Lithium-ion electrochemical cells including fluorocarbon electrolyte additives
View Patent ↗Lithium-ion electrochemical cells are provided that include a positive electrode that includes a lithium metal oxide or a lithium metal phosphate, a negative electrode capable of intercalating or alloying with lithium, and an electrolyte that includes an additive. The additive includes a multifunctional anion that has the formula, X—SO 2 —R f —SO 2 —Y, wherein X and Y are, independently, either O— or R f SO 2 N—, R f is a straight or branched fluoroalkyl moiety having from 1 to 6 carbon atoms, and can, optionally, contain one or more in-chain heteroatoms, wherein R f is a straight or branched chain or cyclic fluoroalkylene having from 1 to 10 carbon atoms and can, optionally, contain one or more in-chain heteroatoms, and wherein both R f and R f have a maximum of 20% non-fluorine substituents. The provided additives can improve the performance, hydrolytic stability, and thermal stability of the provided electrochemical cells.
1. A lithium-ion electrochemical cell comprising:
a positive electrode comprising a lithium metal oxide or a lithium metal phosphate;
a negative electrode capable of intercalating lithium or alloying with lithium; and
a liquid or gel electrolyte comprising a lithium electrolyte salt and an additive, wherein the additive includes a multifunctional anion that has the formula:
− OSO 2 (CF 2 ) n SO 2 O − ,
where n=1-10, and
wherein the additive is present the electrolyte in an amount of from 0.01 to 3 weight percent, based on the total weight of the electrolyte.
2. A lithium-ion electrochemical cell according to claim 1 , wherein the positive electrode comprises a lithium metal oxide.
3. A lithium-ion electrochemical cell according to claim 2 , wherein the lithium metal oxide comprises a lithium mixed metal oxide that includes cobalt, nickel, manganese, or a combination thereof.
4. A lithium-ion electrochemical cell according to claim 1 , wherein the n=1-4.
5. A lithium-ion electrochemical cell according to claim 1 , wherein the additive is present in an amount of from about 0.1 weight percent to about 1.0 weight percent of the total weight of the electrolyte.
6. A lithium-ion electrochemical cell according to claim 1 , wherein the additive includes at least one lithium ion.
7. A lithium-ion electrochemical cell according to claim 1 , further comprising a charge-carrying medium and an electrolyte salt.
8. A lithium-ion electrochemical cell according to claim 7 , wherein the charge-carrying medium comprises an organic carbonate.
9. A lithium-ion electrochemical cell according to claim 8 , wherein the organic carbonate comprises ethylene carbonate, dimethyl carbonate, diethyl carbonate, ethyl methyl carbonate, vinylene carbonate, 2-fluoroethylene carbonate, or a combination thereof.
10. A lithium-ion electrochemical cell according to claim 9 , wherein the organic carbonate comprises vinylene carbonate.
11. A lithium-ion electrochemical cell according to claim 7 , wherein the electrolyte salt is selected from LiPF 6 , LiBF 4 , LiClO 4 , lithium bis(oxalato)borate, LiN(SO 2 CF 3 ) 2 , LiN(SO 2 C 2 F 5 ) 2 , LiAsF 6 , LiC(SO 2 CF 3 ) 3 , LiN(SO 2 F) 2 , LiN(SO 2 F)(SO 2 CF 3 ), LiN(SO 2 F)(SO 2 C 4 F 9 ), and combinations thereof.
12. A lithium-ion electrochemical cell according to claim 11 , wherein the electrolyte salt comprises LiPF 6 , or lithium bis(oxalate)borate.
13. A lithium-ion electrochemical cell according to claim 12 , wherein the electrolyte further comprises vinylene carbonate.
14. A lithium-ion electrochemical cell according to claim 1 , wherein the additive is perfluorinated.
15. A method of stabilizing a lithium-ion electrochemical cell comprising:
providing a lithium-ion electrochemical cell having a lithium metal oxide positive electrode or a lithium metal phosphate positive electrode, a negative electrode capable of intercalating or alloying with lithium, and a liquid electrolyte comprising a lithium electrolyte salt,
adding a multifunctional anion that has the formula:
− OSO 2 (CF 2 ) n SO 2 O − ,
where n=1-10, and
wherein the multifunctional anion is present the electrolyte in an amount of from 0.01 to 3 weight percent, based on the total weight of the electrolyte.