 058102/0122 →
FIRST LIEN NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Jul 20, 2018
From: SOLENIS TECHNOLOGIES, L.P.
To: CITIBANK, N.A., COLLATERAL AGENT
Reel/Frame 046595/0241 →
INTELLECTUAL PROPERTY FIRST LIEN SECURITY AGREEMENT RELEASE Recorded Jul 20, 2018
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 046594/0252 →
INTELLECTUAL PROPERTY SECOND LIEN SECURITY AGREEMENT RELEASE Recorded Jul 20, 2018
From: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 047058/0800 →
SECOND LIEN NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Jul 20, 2018
From: SOLENIS TECHNOLOGIES, L.P.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 046629/0213 →
NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS (SECOND LIEN) Recorded Aug 14, 2014
From: SOLENIS TECHNOLOGIES, L.P.
To: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
Reel/Frame 033535/0847 →
NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS (FIRST LIEN) Recorded Aug 14, 2014
From: SOLENIS TECHNOLOGIES, L.P.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 033535/0806 →
U.S. ASSIGNMENT OF PATENTS Recorded Aug 4, 2014
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 033471/0048 →
Continuity (2)
Provisional Application 61739785 · Dec 20, 2012
Related Publication 20140177673A1 · Jun 26, 2014