Wax dispersion formulations, method of producing same, and uses
View Patent ↗Aqueous wax dispersions useful as surface modifiers for paints, inks and coatings. More particularly, aqueous particulate wax dispersions useful as surface modifiers to provide improved properties in primers, paints, inks and other coating formulations. The dispersions are stable, substantially homogenous, have a high solids concentration at low viscosities, and comply with the applicable FDA regulations for use in food packaging applications.
1. An aqueous wax dispersion comprising:
a) water;
b) at least one particulate wax dispersed within the water, wherein the particulate wax comprises particles having an average particle size of from about 0.1 μm to about 6 μm, wherein substantially all of the wax particles have a particle size of about 20 μm or less, and wherein the particulate wax comprises from about 5% to about 45% by weight of the dispersion; and
c) from greater than 0% to about 5% by weight of a dispersing agent based on the weight of the particulate wax; which dispersing agent coats the surfaces of at least some of the wax particles; and wherein the dispersion has a viscosity of about 200 cps or less at about 25° C., and wherein there is substantially no agglomeration of the wax particles,
wherein the particulate wax has an acid number of 40 or less, and wherein the particulate wax has a saponification number of 80 or less.
2. The aqueous wax dispersion of claim 1 wherein the particulate wax has an acid number of 30 or less, and wherein the particulate wax has a saponification number of 50 or less.
3. The aqueous wax dispersion of claim 1 wherein the particulate wax has a weight average molecular weight of up to about 13,000.
4. The aqueous wax dispersion of claim 1 wherein the particulate wax comprises from about 10% by weight to about 45% by weight of the dispersion.
5. The aqueous wax dispersion of claim 1 wherein the wax comprises a polyolefin wax, oxidized polyolefin wax, Fischer-Tropsch wax, beeswax, Chinese wax, shellac wax, spermaceti wax, wool wax, bayberry wax, candelilla wax, carnauba wax, castor wax, esparto wax, Japan wax, jojoba oil wax, ouricury wax, rice bran wax, soy wax, ceresin wax, montan wax, ozocerite, peat wax, paraffin wax, a microcrystalline wax, a polyethylene wax, a polyethylene homopolymer wax, polypropylene wax, wax grade polytetrafluoroethylene, polytetrafluoroethylene-modified waxes, an alpha-olefin wax, an amide wax, a stearamide wax, or combinations thereof.
6. The aqueous wax dispersion of claim 1 wherein the particulate wax has an acid number of zero, and wherein the particulate wax has a saponification number of zero.
7. A coating composition comprising the aqueous wax dispersion of claim 1 combined with at least one coating material.
8. A coating formed from the coating composition of claim 7 .
9. The aqueous wax dispersion of claim 1 wherein the wax substantially lacks any pendant carboxy groups, hydroxyl groups, ketones, or aldehydes.
10. The aqueous wax dispersion of claim 1 wherein the wax comprises a homopolymer.
11. The aqueous wax dispersion of claim 10 wherein the homopolymer is a polyethylene homopolymer.
12. The aqueous wax dispersion of claim 1 wherein the wax has a crystallinity of about 70% to about 95% at room temperature.
13. The aqueous wax dispersion of claim 1 wherein the wax has density between about 0.95 g/cm 3 to about 1.0 g/cm 3 as determined by ASTM D-1505.
14. An aqueous wax dispersion comprising:
a) water;
b) at least one particulate wax dispersed within the water, wherein the particulate wax comprises particles having an average particle size of from about 0.1 μm to about 6 μm, wherein substantially all of the wax particles have a particle size of about 20 μm or less, and wherein the particulate wax comprises from about 5% to about 45% by weight of the dispersion; and
c) from greater than 0% to about 5% by weight of a dispersing agent based on the weight of the particulate wax; which dispersing agent coats the surfaces of at least some of the wax particles; and wherein the dispersion has a viscosity of about 200 cps or less at about 25° C., and wherein there is substantially no agglomeration of the wax particles,
wherein the wax particles have a crystallinity of from about 70% to about 95% at room temperature.