Manganese-containing diesel oxidation catalyst
An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a first washcoat layer comprising a Pt component and a Pd component, and a second washcoat layer including a refractory metal oxide support containing manganese, a zeolite, and a platinum component is described.
1. An oxidation catalyst composite for abatement of exhaust gas emissions from a lean burn engine comprising:
a carrier substrate having a length, an inlet end, and an outlet end, an oxidation catalyst catalytic material on the carrier, the oxidation catalyst catalytic material including a first washcoat layer comprising a first refractory metal oxide support, a platinum (Pt) component and a palladium (Pd) component in a ratio of Pt to Pd in the range of about 10:1 to 1:10; and
a second washcoat layer comprising a second refractory metal oxide support containing Mn, a zeolite, a Pt component, and optionally a Pd component,
wherein the Mn content of the second refractory metal oxide support is in the range of 0.1% to 30% by weight, and wherein the Mn is doped with Fe, Ni, Co, Cu, Ce, Sn, Ir, In, or a combination thereof, and
wherein the oxidation catalyst composite is effective to abate hydrocarbon and carbon monoxide, and to oxidize NO to NO 2 in a lean burn engine exhaust.
2. The oxidation catalyst composite of claim 1 , wherein the second washcoat layer further comprises a palladium component, and the Pt:Pd ratio of the second washcoat layer is in the range of 1:0 to 10:1.
3. The oxidation catalyst composite of claim 1 , wherein the second washcoat layer is substantially free of palladium.
4. The oxidation catalyst composite of claim 2 , wherein the second washcoat layer palladium component is present in an amount in the range of about 0.1 g/ft 3 to about 10 g/ft 3 .
5. The oxidation catalyst composite of claim 1 , wherein the first washcoat layer is coated on the carrier substrate, and the second washcoat layer is coated on top of the first washcoat layer.
6. The oxidation catalyst composite of claim 1 , wherein the Mn content is in the range of 3 to 10% by weight.
7. The oxidation catalyst composite of claim 1 , wherein the Mn is present in a form selected from the group consisting of a Mn-containing solid solution with the refractory metal oxide support, Mn surface dispersed on the refractory metal oxide support by impregnation and discrete manganese oxide particles on the refractory metal oxide support particles.
8. The oxidation catalyst of claim 1 , wherein the Mn is derived from a soluble Mn species or from bulk Mn oxides.
9. The oxidation catalyst composite of claim 8 , wherein the soluble Mn species is selected from the group consisting of Mn acetate, Mn nitrate, Mn sulfate, and combinations thereof.
10. The oxidation catalyst composite of claim 8 , wherein the bulk Mn oxides are selected from MnO, Mn 2 O 3 , MnO 2 , and combinations thereof.
11. The oxidation catalyst composite of claim 1 , wherein the second refractory metal oxide support comprises alumina, silica, zirconia, titania, ceria, or a combination thereof.
12. The oxidation catalyst composite of claim 1 , wherein the second washcoat layer comprises a Pt component in an amount in the range of about 10 g/ft 3 to 100 g/ft 3 .
13. The oxidation catalyst composite of claim 12 , wherein the second washcoat layer further comprises a Pd component in an amount in the range of about 0.1 g/ft 3 to 10 g/ft 3 .
14. The oxidation catalyst composite of claim 12 , wherein the second washcoat layer comprises a hydrothermally stable zeolite in the form of 6 to 12 member ring structures, selected from ZSM-5, beta, mordenite, Y zeolite, chabazite, ferrierite, or combinations thereof.
15. The oxidation catalyst composite of claim 1 , wherein the first refractory metal oxide support comprises alumina, silica, zirconia, titania, ceria, or a combination thereof.
16. The oxidation catalyst composite of claim 1 , wherein the first washcoat layer comprises a Pt component in an amount in the range of about 10 g/ft 3 to 100 g/ft 3 .
17. The oxidation catalyst composite of claim 16 , wherein the first washcoat layer comprises a Pd component in an amount in the range of about 10 g/ft 3 to 100 g/ft 3 .
18. The oxidation catalyst composite of claim 1 , wherein the second washcoat layer is substantially free of barium and the first washcoat layer is substantially free of zeolite.
19. The oxidation catalyst composite of claim 1 , wherein the second washcoat layer is coated on the carrier substrate, and the first washcoat layer is coated on top of the second washcoat layer.
20. The oxidation catalyst composite of claim 1 , wherein the carrier substrate comprises a flow-through monolith.
21. The oxidation catalyst composite of claim 1 , wherein the first washcoat layer and the second washcoat layer are both coated on the carrier.
22. The oxidation catalyst composite of claim 1 , wherein the first washcoat layer comprises alumina and the second washcoat layer comprises alumina containing Mn in an amount of about 3% to 10% by weight, and wherein the Pt component of the second washcoat layer is present in an amount in the range of about 10 g/ft 3 to 100 g/ft 3 and the second washcoat layer is substantially free of palladium.
23. A method for treating a diesel engine exhaust gas stream, the method comprising contacting an exhaust gas stream with the oxidation catalyst composite of claim 1 .
24. The method of claim 23 , further comprising passing the exhaust gas stream to an SCR catalyst composition immediately downstream from the oxidation catalyst composite.
25. The method of claim 24 , wherein the SCR catalyst composition is disposed on a wall flow filter monolith.
26. A system for treatment of a lean burn engine exhaust gas stream including hydrocarbons, carbon monoxide, and other exhaust components, the system comprising:
an exhaust conduit in fluid communication with the lean burn engine via an exhaust manifold;
the oxidation catalyst composite of claim 1 , wherein the carrier substrate is a flow through substrate; and
a catalyzed soot filter and an SCR catalyst located downstream from the oxidation catalyst composite.
27. The system of claim 26 , wherein the oxidation catalyst composite is added to a lean NO x trap.
28. The system of claim 27 , wherein the lean NO x trap comprises a barium component and a rhodium component.
29. The system of claim 26 , wherein the SCR catalyst is coated onto the catalyzed soot filter.
30. The system of claim 26 , wherein the SCR catalyst is on a flow through substrate immediately downstream from the oxidation catalyst and the catalyzed soot filter is downstream from the SCR catalyst.