Negative-electrode active material for rechargeable lithium battery
View Patent ↗The present invention relates to a method for preparing a negative-electrode active material for rechargeable lithium battery, wherein the negative-electrode active material comprises a core comprising material capable of doping and dedoping lithium; and, a carbon layer formed on the surface of the core, wherein the carbon layer has a three dimensional porous structure comprising nanopores regularly ordered on the carbon layer with a pore wall of specific thickness placed therebetween. In some embodiments, the method comprises modifying a material capable of doping and dedoping lithium with an organic functional group, mixing the modified material with an inorganic oxide, heating the mixture, and removing the inorganic oxide to form the negative-electrode active material.
1. A method for preparing negative-electrode active material for rechargeable lithium battery, comprising:
modifying a material capable of doping and dedoping lithium with an organic functional groups;
mixing the modified material with an inorganic oxide;
heating the mixture; and
removing the inorganic oxide to form a negative-electrode active material having a core comprising the material capable of doping and dedoping lithium, and a carbon layer disposed on the surface of the core, wherein the carbon layer having a three dimensional porous structure comprising nanopores having average diameter of 100 nm to 300 nm, regularly ordered on the carbon layer with a pore wall having thickness of 40 nm to 150 nm placed therebetween.
2. The method according to claim 1 , wherein the heating step comprises:
heating the mixture to form a composite comprising the core and the carbon layer disposed on the surface of the core, wherein particles of the inorganic oxide are disposed in the carbon layer.
3. The method according to claim 1 , wherein the organic functional group is represented by C n H m (wherein, n and m are integer of 1 or more).
4. The method according to claim 1 , wherein the organic functional group is selected from the group consisting of aliphatic organic group having carbon number of from 1 to 30, cycloaliphatic organic group having carbon number of from 3 to 30, and aromatic organic group having carbon number of from 6 to 30.
5. The method according to claim 1 , wherein the inorganic oxide comprise one or more kinds of inactive inorganic oxide, selected from the group consisting of silica, alumina, titania, ceria and zirconia.
6. The method according to claim 1 , wherein the inorganic oxide is added in an amount of 10 to 80 parts by weight, based on 100 parts by weight of the material capable of doping and dedoping lithium modified with the organic functional group.
7. The method according to claim 1 , wherein the material capable of doping and dedoping lithium modified with the organic functional group is in the form of viscous gel.
8. The method according to claim 1 , wherein the step of heating is conducted under vacuum or inert atmosphere.
9. The method according to claim 1 , wherein the heating is conducted at a temperature ranging from 700° C. to 1200° C.
10. The method according to claim 1 , wherein the removal of the inorganic oxide is conducted using basic or acidic material.