Water-absorbing polymer having a high absorption rate
View Patent ↗A process for producing a water-absorbing polymer composition, comprising the process steps of (i) mixing (α1) 0.1 to 99.999% by weight of ethylenically unsaturated monomers containing acid groups or salts thereof (α2) 0 to 70% by weight of polymerized, ethylenically unsaturated monomers copolymerizable with (α1), (α3) 0.001 to 10% by weight of one or more crosslinkers, (α4) 0 to 30% by weight of water-soluble polymers, and (α5) 0 to 20% by weight of one or more assistants, where the sum of their weights (α1) to (α5) is 100% by weight, (ii) free-radical polymerization with crosslinking to form a water-insoluble aqueous untreated hydrogel polymer, and surface postcrosslinking the ground hydrogel polymer wherein blowing agents having a particle size of 100 μm to 900 μm are added to the aqueous monomer solution prior to the addition of the initiator and the start of the free-radical polymerization.
1. A process for producing a water-absorbing polymer composition, comprising the process steps of
(i) forming an aqueous monomer solution by mixing
(α1) from 0.1 to 99.999% by weight, of polymerizable, ethylenically unsaturated monomers containing acid groups or salts thereof or polymerizable, ethylenically unsaturated monomers including a protonated or quaternized nitrogen, or mixtures thereof,
(α2) from 0 to 70% by weight of polymerizable, ethylenically unsaturated monomers copolymerizable with (α1),
(α3) from 0.001 to 10% by weight of one or more crosslinkers,
(α4) from 0 to 30% by weight of water-soluble polymers, and
(α5) from 0 to 20% by weight of one or more assistants, where the sum of their weights (α1) to (α5) is 100% by weight,
(ii) free-radical polymerization with crosslinking to form a water-insoluble aqueous untreated hydrogel polymer,
(iii) drying the hydrogel polymer,
(iv) grinding and sieving the water-absorbing polymer,
(v) surface postcrosslinking the ground hydrogel polymer of step (iv), and
(vi) drying and finishing the water-absorbing polymer,
wherein the process in steps i) and ii) is done in a kneading reactor having at least one shaft and not through a reactor employing a poly belt, and wherein granulated blowing agents consisting of soda carbonate particles having a particle size of 100 μm to 900 μm are added to the aqueous monomer solution of part (i) prior to the addition of an initiator and the start of the free-radical polymerization, and wherein the water-absorbing polymer composition has a FSR is in the range from 0.4 to 0.55.
2. The process according to claim 1 , wherein iii), a comminution the water-insoluble aqueous untreated hydrogel polymer prior to the drying of the hydrogel polymer.
3. The process according to claim 1 wherein the blowing agents have a preferred particle size of 200 μm to 800 μm.
4. The process according to claim 1 , wherein the blowing agent consist of soda carbonate particles having a layer structure.
5. The process according to claim 1 wherein the process steps i) and ii) are effected batchwise or continuously in the kneading reactor.
6. The process according to claim 1 wherein the process steps i) and ii) according to claim 1 are done batchwise in the kneading reactor.
7. The process according to claim 5 wherein the kneading reactor is operated batchwise or continuously with an at least one-shaft system and the granulated blowing agent is incorporated homogeneously in the in the aqueous monomer solution.