Ammonia gas generator and method for producing ammonia in order to reduce nitrogen oxides in exhaust gases
The invention relates to an ammonia gas generator for producing ammonia from an ammonia precursor substance as well as the use thereof in exhaust after treatment systems. The invention further relates to a method for producing ammonia gas to reduce nitrogen oxides in exhaust gases, in particular combustion gases from internal combustion engines such as diesel engines.
1. An ammonia gas generator for generating ammonia gas from a solution of an ammonia precursor substance, comprising:
a catalyst unit, which comprises a catalyst for decomposing and/or hydrolysing ammonia precursor substances into ammonia gas and a mixing chamber upstream from the catalyst in a flow direction, the catalyst being of a catalyst volume V Kat and the mixing chamber being of a mixing chamber volume V Misch ;
an injection device for introducing the solution of the ammonia precursor substance into the mixing chamber; and,
an outlet for the ammonia gas that is generated,
the ammonia gas generator comprising an inlet for a carrier gas which generates a tangential carrier gas stream with respect to the solution of the ammonia precursor substance injected into the mixing chamber, wherein the catalyst unit comprises at least one hydrolysis catalyst, wherein the at least one hydrolysis catalyst is either:
(1) a hydrolysis catalyst that is divided in at least two parts, wherein a first of the at least two parts in the flow direction is in the form of a heated catalyst heated by a heater and wherein a second of the at least two parts in the flow direction is in the form of an unheated catalyst; or
(2) two hydrolysis catalysts arranged one behind the other, a first of the two hydrolysis catalysts being a heated catalyst heated by a heater and a second of the two hydrolysis catalysts being an unheated catalyst.
2. The ammonia gas generator of claim 1 , wherein the catalyst unit is in the form of a cylinder.
3. The ammonia gas generator of claim 1 , wherein a ratio of a diameter D of the catalyst to a length L of the catalyst is 1:3.
4. The ammonia gas generator of claim 1 , wherein the injection device comprises a nozzle which comprises a first number of nozzle openings for introducing the solution of the ammonia precursor substance into the catalyst unit, wherein the first number of nozzle openings are annularly surrounded by a second number of nozzle openings for introducing an atomisation gas into the catalyst unit.
5. The ammonia gas generator of claim 1 , wherein the catalyst is a hydrolysis catalyst having a catalyst cell count of at least 100 cpsi to at most 400 cpsi catalyst cells per end face of the hydrolysis catalyst.
6. The ammonia gas generator of claim 1 , wherein the catalyst comprises a catalytically active coating which is impregnated with at least one of gold and palladium.
7. The ammonia gas generator of claim 1 , wherein the heater comprises at least one of a direct electrical resistance heater and a jacket heater.
8. The ammonia gas generator of claim 1 , wherein the catalyst unit comprises at least one thermal insulation layer of microporous cladding material.
9. The ammonia gas generator of claim 1 , wherein the second part of the at least two parts of the hydrolysis catalyst is followed in the flow direction by a third part, wherein the third part is an unheated catalyst having a mixer structure.
10. A method for generating ammonia as from a solution of an ammonia precursor substance by means of an ammonia gas generator comprising:
a catalyst unit, which comprises a catalyst for decomposing and/or hydrolysing ammonia precursor substances into ammonia gas and a mixing chamber upstream from the catalyst in a flow direction, the catalyst being of a catalyst volume V Kat and the mixing chamber being of a mixing chamber volume V Misch ;
an injection device for introducing the solution of the ammonia precursor substance into the mixing chamber; and,
an outlet for the ammonia gas that is generated, the method comprising:
introducing the solution of the ammonia precursor substance into the mixing chamber separately from a carrier gas; and
introducing the carrier gas tangentially to the solution of the ammonia precursor substance, wherein the catalyst unit comprises at least one hydrolysis catalyst, wherein the at least one hydrolysis catalyst is either:
(1) a hydrolysis catalyst that is divided in at least two parts, wherein a first of the at least two parts in the flow direction is in the form of a heated catalyst heated by a heater and a second of the at least two parts in the flow direction is in the form of an unheated catalyst; or
(2) two hydrolysis catalysts arranged one behind the other, a first of the two hydrolysis catalysts being a heated catalyst heated by a heater and a second of the two hydrolysis catalysts being an unheated catalyst.
11. The method of claim 10 , wherein a partial stream of an exhaust containing less than 5% vol % percent of a total exhaust is used as the carrier gas.
12. The method of claim 10 , wherein the solution of ammonia precursor substance is sprayed from a reservoir container into the mixing chamber by a pump at a spray angle of 10 to 40° relative to a face of the catalyst unit.
13. The method of claim 10 , wherein the solution of ammonia precursor substance is applied to an end face of the catalyst in the form of droplets having a droplet diameter D 32 of less than 20 μm.
14. The method of claim 10 , wherein a volume ratio of carrier gas to atomisation air in the mixing chamber is 7:1 to 10:1.
15. The method of claim 10 , wherein the solution of ammonia precursor substance is injected at a pressure of at least 0.5 bar and atomisation air is injected at a pressure of 0.5 to 2 bar.
16. The method of claim 10 , wherein the solution of ammonia precursor substance is introduced into the catalyst unit such that a catalyst end face loading is 0.2 to 12 g/(h*cm 2 ).
17. The method of claim 10 , wherein the solution of ammonia precursor substance is sprayed into the mixing chamber perpendicular to a surface of the catalyst unit.
18. The method of claim 10 , wherein the solution of ammonia precursor substance is introduced into the mixing chamber together with the carrier gas, wherein the carrier gas and optionally an additional energy source have in total a specific enthalpy flow of H TG /m Precursor of 8000-50000 kJ/kg, where the enthalpy flow is with respect to the introduced mass flow of solution.
19. The method of claim 10 , wherein the carrier gas is a nitrogen oxide containing gas selected from the group consisting of: exhaust from industrial facilities, from combustion engines, from gas engines, from diesel engines and from petrol engines.
20. The method of claim 10 , wherein the heater comprises at least one of a direct electrical resistance heater and a jacket heater.
21. The method of claim 10 , wherein the second part of the at least two parts of the hydrolysis catalyst is followed in the flow direction by a third part, wherein the third part is an unheated catalyst having a mixer structure.
22. The method of claim 10 , wherein the solution of ammonia precursor substance is introduced into the catalyst unit such that a catalyst end face loading is 3.0 to 15 g/(h*cm 2 ).
23. A method for reducing nitrogen oxides in exhaust from industrial facilities, from combustion engines, from gas engines, from diesel engines or from petrol engines, comprising treating an exhaust from an industrial facility, a combustion engine, a gas engine, a diesel engine or a petrol engine with the ammonia gas generated by the ammonia gas generator of claim 1 .