Multi-layer structures prepared by layer-by-layer assembly
A protective layer can be deposited on a surface of an porous polymer separator placing on a Li-metal electrode to protect against adverse electrochemical activity in a battery. The protective layer can be a multilayered structure including graphene oxide.
1. A method of preparing a multi-layer structure on a substrate comprising:
forming a pair of bilayers on a surface of the substrate in a layer-by-layer assembly by contacting the substrate with a solution with sequential adsorption of materials in each layer,
the first bilayer including a first material and a second material, the first and second material having complementary functional groups;
the second bilayer including a third material and a fourth material, the third and fourth material having complementary functional groups; and
the pair of bilayers includes an ion-conductive polymer layer, a polyanion or polycation, and a graphene oxide barrier layer substantially free of graphene.
2. The method of claim 1 , wherein the substrate includes a membrane and preparing the multi-layer structure further comprises:
contacting the membrane with a first solution containing the first material;
contacting the membrane having the first material with a second solution containing the second material;
contacting the membrane having the first and second material with a third solution containing the third material; and
contacting the membrane having the first, second and third material with a fourth solution containing the fourth material.
3. The method of claim 2 , wherein pH of the first solution, the second solution, the third solution, and the fourth solution is adjusted for hydrogen bonding between materials in the bilayers.
4. The method of claim 2 , wherein lithium bis(oxalate)borate is dissolved in the first solution.
5. The method of claim 2 , wherein lithium bis(oxalate)borate is dissolved in the second solution.
6. The method of claim 2 , wherein lithium bis(oxalate)borate is dissolved in the third solution.
7. The method of claim 2 , wherein lithium bis(oxalate)borate is dissolved in the fourth solution.
8. The method of claim 2 , wherein the first solution includes polyethylene oxide, graphene oxide, or polyacrylic acid.
9. The method of claim 2 , wherein the second solution includes polyethylene oxide, graphene oxide, or polyacrylic acid.
10. The method of claim 2 , wherein the third solution includes polyethylene oxide, graphene oxide, or polyacrylic acid.
11. The method of claim 2 , wherein the fourth solution includes polyethylene oxide, graphene oxide, or polyacrylic acid.
12. The method of claim 1 , wherein the first material and the third material are the same.
13. The method of claim 1 , wherein the first material and the third material are different.
14. The method of claim 1 , wherein the second material and the fourth material are the same.
15. The method of claim 1 , wherein the second material and the fourth material are different.
16. The method of claim 1 , wherein the substrate includes a membrane.
17. The method of claim 16 , wherein the membrane includes polypropylene.
18. The method of claim 1 , wherein the substrate is plasma treated.
19. The method of claim 1 , wherein the substrate is glass.
20. The method of claim 1 , wherein the first material is polyethylene oxide, the second material is graphene oxide, the third material is polyethylene oxide, and the fourth material is polyacrylic acid.
21. The method of claim 20 , wherein the pair of bilayers is formed on a polypropylene membrane.