Grain oriented electrical steel sheet and method of producing grain oriented electrical steel sheet

1. A grain oriented electrical steel sheet having a glass coating film formed on a surface of a base metal iron portion of the steel sheet, comprising: a linearly altered portion generated in the glass coating film at one of side edges of the steel sheet, in a continuous line or in a discontinuous broken line in a direction parallel with a rolling direction of the steel sheet, and having a composition different from a composition in other portions of the glass coating film, wherein the glass coating film comprises Mg, wherein an average value R of deviation angles θa of crystal grains positioned below the linearly altered portion in a base metal iron portion of the steel sheet is 0° or more and 20° or less, when the deviation angle θa is defined as a deviation angle of a direction of an axis of easy magnetization of each crystal grain relative to the rolling direction, wherein a characteristic X-ray intensity Ia of Mg in the linearly altered portion of the glass coating film is smaller than an average value Ip of the characteristic X-ray intensity of Mg in the other portions of the glass coating film, wherein the characteristic X-ray intensity Ia of Mg in the linearly altered portion and the average value Ip of the characteristic X-ray intensity of Mg in the other portions of the glass coating film are obtained through an EPMA analysis, and the linearly altered portion is identified in the glass coating film as an Mg reduced portion whose Mg reduction ratio Ir that is a ratio of the Ia relative to the Ip is 0.3 or more and 0.95 or less, and wherein the linearly altered portion is generated only in the glass coating film and not in the base metal iron portion of the steel sheet.

2. The grain oriented electrical steel sheet according to claim 1 ,

wherein a laser beam is radiated in a direction parallel with the rolling direction onto a region at the one of the side edge regions of the steel sheet having an SiO 2 coating film formed on a surface thereof so as to generate a laser processed portion in a continuous line or in a discontinuous broken line in a depth region from an outer layer of the SiO 2 coating film toward a boundary between the SiO 2 coating film and the steel sheet,

wherein the laser processed portion in the SiO 2 coating film is altered, and

wherein the linearly altered portion is generated in the glass coating film.

3. The grain oriented electrical steel sheet according to claim 1 ,

wherein a distance WL from the one of the side edges of the steel sheet to a center with respect to the width direction of the linearly altered portion is 5 mm or more and 35 mm or less, and

wherein a width d of the linearly altered portion is 0.3 mm or more and 5.0 mm or less.

4. The grain oriented electrical steel sheet according to claim 1 ,

wherein the linearly altered portion is generated in a region of 20% or more and 100% or less of a total length in the rolling direction of the steel sheet, and the region starts from one end in the rolling direction of the steel sheet corresponding to an outermost periphery of the steel sheet when the steel sheet is wound up in a coil shape in a final annealing step.

5. A method of producing the grain oriented electrical steel sheet having a glass coating film formed on a surface thereof of claim 1 , the method comprising:

a laser processing step of radiating, onto one of side edge regions of a steel sheet having an SiO 2 coating film formed on a surface thereof, a laser beam in a direction parallel with a rolling direction of the steel sheet so as to generate a laser processed portion in a continuous line or in a discontinuous broken line;

an annealing separator coating step of coating each surface of the steel sheet with an annealing separator after the laser processing step; and

a final annealing step of finally annealing the steel sheet which is coated with the annealing separator so as to form the glass coating film on each surface of the steel sheet,

wherein the laser processed portion is generated in a depth region from an outer layer of the SiO 2 coating film toward a boundary between the SiO 2 coating film and the steel sheet,

wherein, in the final annealing step, the steel sheet is wound up in a coil shape, the steel sheet in the coil shape is placed and finally annealed with the one of the side edges thereof where the laser processed portion is directed downward, the glass coating film is generated from the SiO 2 coating film and the annealing separator, and a linearly altered portion having a composition different from a composition in other portions of the glass coating film is formed in a portion corresponding to the laser processed portion,

wherein an average value R of deviation angles θa of crystal grains positioned below the linearly altered portion in a base metal iron portion of the steel sheet is 0° or more and 20° or less, when the deviation angle θa is defined as a deviation angle of a direction of an axis of easy magnetization of each crystal grain relative to the rolling direction in the steel sheet after the final annealing step,

wherein the characteristic X-ray intensity Ia of Mg in the linearly altered portion and the average value Ip of the characteristic X-ray intensity of Mg in the other portions of the glass coating film are obtained through an EPMA analysis, and the Ia is smaller than the Ip, and the linearly altered portion is identified in the glass coating film as an Mg reduced portion whose Mg reduction ratio Ir that is a ratio of the Ia relative to the Ip is 0.3 or more and 0.95 or less.

6. The method of producing a grain oriented electrical steel sheet, according to claim 5 ,

wherein, in the laser processing step, the laser processed portion is generated in such a manner that a distance WL from the one of the side edges of the steel sheet to a center with respect to the width direction of the laser processed portion is 5 mm or more and 35 mm or less, and a width d of the laser processed portion is 0.3 mm or more and 5.0 mm or less.

7. The method of producing a grain oriented electrical steel sheet, according to claim 5 ,

wherein, in the laser processing step, the laser processed portion is generated in a region of 20% or more and 100% or less of a total length in the rolling direction of the steel sheet, and the region starts from one end in the rolling direction of the steel sheet corresponding to an outermost periphery of the steel sheet when the steel sheet is wound up in a coil shape in the final annealing step.

8. The method of producing a grain oriented electrical steel sheet, according to claim 6 ,

wherein, in the laser processing step, the laser processed portion is generated in a region of 20% or more and 100% or less of a total length in the rolling direction of the steel sheet, and the region starts from one end in the rolling direction of the steel sheet corresponding to an outermost periphery of the steel sheet when the steel sheet is wound up in a coil shape in the final annealing step.