A coated paper with enhanced properties and/or lower cost can be obtained by using a coating that contains a binder and stanchion-encapsulated titanium dioxide. The stanchion-encapsulated titanium dioxide can provide the same or similar brightness, gloss, and/or opacity while using less titanium dioxide.
1. A coated paper comprising:
a base paper having a coating thereon,
wherein said coating comprises a binder and a stanchion-encapsulated pigment,
wherein the pigment comprises particles of titanium dioxide and having an average of 0.2 to 6 stanchions per particle of titanium dioxide and an average stanchion length is within the range of 10 to 500 nm,
wherein the average stanchion lengths of the encapsulated pigment ranges from 0.01 d to 3.5 d where “d” is the encapsulated pigment diameter,
wherein said stanchion-encapsulated pigment comprises 1-30% by weight of said coating,
wherein the stanchion-encapsulated pigment contains a polymeric encapsulating material that comprises a polymer selected from the group consisting of: polyacrylate, polymethacrylate, polyalkyl(meth)acrylate and combinations thereof,
wherein each stanchion protrudes at least two times the thickness of the encapsulating material or connects two or more particles together, and
wherein the stanchion and polymeric encapsulating material are the same material.
2. The coated paper according to claim 1 , wherein the pigment material is 40 to 60% of the weight of said stanchion-encapsulated pigment.
3. The coated paper according to claim 1 , wherein said stanchion-encapsulated titanium dioxide is present in an amount that provides titanium dioxide in the range of 2 to 10 wt % of said coating.
4. The coated paper according to claim 1 , wherein said coated paper has a brightness that is at least 99.7% the brightness of a comparative coated paper that is otherwise identical in composition and formation but which replaces the stanchion-encapsulated titanium dioxide with non-encapsulated titanium dioxide and which uses twice the amount of titanium dioxide in comparison to the amount of titanium dioxide provided by said stanchion-encapsulated titanium dioxide.
5. The coated paper according to claim 1 , wherein said coated paper has an opacity equivalent to or better as compared to a coated paper using a substantially equivalent non-encapsulated titanium dioxide.
6. The coated paper according to claim 1 , wherein equivalent or better gloss is achieved but using 75% or less of the stanchion-encapsulated pigment as compared to a coated paper using a substantially equivalent non-encapsulated titanium dioxide.
7. The coated paper according to claim 1 , wherein equivalent or higher gloss is achieved using lower calendar pressure with the paper using stanchion-encapsulated pigment as compared to a coated paper using non-encapsulated titanium dioxide.
8. The coated paper according to claim 1 , wherein the pigment is a rutile titanium dioxide and said coated paper has an Einlehner Abrasion of less than 10 mg.
9. The coated paper according to claim 1 , wherein said coated paper has an Einlehner abrasion value at least 50% less when compared to the Einlehner value of a coated paper using an equivalent amount of the same titanium dioxide which is non-encapsulated.
10. The coated paper according to claim 1 , wherein the coated paper has a Sheffield Smoothness equivalent to or better than coated paper using 2× by weight of a substantially equivalent non-encapsulated titanium dioxide.
11. The coated paper according to claim 1 , wherein said binder is selected from the group consisting of starch, a vinyl alcohol, a latex, a carboxymethylcellulose, and combinations thereof.
12. The coated paper according to claim 1 , wherein said coating further comprises at least one pigment selected from calcium carbonates, clays, and combinations thereof.
13. The coated paper according to claim 1 , wherein said coating further comprises at least one additive selected from surfactants, dispersants, lubricants, thickeners, anti-foaming agents, opacifying agents, and optical brightening agents.
14. A paper coating composition, comprising a mixture of water, a binder, and stanchion-encapsulated pigment,
wherein said stanchion-encapsulated pigment comprises 1-30% by weight of said coating,
wherein the stanchion-encapsulated pigment contains a polymeric encapsulating material that comprises a polymer selected from the group consisting of: polyacrylate, polymethacrylate, polyalkyl(meth)acrylate and combinations thereof,
wherein each stanchion protrudes at least two times the thickness of the encapsulating material or connects two or more particles together, and
wherein the stanchion and polymeric encapsulating material are the same material.
15. The coating composition according to claim 14 , wherein a pigment material in the stanchion-encapsulated pigment is titanium dioxide.
16. The coating composition according to claim 14 , further comprising at least one pigment selected from calcium carbonates, clays, and combinations thereof.
17. A paper product produced by coating a base paper with the coating composition of claim 14 , claim 15 or claim 16 .
18. The paper product according to claim 17 , wherein said paper is subjected to calendaring after said coating.
19. The paper product according to claim 17 , wherein said paper is not subjected to calendaring after said coating.
20. A paper comprising:
cellulose pulp; and
filler,
wherein the filler comprises a stanchion-encapsulated pigment,
wherein said stanchion-encapsulated pigment comprises 1-30% by weight of said coating,
wherein the pigment comprises particles of titanium dioxide and having an average of 0.2 to 6 stanchions per particle of titanium dioxide and an average stanchion length is within the range of 10 to 500 nm, and
wherein each stanchion protrudes at least two times the thickness of the encapsulating material or connects two or more particles together.
21. The paper according to claim 20 , wherein the paper at a loading level of 50% by weight or less of stanchion-encapsulated titanium dioxide as compared to a paper using a same or similar non-encapsulated titanium dioxide has an opacity which is equivalent or higher than the paper using a non-encapsulated titanium dioxide.
22. The paper according to claim 20 , wherein the paper using stanchion-encapsulated titanium dioxide at an equivalent loading level or less, has a higher brightness as compared to a paper using the same or similar titanium dioxide which is non-encapsulated.