IP Library Granted Patent US 9,453,269
Granted Patent B2
US 9,453,269 · App. 14/110,551 · Granted Sep 27, 2016

Hot-rolled steel sheet for gas nitrocarburizing and manufacturing method thereof

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,453,269
App. No.
14/110,551
Granted
Sep 27, 2016
Kind
B2
Abstract

In a hot-rolled steel sheet, an average pole density of an orientation group of {100}<011> to {223}<110>, which is represented by an arithmetic average of pole density of each orientation of {100}<011>, {116}<110>, {114}<110>, {112}<110>, and {223}<110> in a center portion of a sheet thickness which is a range of the sheet thickness of ⅝ to ⅜ from a surface of the steel sheet, is 1.0 or more and 4.0 or less, the pole density of a crystal orientation of {332}<113> is 1.0 or more and 4.8 or less, an average grain size in a center in the sheet thickness is 10 μm or less, and a microstructure includes, by a structural fraction, pearlite more than 6% and ferrite in the balance.

Claims (57)

1. A manufacturing method of a hot-rolled steel sheet for gas nitrocarburizing, the method comprising:

performing a first hot rolling, which includes one or more of rolling reduction having a rolling-reduction ratio of 40% or more at a temperature range of 1000° C. or more and 1200° C. or less, with respect to a steel ingot or a slab which includes, by mass %,

C content [C]: C of more than 0.07% and equal to or less than 0.2%,

Si content [Si]: Si of 0.001% or more and 2.5% or less,

Mn content [Mn]: Mn of 0.01% or more and 4% or less, and

Al content [Al]: Al of 0.001% or more and 2% or less, and

P content [P] limited to 0.15% or less,

S content [S] limited to 0.03% or less, and

N content [N] limited to 0.01% or less,

Ti content [Ti] contains Ti which satisfies the following Equation 1, and

the balance consists of Fe and unavoidable impurities;

starting a second hot rolling at a temperature range of 1000° C. or more within 150 seconds after a completion of the first hot rolling;

wherein the second rolling includes one or more of rolling reduction having a rolling-reduction ratio of 30% or more in a temperature range of T1+30° C. or more and T1+200° C. or less when temperature determined by a component of the steel sheet in the following Equation 2 is defined as T1° C. in the second hot rolling and a total of the rolling-reduction ratio is 50% or more;

performing a third hot rolling, in which a total of the rolling-reduction ratio is 30% or less, at a temperature range equal to or more than an Ar3 transformation point temperature and less than T1+30° C.;

ending the hot rollings at the Ar3 transformation point temperature or more;

when a pass having rolling-reduction ratio of 30% or more at the temperature range of T1+30° C. or more and T1+200° C. or less is a large rolling-reduction pass, performing a cooling, in which a cooling temperature change is 40° C. or more and 140° C. or less and a cooling end temperature is T1+100° C. or less, at a cooling rate of 50° C./second or more so that a waiting time t second from a completion of a final pass of the large rolling-reduction passes to a start of the cooling satisfies the following Equation 3; and

coiling the steel sheet at more than 550° C.;

0.005+[N]×48/14+[S]×48/32≦Ti≦0.015+[N]×48/14+[S]×48/32   (Equation 1)

T 1=850+10×([C]+[N])×[Mn]+350×[Nb]+250×[Ti]+40×[B]+10×[Cr]+100×[Mo]+100×[V]  (Equation 2)

t≦ 2.5× t 1  (Equation 3)

wherein, t1 is represented by the following Equation (Equation 4),

t 1=0.001×(( Tf−T 1)× P 1/100) 2 −0.109×(( Tf−T 1)× P 1/100)+3.1  (Equation 4)

wherein, Tf is a temperature in ° C. after the final pass rolling reduction of the large rolling-reduction passes and P1 is a rolling-reduction ratio in % of the final pass of the large rolling-reduction passes.

2. The manufacturing method of a hot-rolled steel sheet for gas nitrocarburizing according to claim 1 ,

wherein the cooling performs cooling between rolling stands.

3. The manufacturing method of a hot-rolled steel sheet for gas nitrocarburizing according to claims 1 or 2 ,

wherein the waiting time t second further satisfies the following Equation 5;

t 1≦ t≦ 2.5× t 1  (Equation 5).

4. The manufacturing method of a hot-rolled steel sheet for gas nitrocarburizing according to claims 1 or 2 ,

wherein the waiting time t second further satisfies the following Equation 6;

t≦t 1  (Equation 6).

5. The manufacturing method of a hot-rolled steel sheet for gas nitrocarburizing according to any one of claims 1 or 2 ,

wherein a temperature increase between respective passes in the second hot rolling is 18° C. or less.

6. The manufacturing method of a hot-rolled steel sheet for gas nitrocarburizing according to claim 5 ,

wherein the slab or the steel ingot further comprises any one or two or more of, by mass %,

Nb content [Nb]: Nb of 0.005% or more and 0.06% or less,

Cu content [Cu]: Cu of 0.02% or more and 1.2% or less,

Ni content [Ni]: Ni of 0.01% or more and 0.6% or less,

Mo content [Mo]: Mo of 0.01% or more and 1% or less,

V content [V]: V of 0.01% or more and 0.2% or less,

Cr content [Cr]: Cr of 0.01% or more and 2% or less,

Mg content [Mg]: Mg of 0.0005% or more and 0.01% or less,

Ca content [Ca]: Ca of 0.0005% or more and 0.01% or less,

REM content [REM]: REM of 0.0005% or more and 0.1% or less, and

B content [B]: B of 0.0002% or more and 0.002% or less.

7. The manufacturing method of a hot-rolled steel sheet for gas nitrocarburizing according to any one of claims 1 or 2 ,

wherein the slab or the steel ingot further includes any one kind or two or more kinds of, by mass %,

Nb content [Nb]: Nb of 0.005% or more and 0.06% or less,

Cu content [Cu]: Cu of 0.02% or more and 1.2% or less,

Ni content [Ni]: Ni of 0.01% or more and 0.6% or less,

Mo content [Mo]: Mo of 0.01% or more and 1% or less,

V content [V]: V of 0.01% or more and 0.2% or less,

Cr content [Cr]: Cr of 0.01% or more and 2% or less,

Mg content [Mg]: Mg of 0.0005% or more and 0.01% or less,

Ca content [Ca]: Ca of 0.0005% or more and 0.01% or less,

REM content [REM]: REM of 0.0005% or more and 0.1% or less, and

B content [B]: B of 0.0002% or more and 0.002% or less.

Assignments (2)
CHANGE OF NAME Recorded May 14, 2019
From: NIPPON STEEL & SUMITOMO METAL CORPORATION
To: NIPPON STEEL CORPORATION
Reel/Frame 049257/0828 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 8, 2013
From: YOKOI, TATSUO; SHUTO, HIROSHI; OKAMOTO, RIKI; FUJITA, NOBUHIRO; NAKANO, KAZUAKI; YAMAMOTO, TAKESHI
To: NIPPON STEEL & SUMITOMO METAL CORPORATION
Reel/Frame 031364/0882 →