Process for producing cathode active material for lithium ion secondary battery
To provide a process for producing a cathode active material for a lithium ion secondary battery, a cathode for a lithium ion secondary battery, and a lithium ion secondary battery. A production process which comprises contacting a lithium-containing composite oxide containing Li element and a transition metal element with a composition (1) {an aqueous solution containing cation M having at least one metal element (m)} and a composition (2) {an aqueous solution containing anion N having at least one element (n) selected from the group consisting of S, P, F and B, forming a hardly soluble salt when reacted with the cation M}, wherein the total amount A (mL/100 g) of the composition (1) and the composition (2) contacted per 100 g of the lithium-containing composite oxide is in a ratio of 0.1<A/B<5 based on the oil absorption B (mL/100 g) of the lithium-containing composite oxide.
1. A process for producing a cathode active material for a lithium ion secondary battery, comprising:
contacting a lithium-containing composite oxide comprising Li element and a transition metal element with composition (1) and composition (2); and
heating the lithium-containing composite oxide, the composition (1), and the composition (2), wherein
the total amount A (ml/100 g) of the composition (1) and the composition (2) contacted per 100 g of the lithium-containing composite oxide is in the ratio of 0.7≦A/B based on the oil absorption B (ml/100 g) of the lithium-containing composite oxide, and the contacting of the composition (1) and the composition (2) with the lithium-containing composite oxide is carried out by spraying the composition (1) and the composition (2) to the lithium-containing composite oxide, and by drying the composition (1) and the composition (2) simultaneously or alternatively with the spraying:
composition (1): an aqueous solution comprising containing cation M which comprises having at least one metal element (m) selected from the group consisting of Li, Mg, Ca, Sr, Ba, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Co, Ni, Cu, Zn, Al, In, Sn, Sb, Bi, La, Ce, Pr, Nd, Gd, Dy, Er and Yb;
composition (2): an aqueous solution comprising containing-anion N which comprises having at least one element (n) selected from the group consisting of S, P, F and B, forming a hardly soluble salt when reacted with the cation M.
2. The process according to claim 1 , wherein the metal element (m) contained in the composition (1) is Al.
3. The process according to claim 1 , wherein the anion N contained in the composition (2) is at least one anion selected from the group consisting of SO 4 2− , PO 4 3− and F − .
4. The process according to claim 1 , wherein the heating is carried out at from 250 to 700° C.
5. The process according to claim 1 , wherein the molar ratio of the metal element (m) contained in the composition (1) is within a range of from 0.001 to 0.05 based on the total amount of the transition metal element contained in the lithium-containing composite oxide.
6. The process according to claim 1 , wherein the molar ratio of the anion N contained in the composition (2) is within a range of from 0.001 to 0.05 based on the total amount of the transition metal element contained in the lithium-containing composite oxide.
7. A cathode for a lithium ion secondary battery, comprising:
a cathode active material for a lithium ion secondary battery produced by the process as defined in claim 1 ; and
a binder.
8. A lithium ion secondary battery comprising:
the cathode as defined in claim 7 ;
an anode; and
a non-aqueous electrolyte.
9. The process according to claim 1 , wherein the composition (1) further comprises a pH adjusting agent.
10. The process according to claim 1 , wherein the composition (2) further comprises a pH adjusting agent.
11. The process according to claim 1 , wherein the heating is carried out in an oxygen-containing atmosphere.
12. The process according to claim 1 , wherein the heating is carried out at a temperature of from 350 to 600° C.