Lithium ion batteries using discrete carbon nanotubes, methods for production thereof and products obtained therefrom
View Patent ↗Compositions, and methods of obtaining them, useful for lithium ion batteries comprising discrete oxidized carbon nanotubes having attached to their surface lithium ion active materials in the form of nanometer sized crystals or layers. The composition can further comprise graphene or oxygenated graphene.
1. A composition useful for lithium ion batteries comprising:
discrete carbon nanotubes having crystals or layers of lithium ion active material attached to their surface, wherein the discrete carbon nanotubes have an aspect ratio of 10 to 500 and oxidation levels from 1% to 15% by weight of the carbon nanotube.
2. The composition of claim 1 , wherein the crystals or layers of lithium ion active material comprise tin, silicon, copper, antimony, aluminum, germanium, titanium, or mixtures thereof.
3. The composition of claim 1 , further comprising graphene or oxygenated graphene.
4. The composition of claim 3 , wherein the weight ratio of graphene to carbon nanotube is in the range of 0.1:99.9 to 99.9:0.1.
5. The composition of claim 1 , wherein the carbon nanotubes are present in a weight percentage of 0.1% to 10% by weight of the lithium ion active material.
6. The composition of claim 1 , comprising oxidized carbon nanotubes having crystals or layers of lithium ion active materials attached to their surface, wherein the carbon nanotubes are uniformly dispersed without clustering on a dimension scale less than 1 micrometer.
7. The composition of claim 1 , comprising uniformly dispersible oxidized carbon nanotubes having crystals or layers of lithium ion active materials attached to their surface.
8. The composition of claim 7 , wherein the crystals or layers of lithium ion active materials are chemically attached to the surface of the dispersible oxidized carbon nanotubes.