EMI shielding material having improved delamination behavior
View Patent ↗Disclosed herein are thermoplastic compositions that provide electromagnetic/radio frequency interference (EMI/RFI) shielding characteristics to a molded article. The compositions offer improved delamination behavior. The compositions include a polycarbonate resin, a polysiloxane block co-polycarbonate, a conductive filler capable of providing EMI shielding characteristics and optionally other pigments and/or processing additives. The compositions can be used in a variety of applications such as personal computers, notebook and portable computers, cameras, or other electronic devices.
1. A thermoplastic composition, comprising:
a) from 1 to 30% by weight of polycarbonate;
b) from 30 to 90% by weight of a polysiloxane block co-polycarbonate wherein the polysiloxane block co-polycarbonate has a polysiloxane block content of 10% by weight or less;
c) from 1 to 30% by weight of an electromagnetic shielding agent, wherein the electromagnetic shielding agent comprises a metal fiber, a metal-coated fiber, or a combination thereof; and
d) from 0 to 20% by weight of at least one additive selected from a pigment, a processing additive or a combination including at least one of the foregoing additives;
wherein the composition after molding has a shielding effectiveness of at least about 10 decibels measured according to ASTM D4935;
further wherein the composition after molding and being painted or coated has a decreased number of delamination defects as compared to a reference thermoplastic composition having an equivalent amount of polysiloxane block content but which comprises a polysiloxane block co-polycarbonate having a higher polysiloxane block content.
2. The thermoplastic composition of claim 1 , wherein the polysiloxane block co-polycarbonate has a polysiloxane block content of less than 10% by weight.
3. The thermoplastic composition of claim 1 , wherein the polysiloxane block co-polycarbonate has a polysiloxane block content of 8% by weight or less.
4. The thermoplastic composition of claim 1 , wherein the polysiloxane block co-polycarbonate has a polysiloxane block content of 6% by weight or less.
5. The thermoplastic composition of claim 1 , wherein the polysiloxane block co-polycarbonate has a haze of less than 10% as measured using 3.2 mm thick plaques according to ASTM-D1003-00.
6. The thermoplastic composition of claim 1 , wherein the electromagnetic shielding agent comprises stainless steel fibers.
7. The thermoplastic composition of claim 1 , wherein the composition comprises from 1 to 10% by weight of at least one additive selected from a pigment, a processing additive or a combination including at least one of the foregoing additives.
8. A thermoplastic composition, comprising:
a) from 5 to 20% by weight of polycarbonate;
b) from 50 to 85% by weight of a polysiloxane block co-polycarbonate wherein the polysiloxane block co-polycarbonate has a polysiloxane block content of 8% by weight or less;
c) from 5 to 20% by weight of an electromagnetic shielding agent, wherein the electromagnetic shielding agent comprises a metal fiber, a metal-coated fiber, or a combination thereof; and
d) from 1 to 10% by weight of at least one additive selected from a pigment, a processing additive or a combination including at least one of the foregoing additives;
wherein the composition after molding has a shielding effectiveness of at least about 10 decibels measured according to ASTM D4935;
further wherein the composition after molding and being painted or coated has a decreased number of delamination defects as compared to a reference thermoplastic composition having an equivalent amount of polysiloxane block content but which comprises a polysiloxane block co-polycarbonate having a higher polysiloxane block content.
9. A thermoplastic composition, comprising:
a) from 10 to 25% by weight of polycarbonate;
b) from 60 to 75% by weight of a polysiloxane block co-polycarbonate wherein the polysiloxane block co-polycarbonate has a polysiloxane block content of 6% by weight or less;
c) from 5 to 15% by weight of an electromagnetic shielding agent, wherein the electromagnetic shielding agent comprises a metal fiber, a metal-coated fiber, or a combination thereof; and
d) from 1 to 10% by weight of at least one additive selected from a pigment, a processing additive or a combination including at least one of the foregoing additives;
wherein the composition after molding has a shielding effectiveness of at least about 10 decibels measured according to ASTM D4935;
further wherein the composition after molding and being painted or coated has a decreased number of delamination defects as compared to a reference thermoplastic composition having an equivalent amount of polysiloxane block content but which comprises a polysiloxane block co-polycarbonate having a higher polysiloxane block content.
10. An article of manufacture comprising the composition of claim 1 .
11. The article of manufacture of claim 10 , wherein the article is selected from a computer housing, a cell phone, a pager, a camera housing, a video game, a calculator, a wireless car entry device, an automotive part, a filter housing, a luggage cart, and an office chair.
12. The article of manufacture of claim 10 , wherein the article is a camera housing.
13. A method of reducing an amount of delamination of a molded article having a coating layer comprising the step of molding an article containing the composition of claim 1 ; and applying a coating layer to the molded article.
14. The method of claim 13 , wherein the coating layer comprises paint.
15. An article of manufacture comprising a molded article comprising:
a) from 10 to 25% by weight of polycarbonate;
b) from 60 to 75% by weight of a polysiloxane block co-polycarbonate wherein the polysiloxane block co-polycarbonate has a polysiloxane block content of 6% by weight or less;
c) from 5 to 15% by weight of an electromagnetic shielding agent; and
d) from 0.11 to 10% by weight of at least one additive selected from a pigment, a processing additive or a combination including at least one of the foregoing additives;
wherein the molded article further comprises a single coating layer and wherein the molded article has an EMI shielding effectiveness of at least 10 decibels measured according to ASTM D4935.
16. The article of manufacture of claim 15 , wherein the article is selected from a computer housing, a cell phone, a pager, a camera housing, a video game, a calculator, a wireless car entry device, an automotive part, a filter housing, a luggage cart, and an office chair.
17. The article of manufacture of claim 15 , wherein the article is a camera housing.
18. The article of manufacture of claim 15 , wherein the coating layer comprises paint.
19. A method of reducing an amount of delamination of a molded article having a coating layer comprising the step of molding an article containing the composition of claim 9 ; and applying a coating layer to the molded article.
20. The method of claim 19 , wherein the coating layer comprises paint.