Method for producing acrylamide aqueous solution
View Patent ↗There is provided a method for producing an aqueous acrylamide solution by producing acrylamide by reacting a composition including acrylonitrile with water, in which the composition including acrylonitrile includes 20 to 80 mg of methacrylonitrile per 1 kg of the total weight of the composition including acrylonitrile. According to the present invention, a production method allowing stable obtainment of an aqueous acrylamide solution can be provided as polymerization of the acrylamide can be suppressed without causing a decreas+455e in quality.
1. A method for producing an aqueous acrylamide solution, the method comprising reacting an acrylonitrile composition and water in the presence of a catalyst to produce said aqueous acrylamide solution,
wherein the acrylonitrile composition comprises acrylonitrile and 20 to 80 mg of methacrylonitrile per 1 kg of the acrylonitrile composition.
2. The method according to claim 1 , wherein the reacting of the acrylonitrile composition and water is performed in the presence of a biocatalyst.
3. The method according to claim 1 , wherein the acrylonitrile composition further comprises 2 to 20 mg of acetonitrile per 1 kg of the acrylonitrile composition.
4. The method according to claim 1 , wherein the concentration of the acrylamide in the aqueous acrylamide solution is from 30 to 60% by mass relative to the total mass of the aqueous acrylamide solution.
5. The method according to claim 1 , wherein the acrylonitrile composition comprises acrylonitrile and 30 to 60 mg of methacrylonitrile per 1 kg of the acrylonitrile composition.
6. The method according to claim 1 , wherein the acrylonitrile composition further comprises 5 to 15 mg of acetonitrile per 1 kg of the acrylonitrile composition.
7. The method according to claim 5 , wherein the acrylonitrile composition further comprises 5 to 15 mg of acetonitrile per 1 kg of the acrylonitrile composition.
8. The method according to claim 1 , wherein the concentration of the acrylamide in the aqueous acrylamide solution is from 40 to 50% by mass relative to the total mass of the aqueous acrylamide solution.
9. The method according to claim 7 , wherein the concentration of the acrylamide in the aqueous acrylamide solution is from 40 to 50% by mass relative to the total mass of the aqueous acrylamide solution.
10. The method according to claim 1 , wherein said reacting of said acrylonitrile composition and water is conducted in the presence of said catalyst and a water soluble monocarboxylic acid salt containing two or more carbon atoms.
11. The method according to claim 10 , wherein said water soluble monocarboxylic acid salt containing two or more carbon atoms is at least one selected from the sodium, potassium and ammonium salts of acetic acid, propionic acid, n-caproic acid, acrylic acid, methacrylic acid and vinyl acetic acid.
12. The method according to claim 1 , wherein after said reacting of said acrylonitrile composition and water in the presence of a catalyst a water soluble monocarboxylic acid salt containing two or more carbon atoms is added to the aqueous acrylamide solution.
13. The method according to claim 12 , wherein said water soluble monocarboxylic acid salt containing two or more carbon atoms is at least one selected from the group consisting of sodium, potassium and ammonium salts of acetic acid, propionic acid, n-caproic acid, acrylic acid, methacrylic acid and vinyl acetic acid.