Method for producing carbon-fiber-precursor acrylic fiber bundle
View Patent ↗A steam-drawing apparatus has supply roll 1 that transfers carbon-fiber-precursor acrylic fiber bundle (T) in a transfer direction of fiber bundle (T); fiber-opening device 2 for opening fiber bundle (T); width control device 3 for controlling the width of fiber bundle (T); steam box 4 to provide steam for heating fiber bundle (T) to a temperature that allows fiber bundle (T) to be drawn; and haul-off roll 5 that transfers fiber bundle (T) at a speed faster than that of supply roll 1 . Using width control device 3 provided at a position between supply roll 1 and steam box 4 , the width of fiber bundle (T) after passing through width control device 3 is set to be 65˜110% of the width of fiber bundle (T) before entering the supply roll. The present invention proposes a method for producing a carbon-fiber-precursor acrylic fiber bundle using such a steam-drawing apparatus capable of conducting a high-speed drawing process of carbon-fiber-precursor acrylic fiber bundles at a high draw rate with stable results.
1. A method for producing a carbon-fiber-precursor acrylic fiber bundle, the method comprising:
opening a carbon-fiber-precursor acrylic fiber bundle using a fiber-opening device by jet-spraying fluid from a fluid jet-spray nozzle; and
introducing the carbon-fiber-precursor acrylic fiber bundle into a steam box for heating,
wherein
a gas is used as the jet-sprayed fluid from the fluid jet-spray nozzle,
a flow rate of the gas is at least 7 NL/min but at most 16 NL/min per 1000 dtex, and
a flow speed of the gas is at least 130 m/sec but at most 350 m/sec so that the fluid penetrates through the carbon-fiber precursor acrylic fiber bundle, and
wherein by controlling a width of the carbon-fiber-precursor acrylic fiber bundle via a width control device positioned after the fiber opening device, a width of the carbon-fiber-precursor acrylic fiber bundle immediately after the fiber bundle passes through the width control device is set at 65 to 110% of a width of the fiber bundle immediately before the fiber bundle enters a supply roll, and then the carbon-fiber-precursor acrylic fiber bundle enters the steam box.
2. The method according to claim 1 , wherein
a nozzle aperture of the fluid jet-spray nozzle is shaped rectangular to be long in a width direction of the carbon-fiber-precursor acrylic fiber bundle, and
a ratio of a width of the nozzle aperture of the fluid jet-spray nozzle W 1 to a width of the fiber bundle on a roll positioned immediately before the fiber-opening device W 2 is at least 1.2 but at most 2.0.
3. The method according to claim 1 , wherein a wrap angle of the carbon-fiber-precursor acrylic fiber bundle to rolls positioned immediately before and after the fiber-opening device is set to be at least 90 degrees but at most 200 degrees.
4. The method according to claim 1 , wherein rolls positioned before and after the opening device have a diameter of at least 300 mm but at most 600 mm.
5. The method according to claim 1 , wherein the fiber-opening device comprises a fluid impingement plate positioned in a direction at which a fluid is jet-sprayed from the fluid jet-spray nozzle.
6. The method according to claim 1 ,
wherein the width control device is a grooved roll which has grooves formed in a circumferential direction and is positioned at least 50 mm but at most 1000 mm away from the fiber-opening device in a fiber transfer direction;
the grooves which make contact with both end portions in a width direction of the carbon-fiber-precursor acrylic fiber bundle are shaped to be a cross-sectional part of an arc or ellipse.
7. The method according to claim 6 , wherein after passing through the width control device, the carbon-fiber-precursor acrylic fiber bundle is heated by a hot roll to have a temperature of 80˜160° C. before said introducing.
8. The method according to claim 6 , wherein the grooved roll is a rotating roll.
9. The method according to claim 6 , wherein a flat roll is positioned between the fiber-opening device and the width control device.
10. The method according to claim 1 , wherein the flow rate of the gas is at least 10 NL/min but at most 14 NL/min per 1000 dtex.
11. The method according to claim 1 , wherein the flow speed of the gas is at least 150 m/sec but at most 320 m/sec.
12. The method according to claim 1 , wherein the flow speed of the gas is at least 130 m/sec but at most 230 m/sec.
13. The method according to claim 1 , wherein the gas is air.
14. The method according to claim 1 , wherein the width control device is a rotary driver roll, free roll or fixed roll with grooves formed parallel to a circumferential direction, or a guide with grooves formed thereon.
15. The method according to claim 1 , wherein steam is supplied to the steam box, wherein the steam is set to a temperature of 120 to 167° C.
16. The method according to claim 1 , wherein the acrylic fiber is composed of an acrylonitile-based homopolymer or an acrylonitrile-based copolymer.
17. The method according to claim 1 , wherein the acrylic fiber is composed of acrylonitrile units and methacrylic acid units.