IP Library Granted Patent US 10,314,774
Granted Patent B2
US 10,314,774 · App. 14/110,955 · Granted Jun 11, 2019

Clear wet sprays and gels

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Quick Facts
Patent No.
US 10,314,774
App. No.
14/110,955
Granted
Jun 11, 2019
Kind
B2
Abstract

Sun-care products are described that protect from UV radiation and do not turn white when applied to wet skin. The sun-care product may comprise (A) a cosmetically-acceptable, substantially non-aqueous vehicle, and (B) a UV active, wherein said non-aqueous vehicle comprises alcohol in an amount of 50% (w/w) or less based on the weight of the sun-care product and an ester wherein said non-aqueous vehicle comprises at least 10%>by weight esters based on the total weight of the non-aqueous vehicle and said sun-care product is substantially non-whitening upon application to wet skin.

Claims (15)

1. A substantially anhydrous sun-care product comprising: (A) a cosmetically-acceptable, substantially non-aqueous vehicle comprising at least 10% by weight esters based on the total weight of the non-aqueous vehicle, and (B) a UV active, wherein the non-aqueous vehicle comprises an alcohol selected from the group consisting of ethanol, 1-propanol, 2-propanol, and combinations thereof; and an ester such that the dielectric constant of the non-aqueous vehicle is about 20 or less and the sun-care product is substantially non-whitening upon application to wet skin; wherein the sun-care product comprises no more than 10% (w/w) water and having 50% (w/w) or less of the alcohol.

2. The sun-care product according to claim 1 having from 30% (w/w) to 45% (w/w) of the alcohol.

3. The sun-care product according to claim 1 wherein said UV active is selected from the group consisting of: 4-methylbenzylidene camphor, avobenzone, bemotrizinol, benzophenone-1, benzophenone-2, benzophenone-3 (oxybenzone), benzophenone-4 (sulisobenzone), benzophenone-5 (sulisobenzone sodium), benzophenone-6, benzophenone-8 (dioxybenzone), benzophenone-9, benzylidene camphor sulfonic acid, bisdisulizole disodium, bisoctrizole, camphor benzalkonium methosulfate, cinoxate, DEA methoxycinnamate, diethylamine hydroxybenzoyl hexylbenzoate, digalloyl trioleate, diisopropyl methylcinnamate, dimethoxyphenyl-[1-(3,4)]-4,4-dimethyl 1,3-pentanedione, drometrizole, drometrizole trisiloxane, ecamsule, ensulizole, ethylhexyl p-methoxycinnamate, ethylhexyl triazone, ferulic acid, glyceryl ethylhexanoate dimethoxycinnamate, homomenthyl salicylate (homosalate), iscotrizinol, isoamyl-p-methoxycinnamate, lisadimate, meradimate, camphor benzalkonium methosulfate, octocrylene, octyl dimethyl PABA (padimate O), octyl salicylate (octisalate), p-aminobenzoic acid (PABA), PEG-25 PABA, pentyl dimethyl PABA (padimate A), polysilicone-15, roxadimate, titanium dioxide, trolamine salicylate, zinc oxide, and combinations thereof.

4. The sun-care product according to claim 3 wherein each said UV active is present in an amount from 0.5% (w/w) to 40% (w/w).

5. The sun-care product according to claim 1 having from 50% (w/w) to 99% (w/w) or more of said cosmetically-acceptable, non-aqueous vehicle.

6. The sun-care product according to claim 5 wherein said cosmetically-acceptable, non-aqueous vehicle comprises components selected from the group consisting of: esters, glycols, hydrocarbons, oils, and combinations thereof.

7. The sun-care product according to claim 6 wherein said cosmetically-acceptable, non-aqueous vehicle comprises components selected from the group consisting of: diisopropyl adipate, ethanol, hexylene glycol, isodecyl neopentanoate, isostearyl neopentanoate, phenethyl benzoate, polydimethylsiloxane, silicones, isocetyl alcohol, tridecyl neopentanoate, lauryl lactate, diisopropyl adipate, diethylhexyl malate, cyclomethicone, isohexadecane, and combinations thereof.

8. The sun-care product according to claim 1 having a sun protection factor (SPF) of at least 15.

9. The sun-care product according to claim 1 that is a mist, a spray, an aerosol, a mousse, a gel, a solution, or a dispersion.

10. The sun-care product according to claim 1 wherein said non-aqueous vehicle comprises from about 20%-50% by weight esters based on the total weight of the non-aqueous vehicle.

11. A substantially anhydrous sun-care product comprising: (A) a cosmetically-acceptable, substantially non-aqueous vehicle comprising at least 10% by weight esters based on the total weight of the non-aqueous vehicle, and (B) a UV active, wherein said non-aqueous vehicle comprises an alcohol selected from the group consisting of ethanol, 1-propanol, 2-propanol, and combinations thereof; in an amount of 50% (w/w) or less based on the weight of the sun-care product and an ester the sun-care product is substantially non-whitening upon application to wet skin; wherein the sun-care product comprises no more than 10% (w/w) and having 50% (w/w) or less of the alcohol.

12. The sun-care product according to claim 11 wherein said non-aqueous vehicle comprises from about 20%-50% by weight esters based on the total weight of the non-aqueous vehicle.

13. The sun-care product according to claim 12 wherein said esters are selected from the group consisting of diisopropyl adipate, isodecyl neopentanoate, isostearyl neopentanoate, phenethyl benzoate, tridecyl neopentanoate, lauryl lactate, diisopropyl adipate, diethylhexyl malate and combinations thereof.

14. A method of protecting keratinous substances from UV radiation, said method comprising applying said sun-care product of claim 1 on said keratinous substance.

15. The method according to claim 14 wherein said keratinous substance is the epidermis or hair of a mammal.

Assignments (4)
RELEASE OF SECURITY INTEREST Recorded Jan 10, 2020
From: THE BANK OF NOVA SCOTIA
To: AVOCA LLC; HERCULES LLC; ISP INVESTMENTS LLC; PHARMACHEM LABORATORIES LLC
Reel/Frame 051557/0504 →
SECURITY AGREEMENT Recorded Jul 3, 2017
From: AVOCA, INC.; HERCULES LLC; ISP INVESTMENTS LLC; PHARMACHEM LABORATORIES, INC.
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 043084/0753 →
CHANGE OF NAME Recorded May 24, 2017
From: ISP INVESTMENTS INC.
To: ISP INVESTMENTS LLC
Reel/Frame 042560/0842 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 10, 2013
From: FARES, HANI M.; PRETTYPAUL, DONALD I.; KENNEDY, DIANE M.
To: ISP INVESTMENTS INC.
Reel/Frame 031380/0402 →