Thickened viscoelastic fluids and uses thereof
View Patent ↗The present invention generally relates to a viscoelastic fluids, thickened acid compositions and the like and to methods of using said gelled compositions. The thickened compositions of the present invention can usefully be employed in methods of stimulating and/or modifying the permeability of underground formations, in drilling fluids, completion fluids, workover fluids, acidizing fluids, fracturing, gravel packing and the like.
1. An aqueous viscoelastic fluid which comprises at least one gelling agent composition, wherein said gelling agent composition comprises at least one viscoelastic surfactant of the general formula:
wherein R 1 is a saturated or unsaturated, hydrocarbon group of from about 17 to about 29 carbon atoms, R 2 and R 3 are each independently selected from a straight chain or branched, alkyl or hydroxyalkyl group of from 1 to about 6 carbon atoms, R 4 is selected from H, hydroxyl, alkyl or hydroxyalkyl groups of from 1 to about 4 carbon atoms; k is an integer of from 2-20, m is an integer of from 1-20 and n is an integer of from 0-20, and a solvent system that comprises water, monohydric alcohol and a dihydric or polyhydric alcohol, wherein the monohydric alcohol is ethanol and the dihydric or polyhydric alcohol is propylene glycol, wherein the weight to weight ratio of said monohydric alcohol to said dihydric or polyhydric alcohol in said gelling agent composition is from about 1.0 to 2.2, and wherein the water content of said gelling agent composition is 15% by weight or greater, and the weight to weight ratio of ethanol to water is from about 1.0 to 1.175.
2. The fluid of claim 1 wherein R 1 is a saturated or unsaturated, hydrocarbon group of from about 18 to about 21 carbon atoms, R 2 and R 3 are each independently selected from a straight chain or branched, alkyl or hydroxyalkyl group of from 1 to about 3 carbon atoms, R 4 is selected from H, alkyl or hydroxyalkyl groups of from 1 to about 3 carbon atoms; k is an integer of from 2-6, m is an integer of from 1-6 and n is an integer of from 0-6.
3. A well stimulation composition which comprises from about 0.5% to about 10% of the thickened viscoelastic fluid of claim 1 .
4. The well stimulation fluid of claim 3 wherein said fluid is a fracturing fluid, matrix acidizing fluid, a completion acidizing fluid, a fracture acidizing fluid, or a damage removal acidizing fluid.
5. An acidizing fluid which comprised at least one acid and an effective amount of the viscoelastic fluid of claim 1 .
6. The acidizing fluid of claim 5 wherein said acid is selected from the group consisting of mineral acids, organic acids, and mixtures thereof.
7. The acidizing fluid of claim 6 wherein said acid is selected from the group consisting of hydrochloric, hydrofluoric, acetic, formic, sulfamic, chloroacetic, and mixtures thereof.
8. A method of acidizing an underground formation which comprises injecting the acidizing fluid of claim 5 into said formation.
9. The method of claim 8 wherein said formation is a hydrocarbon reservoir or a water reservoir.
10. The method of claim 9 wherein said acidizing fluid is injected into said reservoir at a rate at or above the reservoir fracture pressure.
11. An aqueous fracturing fluid which comprises an effective amount of the viscoelastic fluid of claim 1 .
12. A method of fracturing a subterranean formation comprising the steps of pumping the aqueous fracturing fluid of claim 11 through a wellbore and into a subterranean formation at a pressure sufficient to fracture the formation.
13. An aqueous viscoelastic fluid which comprises at least one gelling agent composition, wherein said gelling agent composition comprises at least one viscoelastic surfactant of the general formula:
wherein R 1 is a saturated or unsaturated, hydrocarbon group of from about 17 to about 29 carbon atoms, R 2 and R 3 are each independently selected from a straight chain or branched, alkyl or hydroxyalkyl group of from 1 to about 6 carbon atoms, R 4 is selected from H, hydroxyl, alkyl or hydroxyalkyl groups of from 1 to about 4 carbon atoms; k is an integer of from 2-20, m is an integer of from 1-20 and n is an integer of from 0-20, and a solvent system that comprises water, from about 16 wt % to about 22 wt % ethanol, from about 10 wt % to about 16 wt % propylene glycol, and wherein the total weight % ethanol+propylene glycol is from about 25 weight % to about 40 weight %.
14. The fluid of claim 13 wherein the weight to weight ratio of ethanol to propylene glycol is from about 1.0 to 2.2.
15. The fluid of claim 14 which comprises from about 15-25 wt % water.
16. The fluid of claim 15 wherein the weight to weight ratio range of ethanol to water is from about 1.0 to about 1.175.