IP Library Granted Patent US 9,994,003
Granted Patent B2
US 9,994,003 · App. 14/128,100 · Granted Jun 12, 2018

Multi-layer cast film

Inventors: Joachim Fiebig (St. Marien, AT); Kristin Reichelt (Neuhofen/Krems, AT)
Assignee: Borealis AG
B32B27/08B29C47/0021B29C47/065B32B27/32C08L23/142B32B2439/70Y10T428/24942Y10T428/24975Y10T428/2804Y10T428/2826
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Quick Facts
Patent No.
US 9,994,003
App. No.
14/128,100
Granted
Jun 12, 2018
Kind
B2
Abstract

A multi-layer polymer film comprising a core layer and a sealing layer, said sealing layer comprises a propylene copolymer composition, said propylene copolymer composition—has a comonomer content in the range of 3.0 to 8.0 wt.-%, the comonomers are C 5 to C 12 α-olefins, —comprises a polypropylene (A) and a polypropylene (B) in the weight ratio [(A)/(B)] of 20/80 to 80/20, wherein—said polypropylene (A) has a comonomer content of equal or below 4.0 wt.-%, the comonomers are C 5 to C 12 α-olefins, and—said propylene copolymer (B) has a comonomer content of 4.0 to 20.0 wt.-%, the comonomers are C 5 to C 12 α-olefins.

Claims (37)

1. A multi-layer polymer film comprising:

(a) a core layer (CL) being selected from the group consisting of polyvinyl alcohols, polyacrylates, polyamides, poly(ethylene terephthalate), polyolefins (PO) and mixtures thereof, and

(b) a sealing layer (SL), said sealing layer (SL) comprises a propylene copolymer composition (P), said propylene copolymer composition (P);

(c1) has a comonomer content in the range 3.0 to 8.0 wt. %, the comonomer is C 6 α-olefin,

(c2) comprises a polypropylene (A) and a polypropylene (B) in the weight ratio [(A)/(B)] of 35/65 to 50/50, wherein

said polypropylene (A) is a propylene homopolymer (H-A) or a propylene copolymer (C-A) having a comonomer content of below 4.0 wt. %, the comonomer is C 6 α-olefin, and

said propylene copolymer (B) has a comonomer content of 4.0 to 20.0 wt. %, the comonomer is C 6 α-olefin,

(c3) fulfills the ratio

MFR( A )/MFR( P )<1.0

wherein MFR(A) is the melt flow rate MFR 2 (230° C.) [g/10 min] measured according to ISO 1133 of the polypropylene (A), MFR(P) is the melt flow rate MFR 2 (230° C.) [g/10 min] measured according to ISO 1133 of the propylene copolymer composition (P),

(c4) has a xylene soluble content (XCS) determined at 25° C. according to ISO 16152 in the range of below 16.0 wt. %

(c5) has a melting temperature Tm determined by differential scanning calorimetry (DSC) of at least 135° C.,

(c6) has a heat sealing initiation temperature (SIT) of equal or below 115° C., and

(c7) is free of any elastomeric copolymer component, and wherein the multilayer polymer film is cast and not subjected to a stretching step.

2. A multilayer polymer film according to claim 1 , wherein the multi-layer polymer film is unoriented.

3. A multi-layer polymer film according to claim 1 , wherein the sealing layer (SL) and/or the propylene copolymer composition (P) has/have:

(a) a molecular weight distribution (MWD) measured by gel permeation chromatography (GPC) of at least 2.5, and/or

(b) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 2.0 to 50.0 g/10 min.

4. A multi-layer polymer film according to claim 1 , wherein:

com (P)-com (A) is at least 1.0 wherein com (A) is the comonomer content of the polypropylene (A) given in weight percent [wt. %], com (P) is the comonomer content of the propylene copolymer composition (P) given in weight percent [wt. %].

5. A multi-layer polymer film according to claim 1 , wherein the sealing layer (SL) and/or the propylene copolymer composition (P) fulfill(s) the equation (1):

Tm −SIT≥22° C.  (1)

wherein Tm is the melting temperature of the sealing layer (SL) and/or of the propylene copolymer composition (P) determined by differential scanning calorimetry (DSC) and given in centigrade [° C.],

SIT is the heat sealing initiation temperature (SIT) given in centigrade [° C.] of the sealing layer (SL) and/or of the propylene copolymer composition (P).

6. A multi-layer polymer film according to claim 1 , wherein the polypropylene (A) of the propylene copolymer composition (P):

(a) is a propylene copolymer (C-A) with a comonomer content in the range of 0.5 to below 4.0 wt. %, and/or

(b) has a melt flow rate MFR, (230° C.) measured according to ISO 1133 of at least 1.5 g/10 min, and/or

(c) has a xylene soluble content (XCS) of below 2.5 wt. %.

7. A multi-layer polymer film according to claim 1 , wherein said core layer (CL) comprises a propylene homopolymer.

8. A multi-layer polymer film according to claim 1 , wherein said core layer (CL) is a polypropylene (PP) or a propylene homopolymer, having:

(a) a melt flow rate MFR, (230° C.) measured according to ISO 1133 in the range of 1.0 to 15.0 g/10 min, and/or

(b) a melting temperature Tm determined by differential scanning calorimetry (DSC) of at least 155° C.

9. A multi-layer polymer film according to claim 1 , wherein:

(a) core layer (CL) has a thickness in the range of 20 to 100 μm, and/or

(b) the sealing layer (SL) has a thickness in the range of 2 to 15 μm.

10. A multi-layer polymer film according to claim 1 , wherein said multi-layer polymer film comprises three layers, namely a core layer (CL), a sealing layer (SL) and at least one of (a) an outer layer (OL) being a polyolefin (PO), or (b) a further sealing layer (SL), (c) a metal layer (ML);

wherein the multi-layer polymer film has the stacking order: (a1) sealing layer (SL)-core layer (CL)-outer layer (OL); or (b1) sealing layer (SL)-core layer (CL)-sealing layer (SL); or (c1) sealing layer (SL)-core layer (CL)-a metal layer (ML).

Assignments (2)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 20, 2013
From: FIEBIG, JOACHIM; REICHELT, KRISTIN
To: BOREALIS AG
Reel/Frame 031827/0501 →
Priority Claims (1)
EP 11171473 · Jun 27, 2011 · regional
Continuity (1)
Related Publication 20140134413A1 · May 15, 2014