IP Library Granted Patent US 9,530,568
Granted Patent B2
US 9,530,568 · App. 14/122,247 · Granted Dec 27, 2016

Method of manufacturing conductive polymer microparticle dispersion and method of manufacturing electrolytic capacitor containing the conductive polymer microparticle dispersion

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Quick Facts
Patent No.
US 9,530,568
App. No.
14/122,247
Granted
Dec 27, 2016
Kind
B2
Abstract

At least one monomer selected from thiophenes and their derivatives is oxidatively polymerized with an oxidizing agent in a solvent mainly composed of water in the presence of a polyanion as a dopant. This conductive polymer microparticle dispersion is manufactured by using, as the polyanion, a polystyrene sulfonic acid and/or its salt each having a Hazen color number in the range of 10 to 1000, inclusive, when the hue of a 2% aqueous solution thereof is measured by the APHA method.

Claims (8)

1. A method of manufacturing a conductive polymer microparticle dispersion, the method comprising:

preparing a polyanion which is at least one of polystyrene sulfonic acids and polystyrene sulfonates each having a Hazen color number in a range of 10 to 1000, inclusive, when a hue of a 2% aqueous solution thereof is measured by American Public Health Association method;

preparing a dispersion liquid by dispersing, in a solvent mainly composed of water, at least one monomer selected from thiophenes and derivatives thereof, and the polyanion as a dopant; and

preparing a conductive polythiophene microparticle dispersion doped with the polyanion by mixing the dispersion liquid with an oxidizing agent so as to oxidatively polymerize the at least one monomer.

2. A method of manufacturing an electrolytic capacitor, the method comprising:

impregnating a capacitor element having a positive electrode formed with a dielectric layer thereon with the conductive polymer microparticle dispersion prepared by the method of claim 1 ; and

forming a conductive polymer solid electrolyte layer between the positive electrode and a negative electrode by removing a solvent component contained in the conductive polymer microparticle dispersion.

3. The method of manufacturing a conductive polymer microparticle dispersion according to claim 1 , wherein a content of the polyanion with respect to 1 weight parts of the monomer falls within a range from 1 to 5 weight parts, inclusive, when preparing the dispersion liquid.

Assignments (3)
CORRECTIVE ASSIGNMENT TO CORRECT THE ERRONEOUSLY FILED APPLICATION NUMBERS 13/384239, 13/498734, 14/116681 AND 14/301144 PREVIOUSLY RECORDED ON REEL 034194 FRAME 0143. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Dec 24, 2020
From: PANASONIC CORPORATION
To: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
Reel/Frame 056788/0362 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 10, 2014
From: PANASONIC CORPORATION
To: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
Reel/Frame 034194/0143 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 15, 2014
From: TAKATANI, KAZUHIRO; AOYAMA, TATSUJI
To: PANASONIC CORPORATION
Reel/Frame 033309/0151 →