Method for producing inorganic substance powder highly-oriented thin film sheet
The problem addressed by the invention lies in providing a method for producing an inorganic substance powder highly-oriented thin film sheet with which it is possible to produce a sheet of uniform thickness while preventing the generation of impurities, improving sheet surface properties, adjusting apparent specific gravity, and the like. The method for producing a thin film sheet comprises a step for preparing a predetermined inorganic substance powder, thermoplastic resin, and auxiliary agent, a step for exposing the starting materials mixed at a predetermined mixture ratio to high shear stress while kneading, a step for feeding the kneaded starting materials to a T die-type extrusion molding device and molding a sheet, and a step for adjusting the apparent gravity as desired by stretching under predetermined conditions.
1. A method for producing an inorganic substance powder highly-blended thin film sheet that blends and kneads inorganic substance powder, thermoplastic resin and an auxiliary agent at predetermined blending rates, molds and then draws to finish into a thin film sheet, the method comprising:
a step of preparing the inorganic substance powder, the thermoplastic resin and the auxiliary agent, wherein the inorganic substance powder has an average particle size of 0.5 to 15 gm and is free of particles with a particle size of at least 50 μm;
a step of molding an inorganic substance powder highly-blended thin film sheet intermediate body by setting a weight ratio of the inorganic substance powder to the thermoplastic resin to 60:40 to 82:18, blending the auxiliary agent at 0.05% by weight to 4.0% by weight based on the total amount of the inorganic substance powder and the thermoplastic resin being 100% by weight and charging as starting materials into an extrusion molding machine equipped with twin screws, thereby causing high shearing stress to act on and knead the starting materials, extruding by way of a T die system by pushing the starting materials thus kneaded through a die, immediately followed by causing to contact a roll that is 50° C. or higher and molding; and
a step of performing longitudinal drawing and/or horizontal drawing so that the inorganic substance powder highly-blended thin film sheet after drawing has a desired apparent specific gravity, by controlling drawing ratios in the longitudinal direction and horizontal direction both to 1.1 times to 3.0 times,
wherein the thermoplastic resin is selected so as to be able to cause the apparent specific gravity of the inorganic substance powder highly-blended thin film sheet to decrease to 0.55 to 1.40 when establishing drawing ratios of 1.1 times to 3.0 times, and
wherein the desired apparent specific gravity is adjusted to the range of 0.55 to 1.40 to be white and opaque by selecting the thermoplastic resin in the above-mentioned way in the step of performing longitudinal and/or horizontal drawing.
2. The method for producing according to claim 1 , wherein the draw ratio is 1.1 times to 2.5 times for both draw ratios in the longitudinal direction and horizontal direction.
3. The method for producing according to claim 1 , wherein the desired apparent specific gravity is in the range of 0.55 to 1.25.
4. The method for producing according to claim 1 , wherein the thermoplastic resin is at least one type of resin selected from the group consisting of polyethylene, polypropylene, polystyrene and polyethylene terephthalate.
5. The method for producing according to claim 1 , wherein the thermoplastic resin is a polyethylene resin in which at least 60% by weight of the polyethylene resin is a high-density polyethylene resin having a melt mass flow rate of 0.02 to 1.2 g/10 min.
6. The method for producing according to claim 1 , wherein the thermoplastic resin consists of high-density polyethylene resin, and 50% by weight to 100% by weight of the high-density polyethylene resin has a melt mass flow rate of 0.02 to 0.5 g/10 min, and the remainder of the high-density polyethylene resin has a melt mass flow rate of 0.5 to 1.2 g/10 min.
7. The method for producing according to claim 1 , wherein the inorganic substance powder is at least one type of inorganic substance powder selected from the group consisting of calcium carbonate, clay, silica, titanium oxide, talc, kaolin and aluminum hydroxide.
8. The method for producing according to claim 1 , wherein calendar processing is performed on the inorganic substance powder highly-blended thin film sheet in order to improve smoothness.