Multilayer polyester film for ready meals
Coextruded, biaxially oriented multilayer films comprising a base layer comprising a polyester having an intrinsic viscosity greater than 0.75 dl/g and a heat-sealable layer directly adhered to said base layer, said heat-sealable layer comprising an amorphous polyester having a melting temperature not higher than the melting temperature of the polyester of the base layer and a thermoplastic resin characterized in that the heat-sealable layer comprises a further polyester resin are described. Also packages comprising a container, a food product and the above coextruded, biaxially oriented multilayer film are described. The packages are particularly suitable for “ready-meals” to be used in conventional oven at high temperatures.
1. A coextruded, biaxially oriented multilayer film comprising
a base layer comprising a polyester having an intrinsic viscosity measured according to ASTM method D4603-03 greater than 0.75 dl/g and a heat-sealable layer directly adhered to said base layer, said heat-sealable layer comprising
from about 25% to 70% by weight of an amorphous polyester having a melting temperature not higher than the melting temperature of the polyester of the base layer, wherein said amorphous polyester is derived from an aliphatic diol and a cycloaliphatic diol with one or more dicarboxylic acids,
from 10% to 20% by weight of a thermoplastic resin, wherein the thermoplastic resin comprises at least one member selected from the group consisting of polyamide, polystyrene, ionomer resin, ethylene/unsaturated carboxylic acid copolymer, ethylene/unsaturated ester copolymer, ethylene/propylene copolymer, and ethylene/cyclic olefin copolymer; and
from 20% to 60% by weight of a further polyester, which is different from the first amorphous polyester, wherein the further polyester resin comprises at least one further polyester resin selected from those derived from one or more aliphatic diols and an aromatic dicarboylic acid and it is characterized by a melting point higher than 240° C.
the multilayer film having a free shrink of less than 10% at temperature below 140° C. measured according to ASTM D2732.
2. A film according to claim 1 wherein the amorphous polyester in the heat-sealable layer is derived from an aliphatic diol and a cycloaliphatic diol with an aromatic dicarboxylic acid.
3. A film according to claim 2 wherein the amorphous polyester is a co-polyester of terephthalic acid with an aliphatic diol and a cycloaliphatic diol.
4. A film according to claim 1 wherein the amorphous polyester resin in the heat-sealable layer is the same polyester resin used in the base layer.
5. A film according to claim 1 wherein the further polyester resin is derived from one or more aliphatic diols.
6. A film according to claim 5 wherein the further polyester resin is polyethylene terephthalate.
7. A film according to claim 1 wherein the thermoplastic resin is selected among polyamides, polystyrenes, ionomers, ethylene/unsaturated carboxylic acid copolymers, ethylene/unsaturated esters copolymers, and ethylene/propylene copolymers and ethylene/cyclic olefin copolymers.
8. A film according to claim 7 wherein the thermoplastic resin is an ethylene/(meth)acrylic acid copolymer.
9. A film according to claim 1 wherein in the heat-sealable layer of the multilayer film the amount of the first amorphous polyester is from 40 to 60% by weight, the amount of the further polyester is from 25 to 50% by weight and the amount of thermoplastic resin is about 15% by weight, with respect to the total weight of the heat-sealable layer.
10. A film according to claim 1 wherein the heat-sealable layer of the multilayer film further comprises an anti-fog agent.
11. A film according to claim 1 wherein the heat-sealable layer of the multilayer film is coated with an anti-fog agent.
12. A film according to claim 10 wherein said anti-fog agent is a non-ionic surfactant.
13. A film according to claim 1 comprising an outer layer on the opposite side of the base layer to the heat-sealable layer.
14. A package comprising a container, a food product, and a lid formed of a coextruded, biaxially oriented, heat-sealable film according to claim 1 sealed onto said container.
15. The package according to claim 14 for use in conventional oven at temperatures higher than 140° C.
16. The film according to claim 3 wherein the amorphous polyester is a co-polyester of terephthalic acid with ethylene glycol and 1,4-dicyclohexanedimethanol.
17. The film according to claim 5 wherein the further polyester resin comprises a polyester derived from ethylene glycol, cyclohexandimethanol, and terephthalic acid.
18. The film according to claim 7 wherein the thermoplastic resin comprises at least one member selected from the group consisting of styrene-butadiene block copolymer, ethylene/(meth)acrylic acid copolymer, ethylene/vinyl acetate copolymer, and ethylene/norbornene copolymer.
19. The film according to claim 12 wherein said anti-fog agent is a non-ionic surfactant comprising at least one member selected from the group consisting of polyhydric alcohol fatty acid ester, ethoxylated derivative of polyhydric alcohol fatty acid ester, and ethoxylated sorbitan ester with higher fatty acids.