Aluminum plated steel sheet having excellent corrosion resistance with respect to alcohol or mixed gasoline of same and appearance
View Patent ↗The present invention relates to aluminum plated steel sheet which does not require coating after plating and is high in production flexibility enabling application of conventional production processes as they are or exhibits excellent corrosion resistance to flex fuels and further is excellent in appearance and to fuel tanks characterized by being produced using the steel sheet. The Si, Mg, Ca, and Ti ingredients in the aluminum plating layer are defined and the cooling method after hot dip aluminum coating is controlled to make Mg 2 Si particles with a long axis of 10 μm or less and an aspect ratio of 1 to 3 finely disperse in the plating layer. Due to the Mg 2 Si particles, it is possible to give an excellent corrosion resistance to flex fuels and suppress the deterioration in appearance due to MgO.
1. Aluminum plated steel sheet which is excellent in corrosion resistance and appearance, comprising steel sheet on at least one surface of which there is a plating layer consisting of, by mass %,
Si: 2% to 11%,
Mg: 3% to 9%,
Ca: 0.1% to 5%,
Ti: 0.008% to 0.05%, and
a balance of Al and unavoidable impurities,
said plating layer containing clumps of Mg 2 Si particles with a long axis of greater than 0 μm and 10 μm or less, and a ratio of a long axis and a short axis, an aspect ratio, of 1 to 3,
wherein the long axis and the aspect ratio are measured by examining the vertical cross-section of the plating layer.
2. Aluminum plated steel sheet which is excellent in corrosion resistance and appearance as set forth in claim 1 characterized by having an Al—Si—Fe-based alloy layer of a thickness of greater than 0 μm and 5 μm or less at the interface of said plating layer and said steel sheet.
3. Aluminum plated steel sheet which is excellent in corrosion resistance and appearance as set forth in claim 1 or 2 characterized in that said plating layer has a thickness of 9 to 35 μm.
4. A fuel tank which is excellent in corrosion resistance and appearance characterized by using aluminum plated steel sheet which has a plating layer consisting of, by mass %,
Si: 2% to 11%,
Mg: 3% to 9%,
Ca: 0.1% to 5%,
Ti: 0.008% to 0.05%, and
a balance of Al and unavoidable impurities,
said plating layer containing clumps of Mg 2 Si particles with a long axis of greater than 0 μm and 10 μm or less and a ratio of a long axis and a short axis, an aspect ratio, of 1 to 3,
wherein the long axis and the aspect ratio are measured by examining the vertical cross-section of the plating layer.