IP Library Granted Patent US 9,487,400
Granted Patent B2
US 9,487,400 · App. 14/136,133 · Granted Nov 8, 2016

Process to prepare a mixture of hydrogen and carbon monoxide from a liquid hydrocarbon feedstock containing a certain amount of ash

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Quick Facts
Patent No.
US 9,487,400
App. No.
14/136,133
Granted
Nov 8, 2016
Kind
B2
Abstract

A process to prepare a synthesis gas mixture comprising hydrogen and carbon monoxide from a liquid hydrocarbon feedstock containing between 0.1 and 4 wt % ash comprises performing a partial oxidation on a hydrocarbon feed using a multi-orifice burner provided with an arrangement of separate co-annular passages, wherein the hydrocarbon flows through a passage of the burner, an oxidizer gas flows through a separate passage of the burner and wherein the passage for hydrocarbon feed and the passage for oxidizer gas are separated by a passage through which a moderator gas flows and wherein the exit velocity of the moderator gas is greater than the exit velocity of the oxidizer gas.

Claims (7)

1. A process for preparing a synthesis gas mixture having a hydrogen to carbon monoxide molar ratio of greater than 1.8 from a liquid hydrocarbon feedstock containing between 0.1 and 4 wt % ash by

(aa) subjecting said feedstock to a partial oxidation and a water quench to obtain a wet synthesis gas mixture of hydrogen and carbon monoxide,

(bb) performing a water gas shift reaction on one part of the wet synthesis gas,

(cc) removing HCN and COS from a second part of the wet synthesis gas,

(dd) performing an acid gas removal step on the combined gaseous effluents of step (bb) and (cc) to remove NH3 and H2S,

wherein the desired molar ratio of hydrogen to carbon monoxide in the product gas obtained in step (dd) is controlled by selecting the ratio of wet synthesis gas which is subjected to step (bb) and to step (cc),

wherein step (aa) is performed by a process comprising performing a partial oxidation on a hydrocarbon feed using a multi-orifice burner provided with an arrangement of separate co-annular passages, wherein the hydrocarbon flows through a passage of the burner, an oxidizer gas flows through a separate passage of the burner and wherein the passage for hydrocarbon and the passage for oxidizer gas are separated by a passage through which a moderator gas flows and wherein the exit velocity of the moderator gas is greater than the exit velocity of the oxidizer gas.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 16, 2018
From: SHELL OIL COMPANY
To: AIR PRODUCTS AND CHEMICALS, INC.
Reel/Frame 045818/0028 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 6, 2014
From: DEJONG, JOHANNES CORNELIS; MARTENS, FRANCISCUS JOHANNA ARNOLDUS
To: SHELL OIL COMPANY
Reel/Frame 032832/0978 →