IP Library Patent Application 14128240
Patent Application
App. No. 14/128,240

BINDER FOR ELECTRODE OF ELECTROCHEMICAL ELEMENT, COMPOSITION FOR ELECTRODE OF ELECTROCHEMICAL ELEMENT, ELECTRODE OF ELECTROCHEMICAL ELEMENT AND ELECTROCHEMICAL ELEMENT

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Quick Facts
Patent No.
US None
App. No.
14/128,240
Abstract

The invention relates to a binder for an electrode of an electrochemical element. The binder is a polymer having an N-vinyl formamide unit, which suppresses the decline of battery performances due to deterioration of binding property and increase of internal resistance of the battery and improves the battery performance.

Claims (27)

1 .- 9 . (canceled)

10 . A binder for an electrode of an electrochemical element, wherein the binder is a polymer having an N-vinyl formamide unit.

11 . The binder for an electrode of an electrochemical element of claim 10 , wherein the content of the N-vinyl formamide unit in the polymer is 10 mol % to 100 mol %.

12 . The binder for an electrode of an electrochemical element of claim 10 , wherein the binder is water-soluble.

13 . The binder for an electrode of an electrochemical element of claim 10 , wherein the content of the N-vinyl formamide unit in the polymer is 50 mol % to 100 mol %.

14 . The binder for an electrode of an electrochemical element of claim 10 , wherein the viscosity average molecular weight of the polymer is 10,000 to 10 million.

15 . The binder for an electrode of an electrochemical element of claim 10 , wherein the viscosity average molecular weight of the polymer is 10,000 to 8 million.

16 . The binder for an electrode of an electrochemical element of claim 10 , wherein the viscosity average molecular weight of the polymer is 50,000 to 5 million.

17 . The binder for an electrode of an electrochemical element of claim 10 , wherein the oxidation current value obtained with the cyclic voltammetry of Condition I below is 2 mA/g or less;

<Condition I>

using a three-electrode electrolytic cell of the following specification, the current value of the first cycle is determined with a scan speed of 1 mV/s and a scan range of 3.5 V to 5 V; the oxidation current value is obtained by dividing the current value at a voltage value of 4.8 V by the mass of a working electrode;

{Specification of Three-Electrode Electrolytic Cell}

working electrode: an electrode of a mixture layer containing 1 part by mass of a binder for an electrode and 1 part by mass of acetylene black is disposed between an aluminum foil and an aluminum mesh;

reference electrode: a lithium foil;

counter electrode: a lithium foil;

electrolyte solution: 1 mol/L of a hexafluorophosphate lithium solution (solvent: ethylene carbonate/diethyl carbonate=1/2 (volume ratio)).

18 . The binder for an electrode of an electrochemical element of claim 10 , wherein the reduction current value obtained with the cyclic voltammetry of Condition II below is 5 mA/g or less;

<Condition II>

using a three-electrode electrolytic cell of the following specification, the current value of the first cycle is determined with a scan speed of 1 mV/s and a scan range of 3 V to 0 V; the reduction current value is obtained by dividing a current value at a voltage value of 0.5 V by the mass of a working electrode;

{Specification of Three-Electrode Electrolytic Cell}

working electrode: an electrode of a mixture layer containing 1 part by mass of a binder for an electrode and 1 part by mass of acetylene black is disposed between an aluminum foil and an aluminum mesh;

reference electrode: a lithium foil;

counter electrode: a lithium foil;

electrolyte solution: 1 mol/L of a hexafluorophosphate lithium solution (solvent: ethylene carbonate/diethyl carbonate=1/2 (volume ratio)).

19 . A composition for an electrode of an electrochemical element, wherein the composition contains the binder for an electrode of an electrochemical element of claim 10 .

20 . An electrode for an electrochemical element, including a current collector and a mixture layer disposed on the current collector, wherein the mixture layer contains the composition for an electrode of an electrochemical element of claim 19 and an electrode active material.

21 . An electrochemical element, including the electrode for an electrochemical element of claim 20 .

Assignments (2)
MERGER Recorded Jun 28, 2017
From: MITSUBISHI RAYON CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043029/0663 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 23, 2014
From: OKADA, HARUKI; FUJIKAWA, DAISUKE; NODONO, MITSUFUMI; MOMOSE, FUMINO; SHIMONAKA, AYAKO; ITOU, MASAKAZU; ISHII, AKIHIRO; MOMOSE, HIKARU
To: MITSUBISHI RAYON CO., LTD.
Reel/Frame 032024/0825 →