Polymer compositions and methods
The present invention encompasses polymer compositions comprising aliphatic polycarbonate chains containing functional groups that increase the polymer's ability to wet or adhere to inorganic materials. In certain embodiments, chain ends of the aliphatic polycarbonates are modified to introduce silicon-containing functional groups, boron-containing functional groups, phosphorous-containing functional groups, sulfonic acid groups or carboxylic acid groups.
1. An epoxide CO 2 copolymer composition comprising epoxide CO 2 copolymer chains wherein:
one or more chain ends of at least a portion of the epoxide CO 2 copolymer chains within the epoxide CO 2 copolymer composition have a formula:
where,
R 1 , R 2 , R 3 , and R 4 are, at each occurrence in the polymer chain, independently selected from the group consisting of —H, fluorine, an optionally substituted C 1-30 aliphatic group, and an optionally substituted C 1-20 heteroaliphatic group, and an optionally substituted C 6-10 aryl group, where any two or more of R 1 , R 2 , R 3 , and R 4 may optionally be taken together with intervening atoms to form one or more optionally substituted rings optionally containing one or more heteroatoms and/or one or more sites of unsaturation;
—Q— is a bivalent or multivalent moiety;
each Z comprises an adhesion enhancing functional group independently selected from the group consisting of: silicon-containing functional groups, phosphorous-containing functional groups, —SO 3 H, —CO 2 H, and —N(R α ) 3 + where each R α is at each occurrence, independently selected from the group consisting of optionally substituted phenyl, and optionally substituted C 1-12 aliphatic; and
α is an integer from 1 to 4 inclusive;
the epoxide CO 2 copolymer composition is characterized in that, on average in the composition, the percentage of carbonate linkages in epoxide CO 2 copolymer chains is 90% or greater;
the number average molecular weight of the epoxide CO 2 copolymer composition is less than about 20,000 g/mol; and
further, wherein one or more chain ends of at least a portion of the epoxide CO 2 copolymer chains within the epoxide CO 2 copolymer composition have a formula:
where,
R 1 , R 2 , R 3 , and R 4 are, at each occurrence in the polymer chain, independently selected from the group consisting of —H, fluorine, an optionally substituted C 1-30 aliphatic group, and an optionally substituted C 1-20 heteroaliphatic group, and an optionally substituted C 6-10 aryl group, where any two or more of R 1 , R 2 , R 3 , and R 4 may optionally be taken together with intervening atoms to form one or more optionally substituted rings optionally containing one or more heteroatoms and/or one or more sites of unsaturation.
2. The epoxide CO 2 copolymer composition of claim 1 , wherein the adhesion enhancing functional group is linked to a chain end via an ester linkage.
3. The epoxide CO 2 copolymer composition of claim 1 , wherein the adhesion enhancing functional group is linked to a chain end via a urethane linkage.
4. The epoxide CO 2 copolymer composition of claim 1 , wherein the adhesion enhancing functional group is linked to a chain end via an ether linkage.
5. The epoxide CO 2 copolymer composition of claim 1 , wherein the adhesion enhancing functional group comprises a silicon-containing functional group and a silicon atom is bonded directly to a terminal oxygen atom of the epoxide CO 2 copolymer.
6. The epoxide CO 2 copolymer composition of claim 1 , wherein the epoxide CO 2 copolymer chains comprise a primary repeat unit having a formula:
7. The epoxide CO 2 copolymer composition of claim 6 , wherein the -Q-(Z) α , moieties are selected from the group consisting of:
where R a and R b are, at each occurrence, independently selected from the group consisting of —H, halogen, an optionally substituted C 1-20 aliphatic group, an optionally substituted C 1-20 heteroaliphatic group, an optionally substituted C 6-14 aryl group, an optionally substituted acyloxy group, an optionally substituted acyl group, an optionally substituted alkoxy group, an optionally substituted 3- to 14-membered carbocyclic group, and an optionally substituted 3- to 12-membered heterocyclic group, where any two or more R a and R b groups may optionally be taken together with intervening atoms to form one or more optionally substituted, optionally unsaturated rings optionally containing one or more heteroatoms, where any two or more R a and R b groups on adjacent carbon atoms may optionally be taken together with intervening atoms to form an optionally substituted aryl ring, where an R a or R b on one carbon atom and an R a or R b , on an adjacent carbon may optionally be taken together with the bond between the adjacent carbons to represent a double bond between the two carbon atoms, and where R a and R b groups attached to the same atom may be taken together to form an optionally substituted moiety selected from the group consisting of: alkene, imine, oxime, and hydrazone;
R d is, at each occurrence, independently selected from the group consisting of: halogen, —NO 2 , —CN, —SR, —S(O)R, —S(O) 2 R, —NRC(O)R, —OC(O)R, —CO 2 R, —NCO, —N 3 , —OR, —OC(O)N(R) 2 , —N(R) 2 , —NRC(O)R, —NRC(O)OR; or an optionally substituted radical selected from the group consisting of C 1-20 aliphatic, C 1-20 heteroaliphatic, a 3- to 14-membered carbocycle, a 3- to 12-membered heterocycle, a 5- to 12-membered heteroaryl, and 6- to 10-membered aryl; where two or more adjacent R d groups can be taken together to form an optionally substituted saturated, partially unsaturated, or aromatic 5- to 12-membered ring containing 0 to 4 heteroatoms; where each occurrence of R is independently —H, or an optionally substituted moiety selected from the group consisting of C 1-6 aliphatic, C 1-6 heteroaliphatic, 3- to 7-membered heterocyclic, 3- to 7-membered carbocyclic 6- to 10-membered aryl, and 5- to 10-membered heteroaryl;
each R 1s is independently a C 1-6 aliphatic group or optionally substituted aryl group;
each R 2s is independently —H, optionally substituted C 1-6 aliphatic, or optionally substituted phenyl;
each Q′ is a multifunctional organic moiety optionally containing one or more heteroatoms and each Q′ may be the same or different;
s is an integer from 1 to 8; and
m is 0, 1, 2, or 3.
8. The epoxide CO 2 copolymer composition of claim 6 , wherein each
moiety in the polymer chain is independently selected from the group consisting of:
where each R x is independently an optionally substituted moiety selected from the group consisting of C 2-20 aliphatic, C 2-20 heteroaliphatic, 3- to 14-membered carbocyclic, 6- to 10-membered aryl, 5- to 10-membered heteroaryl, and 3- to 12-membered heterocyclic.
9. The epoxide CO 2 copolymer composition of claim 1 , wherein the epoxide CO 2 polymer chains comprise a copolymer of CO 2 and an epoxide selected from the group consisting of: ethylene oxide, propylene oxide, 1,2 butene oxide, cyclohexene oxide, epichlorohydrin, 3-vinyl cyclohexene oxide, 3-ethyl cyclohexene oxide, a glycidyl ester, a glycidyl ether and any combination of two or more of these.
10. The epoxide CO 2 copolymer composition of claim 1 , wherein the epoxide CO 2 polymer chains comprise a copolymer of CO 2 and propylene oxide.
11. An epoxide CO 2 copolymer composition comprising epoxide CO 2 polymer chains wherein at least a portion of the epoxide CO2 copolymer chains within the epoxide CO2 copolymer composition have the formula P1:
where
R 1 , R 2 , R 3 , and R 4 are, at each occurrence in the polymer chain, independently selected from the group consisting of —H, fluorine, an optionally substituted C 1-30 aliphatic group, and an optionally substituted C 1-20 heteroaliphatic group, and an optionally substituted C 6-10 aryl group, where any two or more of R 1 , R 2 , R 3 , and R 4 may optionally be taken together with intervening atoms to form one or more optionally substituted rings optionally containing one or more heteroatoms and/or one or more sites of unsaturation;
n is an integer from about 2 to about 100;
is a multivalent moiety; and
Y is, at each occurrence, independently selected from the group consisting of
—Q— is a bivalent or multivalent moiety,
each Z comprises an adhesion enhancing functional group independently selected from the group consisting of: silicon-containing functional groups, phosphorous-containing functional groups, —SO 3 H, —CO 2 H, and —N(R α ) 3 + where each R α is at each occurrence, independently selected from the group consisting of optionally substituted phenyl, and optionally substituted C 1-12 aliphatic, and
α is an integer from 1 to 4 inclusive; and
x and y are each independently from 0 to 6, and the sum of x and y is between 2 and 6further, wherein one or more chain ends of at least a portion of the epoxide CO 2 copolymer chains within the epoxide CO 2 copolymer composition have a formula:
where,
R 1 , R 2 , R 3 , and R 4 are, at each occurrence in the polymer chain, independently selected from the group consisting of —H, fluorine, an optionally substituted C 1-30 aliphatic group, and an optionally substituted C 1-20 heteroaliphatic group, and an optionally substituted C 6-10 aryl group, where any two or more of R 1 , R 2 , R 3 , and R 4 may optionally be taken together with intervening atoms to form one or more optionally substituted rings optionally containing one or more heteroatoms and/or one or more sites of unsaturation.
12. The epoxide CO 2 copolymer composition of claim 11 , wherein the epoxide CO 2 polymer chains of formula P1 are selected from the group consisting of:
13. The epoxide CO 2 copolymer composition of claim 11 , wherein the epoxide CO 2 polymer chains of formula P1 are of formula:
14. The epoxide CO 2 copolymer composition of claim 12 , wherein
represents the bound form of a diol selected from the group consisting of: 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 1,5-pentanediol, 2,2-dimethylpropane-1,3-diol, 2-butyl-2-ethylpropane-1,3-diol, 2-methyl-2,4-pentane diol, 2-ethyl-1,3-hexane diol, 2-methyl-1,3-propane diol, 1,5-hexanediol, 1,6-hexanediol, 1,8-octanediol, 1,10-decanediol, 1,12-dodecanediol, 2,2,4,4-tetramethylcyclobutane-1,3-diol, 1,3-cyclopentanediol, 1,2-cyclohexanediol, 1,3-cyclohexanediol, 1,4-cyclohexanediol, 1,2-cyclohexanedimethanol, 1,3-cyclohexanedimethanol, 1,4-cyclohexanedimethanol, 1,4-cyclohexanediethanol, isosorbide, glycerol monoesters, glycerol monoethers, trimethylolpropane monoesters, trimethylolpropane monoethers, pentaerythritol diesters, pentaerythritol diethers, and alkoxylated derivatives of any of these.
15. The epoxide CO 2 copolymer composition of claim 12 , wherein
represents the bound form of a diol selected from the group consisting of: diethylene glycol, triethylene glycol, tetraethylene glycol, higher poly(ethylene glycol) having number average molecular weights of from 220 to about 2000 g/mol, dipropylene glycol, tripropylene glycol, and higher poly(propylene glycols) having number average molecular weights of from 234 to about 2000 g/mol.
16. The epoxide CO 2 copolymer composition of claim 12 , further comprising epoxide CO 2 polymer chains of formula P1′
where
R 1 , R 2 , R 3 , and R 4 are, at each occurrence in the polymer chain, independently selected from the group consisting of —H, fluorine, an optionally substituted C 1-30 aliphatic group, and an optionally substituted C 1-20 heteroaliphatic group, and an optionally substituted C 6-10 aryl group, where any two or more of R 1 , R 2 , R 3 , and R 4 may optionally be taken together with intervening atoms to form one or more optionally substituted rings optionally containing one or more heteroatoms and/or one or more sites of unsaturation;
n is an integer from about 2 to about 100;
is a multivalent moiety; and
Y is, at each occurrence, independently selected from the group consisting of a moiety having a reactive olefin selected from an acrylate, a styrene, and a vinyl ether;
and
x and y are each independently from 0 to 6, and the sum of x and y is between 2 and 6.
17. The epoxide CO 2 copolymer composition of claim 16 , wherein each Y of an epoxide CO 2 copolymer chain of formula P1 is independently a
moiety selected from the group consisting of:
where
p is an integer from 1 to 10;
R a and R b are, at each occurrence, independently selected from the group consisting of —H, halogen, an optionally substituted C 1-20 aliphatic group, an optionally substituted C 1-20 heteroaliphatic group, an optionally substituted C 6-14 aryl group, an optionally substituted acyloxy group, an optionally substituted acyl group, an optionally substituted alkoxy group, an optionally substituted 3- to 14-membered carbocyclic group, and an optionally substituted 3- to 12-membered heterocyclic group, where any two or more R a and R b groups may optionally be taken together with intervening atoms to form one or more optionally substituted, optionally unsaturated rings optionally containing one or more heteroatoms, where any two or more R a and R b groups on adjacent carbon atoms may optionally be taken together with intervening atoms to form an optionally substituted aryl ring, where an R a or R b on one carbon atom and an R a or R b , on an adjacent carbon may optionally be taken together with the bond between the adjacent carbons to represent a double bond between the two carbon atoms, and where R a and R b groups attached to the same atom may be taken together to form an optionally substituted moiety selected from the group consisting of: alkene, imine, oxime, and hydrazone; and
R d is, at each occurrence, independently selected from the group consisting of: halogen, —NO 2 , —CN, —SR, —S(O)R, —S(O) 2 R, —NRC(O)R, —OC(O)R, —CO 2 R, —NCO, —N 3 , —OR, —OC(O)N(R) 2 , —N(R) 2 , —NRC(O)R, —NRC(O)OR; or an optionally substituted radical selected from the group consisting of C 1-20 aliphatic, C 1-20 heteroaliphatic, a 3- to 14-membered carbocycle, a 3- to 12-membered heterocycle, a 5- to 12-membered heteroaryl, and 6- to 10-membered aryl; where two or more adjacent R d groups can be taken together to form an optionally substituted saturated, partially unsaturated, or aromatic 5- to 12-membered ring containing 0 to 4 heteroatoms; where each occurrence of R is independently —H, or an optionally substituted moiety selected from the group consisting of C 1-6 aliphatic, C 1-6 heteroaliphatic, 3- to 7-membered heterocyclic, 3- to 7-membered carbocyclic 6- to 10-membered aryl, and 5- to 10-membered heteroaryl.
18. The epoxide CO 2 copolymer composition of claim 16 , wherein each Y of an epoxide CO 2 copolymer chain of formula P1 is independently a
moiety selected from the group consisting of:
where s is an integer from 1 to 8; and
R d is, at each occurrence, independently selected from the group consisting of:
halogen, —NO 2 , —CN, —SR, —S(O)R, —S(O) 2 R, —RC(O)R, —OC(O)R, —CO 2 R, —NCO, —N 3 , —OR, —OC(O)N(R) 2 , —N(R) 2 , —NRC(O)R, —NRC(O)OR; or an optionally substituted radical selected from the group consisting of C 1 - 20 aliphatic, C 1 - 20 heteroaliphatic, a 3- to 14-membered carbocycle, a 3- to 12-membered heterocycle, a 5- to 12-membered heteroaryl, and 6- to 10-membered aryl; where two or more adjacent R d groups can be taken together to form an optionally substituted saturated, partially unsaturated, or aromatic 5- to 12-membered ring containing 0 to 4 heteroatoms; where each occurrence of R is independently —H, or an optionally substituted moiety selected from the group consisting of C 1 - 6 aliphatic, C 1 - 6 heteroaliphatic, 3- to 7-membered heterocyclic, 3- to 7-membered carbocyclic 6- to 10-membered aryl, and 5- to 10-membered heteroaryl; and
R 5 is, at each occurrence, independently selected from the group consisting of —CH 3 , -Ph, and —SO 3 H.
19. The epoxide CO 2 copolymer composition of claim 17 , wherein each Y of an epoxide CO 2 copolymer chain of formula P1 is independently a
moiety selected from the group consisting of:
20. The epoxide CO 2 copolymer composition of claim 1 , further comprising epoxide CO 2 polymer chains of formula:
where
R 1 , R 2 , R 3 , and R 4 are, at each occurrence in the polymer chain, independently selected from the group consisting of —H, fluorine, an optionally substituted C 1-30 aliphatic group, and an optionally substituted C 1-20 heteroaliphatic group, and an optionally substituted C 6-10 aryl group, where any two or more of R 1 , R 2 , R 3 , and R 4 may optionally be taken together with intervening atoms to form one or more optionally substituted rings optionally containing one or more heteroatoms and/or one or more sites of unsaturation;
—Q— is a bivalent or multivalent moiety,
each Z comprises a moiety independently selected from the group consisting of: silicon-containing functional groups, phosphorous-containing functional groups, —SO 3 H, —CO 2 H, and —N(R α ) 3 + where each R α is at each occurrence, independently selected from the group consisting of optionally substituted phenyl, and optionally substituted C 1-12 aliphatic,
α is an integer from 1 to 4 inclusive;
X′ is selected from the group consisting of C 1-20 acyl oxy, halogen, alkoxy, nitrate, azide, optionally substituted phenoxy, nitrophenoxy and sulfonate; and
n is an integer from 5 to about 500.
21. The epoxide CO 2 copolymer composition of claim 20 , wherein the epoxide CO 2 polymer chains of formula:
are of formula:
22. The epoxide CO 2 copolymer composition of claim 20 , wherein the
groups of the epoxide CO 2 copolymer chains of formula:
are selected from the group consisting of:
where
p is an integer from 1 to 10;
R a and R b are, at each occurrence, independently selected from the group consisting of —H, halogen, an optionally substituted C 1-20 aliphatic group, an optionally substituted C 1-20 heteroaliphatic group, an optionally substituted C 6-14 aryl group, an optionally substituted acyloxy group, an optionally substituted acyl group, an optionally substituted alkoxy group, an optionally substituted 3- to 14-membered carbocyclic group, and an optionally substituted 3- to 12-membered heterocyclic group, where any two or more R a and R b groups may optionally be taken together with intervening atoms to form one or more optionally substituted, optionally unsaturated rings optionally containing one or more heteroatoms, where any two or more R a and R b groups on adjacent carbon atoms may optionally be taken together with intervening atoms to form an optionally substituted aryl ring, where an R a or R b on one carbon atom and an R a or R b , on an adjacent carbon may optionally be taken together with the bond between the adjacent carbons to represent a double bond between the two carbon atoms, and where R a and R b groups attached to the same atom may be taken together to form an optionally substituted moiety selected from the group consisting of: alkene, imine, oxime, and hydrazone; and
R d is, at each occurrence, independently selected from the group consisting of: halogen, —NO 2 , —CN, —SR, —S(O)R, —S(O) 2 R, —NRC(O)R, —OC(O)R, —CO 2 R, —NCO, —N 3 , —OR, —OC(O)N(R) 2 , —N(R) 2 , —NRC(O)R, —NRC(O)OR; or an optionally substituted radical selected from the group consisting of C 1-20 aliphatic, C 1-20 heteroaliphatic, a 3- to 14-membered carbocycle, a 3- to 12-membered heterocycle, a 5- to 12-membered heteroaryl, and 6- to 10-membered aryl; where two or more adjacent R d groups can be taken together to form an optionally substituted saturated, partially unsaturated, or aromatic 5- to 12-membered ring containing 0 to 4 heteroatoms; where each occurrence of R is independently —H, or an optionally substituted moiety selected from the group consisting of C 1-6 aliphatic, C 1-6 heteroaliphatic, 3- to 7-membered heterocyclic, 3- to 7-membered carbocyclic 6- to 10-membered aryl, and 5- to 10-membered heteroaryl.
23. The epoxide CO 2 copolymer composition of claim 20 , wherein the
groups of the epoxide CO 2 copolymer chains of formula:
are selected from the group consisting of:
where s is an integer from 1 to 8;
R d is, at each occurrence, independently selected from the group consisting of:
halogen, —NO 2 , —CN, —SR, —S(O)R, —S(O) 2 R, —NRC(O)R, —OC(O)R, —CO 2 R, —NCO, —N 3 , —OR, —OC(O)N(R) 2 , —N(R) 2 , —NRC(O)R, —NRC(O)OR; or an optionally substituted radical selected from the group consisting of C 1 - 20 aliphatic, C 1 - 20 heteroaliphatic, a 3- to 14-membered carbocycle, a 3- to 12-membered heterocycle, a 5- to 12-membered heteroaryl, and 6- to 10-membered aryl; where two or more adjacent R d groups can be taken together to form an optionally substituted saturated, partially unsaturated, or aromatic 5- to 12-membered ring containing 0 to 4 heteroatoms; where each occurrence of R is independently —H, or an optionally substituted moiety selected from the group consisting of C 1 - 6 aliphatic, C 1 - 6 heteroaliphatic, 3- to 7-membered heterocyclic, 3- to 7-membered carbocyclic 6- to 10-membered aryl, and 5- to 10-membered heteroaryl; and
R 5 is, at each occurrence, independently selected from the group consisting of —CH 3 , -Ph, and —SO 3 H.
24. A higher polymer comprising the reaction product of an epoxide CO 2 copolymer composition of claim 1 with a polyfunctional reagent selected from the group consisting of: polyisocyanates, melamine, and phenol formaldehyde resins.
25. A higher polymer comprising a reaction product of olefin polymerization between an epoxide CO 2 copolymer composition of claim 16 and a reactive diluent comprising a reactive olefin.
26. A composite comprising a higher polymer composition of claim 24 in combination with one or more inorganic materials.
27. A glass laminate comprising epoxide CO 2 copolymer composition of claim 1 .
28. A method for producing an epoxide CO 2 copolymer composition of claim 1 having improved glass adhesion comprising the step of treating the epoxide CO 2 copolymer with a reagent to convert at least a portion of the free —OH end groups of the epoxide CO 2 copolymer to moieties comprising a functional group selected from the group consisting of: carboxylic acid groups, silicon-containing functional groups, sulfonic acid groups, boron-containing functional groups, phosphorus-containing functional groups, ammonium groups, and combinations of two or more of these.
29. The epoxide CO 2 copolymer composition of claim 11 , wherein each Y of an epoxide CO 2 copolymer chain of formula P1 is independently a
moiety selected from the group consisting of:
where
p is an integer from 1 to 10;
R a and R b are, at each occurrence, independently selected from the group consisting of —H, halogen, an optionally substituted C 1-20 aliphatic group, an optionally substituted C 1-20 heteroaliphatic group, an optionally substituted C 6-14 aryl group, an optionally substituted acyloxy group, an optionally substituted acyl group, an optionally substituted alkoxy group, an optionally substituted 3- to 14-membered carbocyclic group, and an optionally substituted 3- to 12-membered heterocyclic group, where any two or more R a and R b groups may optionally be taken together with intervening atoms to form one or more optionally substituted, optionally unsaturated rings optionally containing one or more heteroatoms, where any two or more R a and R b groups on adjacent carbon atoms may optionally be taken together with intervening atoms to form an optionally substituted aryl ring, where an R a or R b on one carbon atom and an R a or R b , on an adjacent carbon may optionally be taken together with the bond between the adjacent carbons to represent a double bond between the two carbon atoms, and where R a and R b groups attached to the same atom may be taken together to form an optionally substituted moiety selected from the group consisting of: alkene, imine, oxime, and hydrazone; and
R d is, at each occurrence, independently selected from the group consisting of: halogen, —NO 2 , —CN, —SR, —S(O)R, —S(O) 2 R, —NRC(O)R, —OC(O)R, —CO 2 R, —NCO, —N 3 , —OR, —OC(O)N(R) 2 , —N(R) 2 , —NRC(O)R, —NRC(O)OR; or an optionally substituted radical selected from the group consisting of C 1-20 aliphatic, C 1-20 heteroaliphatic, a 3- to 14-membered carbocycle, a 3- to 12-membered heterocycle, a 5- to 12-membered heteroaryl, and 6- to 10-membered aryl; where two or more adjacent R d groups can be taken together to form an optionally substituted saturated, partially unsaturated, or aromatic 5- to 12-membered ring containing 0 to 4 heteroatoms; where each occurrence of R is independently —H, or an optionally substituted moiety selected from the group consisting of C 1-6 aliphatic, C 1-6 heteroaliphatic, 3- to 7-membered heterocyclic, 3- to 7-membered carbocyclic 6- to 10-membered aryl, and 5- to 10-membered heteroaryl.
30. The epoxide CO 2 copolymer composition of claim 11 , wherein each Y of an epoxide CO 2 copolymer chain of formula P1 is independently a
moiety selected from the group consisting of:
where s is an integer from 1 to 8; and
R d is, at each occurrence, independently selected from the group consisting of: halogen, —NO 2 , —CN, —SR, —S(O)R, —S(O) 2 R, —NRC(O)R, —OC(O)R, —CO 2 R, —NCO, —N 3 , —OR, —OC(O)N(R) 2 , —N(R) 2 , —NRC(O)R, —NRC(O)OR; or an optionally substituted radical selected from the group consisting of C 1 - 20 aliphatic, C 1 - 20 heteroaliphatic, a 3- to 14-membered carbocycle, a 3- to 12-membered heterocycle, a 5- to 12-membered heteroaryl, and 6- to 10-membered aryl; where two or more adjacent R d groups can be taken together to form an optionally substituted saturated, partially unsaturated, or aromatic 5- to 12-membered ring containing 0 to 4 heteroatoms; where each occurrence of R is independently —H, or an optionally substituted moiety selected from the group consisting of C 1 - 6 aliphatic, C 1 - 6 heteroaliphatic, 3- to 7-membered heterocyclic, 3- to 7-membered carbocyclic 6- to 10-membered aryl, and 5- to 10-membered heteroaryl; and
R 5 is, at each occurrence, independently selected from the group consisting of —CH 3 , -Ph, and —SO 3 H.
31. The epoxide CO 2 copolymer composition of claim 29 , wherein each Y of an epoxide CO 2 copolymer chain of formula P1 is independently a
moiety selected from the group consisting of:
32. The epoxide CO 2 copolymer composition of claim 1 , wherein the epoxide CO 2 copolymer composition is characterized in that, on average in the composition, the percentage of carbonate linkages in epoxide CO 2 copolymer chains is 95% or greater.
33. The epoxide CO 2 copolymer composition of claim 1 , wherein the epoxide CO 2 copolymer composition is characterized in that, on average in the composition, the percentage of carbonate linkages in epoxide CO 2 copolymer chains is 99% or greater.
34. The epoxide CO 2 copolymer composition of claim 11 , wherein the epoxide CO 2 copolymer composition is characterized in that, on average in the composition, the percentage of carbonate linkages in epoxide CO 2 copolymer chains is 90% or greater.
35. The epoxide CO 2 copolymer composition of claim 11 , wherein the epoxide CO 2 copolymer composition is characterized in that, on average in the composition, the percentage of carbonate linkages in epoxide CO 2 copolymer chains is 95% or greater.
36. The epoxide CO 2 copolymer composition of claim 11 , wherein the epoxide CO 2 copolymer composition is characterized in that, on average in the composition, the percentage of carbonate linkages in epoxide CO 2 copolymer chains is 99% or greater.
37. The epoxide CO 2 copolymer composition of claim 1 , the number average molecular weight of the epoxide CO 2 copolymer composition is between 500 g/mol and 5,000g/mol.
38. The epoxide CO 2 copolymer composition of claim 33 , the number average molecular weight of the epoxide CO 2 copolymer composition is between 500 g/mol and 5,000g/mol.
39. The epoxide CO 2 copolymer composition of claim 36 , the number average molecular weight of the epoxide CO 2 copolymer composition is between 500 g/mol and 5,000g/mol.