Battery having electrode structure including metal fiber and preparation method of electrode structure
The present invention relates to a battery having an electrode structure using metal fiber and a preparation method of an electrode structure. A preparation method of an electrode structure, according to one embodiment of the present invention, includes a step for providing one or more metal fibers forming a conductive network; a step for providing particle compositions including electrical active materials of a particle shape; a step for mixing the metal fibers and the particle compositions; and a step for compressing the mixed metal fibers and the particle compositions.
1. A battery including an electrode, the battery comprising:
a conductive network that is formed by using one or more metal fibers;
a pre-coated layer on surfaces of some or all of the surfaces of some or all of the one or more metal fibers; and
a particle composition comprising a first electrically active material that is provided as particles which are bound to the conductive network and a plurality of binder particles by using a dry mixing process so as to form the particle composition as non-solvent dry powder,
wherein the binder particles are provided as point binders between the one or more metal fibers and the first electrically active material particles, and between the first electrically active material particles by applying heat energy or ultraviolet rays,
wherein the pre-coated layer comprises a second electrically active material provided as particles and having chemical affinity for forming a chemical compound with the first electrically active material, and the second electrically active material is different from the first electrically active material, and
wherein the one or more metal fibers are randomly arranged to be tangled to each other to form pores in the conductive network and the first electrically active material particles are impregnated into the pores, and the first electrically active material particles bound to the conductive network are electrically contracted with the conductive network via the second electrically active material particles.
2. The battery of claim 1 , wherein the one or more metal fibers are bonded to one another by randomly only physically contacting one another, and the conductive network has a nonwoven structure.
3. The battery of claim 1 , wherein the particle composition further comprises any one or all of a conductor, and porous ceramic particles.
4. The battery of claim 1 , wherein each of the one or more metal fibers has a thickness ranging from 1 μm to 200 μm.
5. The battery of claim 1 , wherein each of the one or more metal fibers has a thickness ranging from 2 μm to 20 μm.
6. The battery of claim 1 , wherein the one or more metal fibers comprise any one of stainless steel, aluminum, nickel, titanium, copper, an alloy thereof, or a combination thereof.
7. The battery of claim 1 , wherein a ratio of an average size of the first and second electrically active material particles to an average thickness of the one or more metal fibers ranges from 0.01 to 10.
8. A battery including an electrode, the battery comprising:
a conductive network that is formed by using one or more metal fibers; the conductive network has a nonwoven structure;
a pre-coated layer on surfaces of some or all of the surfaces of some or all of the one or more metal fibers; and
a particle composition comprising a first electrically active material that is provided as particles which are bound to the conductive network and a plurality of binder particles by using a dry mixing process so as to form the particle composition as non-solvent dry powder,
wherein the binder particles are provided as point binders between the one or more metal fibers and the first electrically active material particles, and between the first electrically active material particles by applying heat energy or ultraviolet rays,
wherein the pre-coated layer comprises a second electrically active material provided as particles and having chemical affinity for forming a chemical compound with the first electrically active material, and the second electrically active material is different from the first electrically active material, and
wherein the one or more metal fibers are randomly arranged to be tangled to each other to form pores in the conductive network and the first electrically active material particles are impregnated into the pores, and the first electrically active material particles bound to the conductive network are electrically contracted with the conductive network via the second electrically active material particles.
9. The battery of claim 8 , wherein the particle composition further comprises any one or all of a conductor, and porous ceramic particles.
10. The battery of claim 8 , wherein each of the one or more metal fibers has a thickness ranging from 1 μm to 200 μm.
11. The battery of claim 8 , wherein each of the one or more metal fibers has a thickness ranging from 2 μm to 20 μm.
12. The battery of claim 8 , wherein the one or more metal fibers comprise any one of stainless steel, aluminum, nickel, titanium, copper, an alloy thereof, or a combination thereof.
13. The battery of claim 8 , wherein a ratio of an average size of the first electrically active material particles to an average thickness of the one or more metal fibers ranges from 0.01 to 10.
14. The battery of claim 1 , wherein the first electrically active material and the second electrically active material comprise an electrically active material for a cathode, and the electrically active material for a cathode is selected from the group consisting of oxide, phosphate, sulfide, and fluoride, each of which includes two or more components selected from lithium, nickel, cobalt, chromium, magnesium, strontium, vanadium, lanthanum, cerium, iron, cadmium, lead, and/or manganese, and a combination thereof.
15. The battery of claim 1 , wherein the point binders make point contacts with the one or more metal fibers or the first electrically active material particles, and wherein the first electrically active material is bound to some of all of the one or more metal fibers by forming a sintered body through thermal treatment between the first electrically active material and the second electrically active material having chemical affinity with the first electrically active material.
16. The battery of claim 8 , wherein the point binders make point contacts with the one or more metal fibers or the first electrically active material particles, and wherein the first electrically active material is bound to some of all of the one or more metal fibers by forming a sintered body through thermal treatment between the first electrically active material and the second electrically active material having chemical affinity with the first electrically active material.