STABILIZED NANOCRYSTALS
Fluorescent semiconductor nanocrystals and quantum dots having an inorganic coating on the outermost surface of the nanocrystal are described herein as well as methods for preparing and using such nanocrystals and quantum dots. Devices in which such nanocrystals and quantum dots are used are also described.
1 . A nanoparticle comprising:
1 . a semiconductor nanocrystal defining an outermost surface; and
an inorganic coating substantially covering the outermost surface of the semiconductor nanocrystal, said inorganic coating comprising less than about 30% organic components.
2 . The nanoparticle of claim 1 , wherein the inorganic coating comprises silicon dioxide, silicon monoxide, silicon nitride, zirconium oxide, tantalum oxide, lanthanum oxide, cerium oxide, hafnium oxide, or a combination thereof.
3 . The nanoparticle of claim 1 , wherein the inorganic coating comprises silicon dioxide.
4 . The nanoparticle of claim 1 , wherein the inorganic coating directly contacts the outermost surface of the semiconductor nanocrystal.
5 . The nanoparticle of claim 1 , wherein the inorganic coating forms a passivation layer on the outermost surface of the semiconductor nanocrystal.
6 . The nanoparticle of claim 1 , wherein the inorganic coating is substantially free of organic components.
7 . The nanoparticle of claim 1 , wherein the inorganic coating comprises less than about 20% organic components.
8 . The nanoparticle of claim 1 , wherein the inorganic coating comprises less than about 10% organic components.
9 . The nanoparticle of claim 1 , wherein the inorganic coating comprises less than about 5% organic components.
10 . The nanoparticle of claim 1 , wherein the inorganic coating comprises less than about 1% organic components.
11 . The nanoparticle of claim 1 , wherein the semiconductor nanocrystal comprises a mean particle diameter of from about 1 nm to about 500 nm.
12 . The nanocrystal of claim 1 , wherein the semiconductor nanocrystal comprises a mean particle diameter of from about 1 nm to about 100 nm.
13 . The nanoparticle of claim 1 , wherein the semiconductor nanocrystal comprises a mean particle diameter of from about 5 nm to about 15 nm.
14 . The nanoparticle of claim 1 , wherein the semiconductor nanocrystal comprises a core nanocrystal.
15 . The nanoparticle of claim 1 , wherein the semiconductor nanocrystal comprises a core-shell nanocrystal.
16 . The nanoparticle of claim 1 , wherein the semiconductor nanocrystal comprises an alloy-gradient nanocrystal.
17 . The nanoparticle of claim 16 , wherein the alloy-gradient nanocrystal is homogenous.
18 . The nanoparticle of claim 16 , wherein the alloy-gradient nanocrystal is non-homogeneous.
19 . The nanoparticle of claim 16 , wherein the alloy-gradient nanocrystal comprises at least one Group II element and two or more different Group VI elements.
20 . The nanoparticle of claim 1 , further comprising at least one secondary inorganic passivation material.
21 . The nanoparticle of claim 20 , wherein the secondary inorganic passivation material comprises aluminum oxide (Al 2 O 3 ).
22 . A powder comprising a plurality of the nanoparticles of claim 1 .
23 . An optoelectronic device comprising at least one nanoparticle of claim 1 .
24 . An light emitting device (LED) comprising at least one nanoparticle of claim 1 .
25 . A method for preparing a nanoparticle comprising:
providing a suspension of nanocrystals in pyridine; and
adding an inorganic coating material to the suspension of nanocrystals in pyridine suspension.
26 . The method of claim 25 , wherein the inorganic coating comprises silicon dioxide, silicon monoxide, silicon nitride, zirconium oxide, tantalum oxide, lanthanum oxide, cerium oxide, hafnium oxide, or a combination thereof.
27 . The method of claim 25 , wherein the inorganic coating comprises silicon dioxide.
28 . The method of claim 25 , further comprising contacting the outermost surface of the semiconductor nanocrystal with the inorganic coating.
29 . The method of claim 25 , further comprising forming a passivation layer on the outermost surface of the semiconductor nanocrystal with the inorganic coating.
30 . The method of claim 25 , wherein the inorganic coating is substantially free of organic components.