Overcoat formulation for long-life electrophotographic photoconductors and method for making the same
View Patent ↗An overcoat layer and method to make an overcoated photoconductor drum of an electrophotographic image forming device using irradiation such as with electron beam (EB) or ultraviolet (UV) light is provided. The photoconductor drum is then cured using EB dose of between 10 and 100 kiloGrays (kGy), preferably between 20 and 40 kGys or UV irradiation with an exposure of between 0.1 and 2 J/cm 2 . The unique overcoat layer of the present invention is formed having a biphasic morphology comprised of a highly cured crosslinked phase and a second phase enriched in uncured material. The desired amount of uncured uncrosslinked material found in the second phase of the biphasic structure, is between 2-70 wt % range, with particularly good combination of long-life and electrical performance when present at the 5-50 wt % level, and the best performance at the 15-40 wt % level. The biphasic morphology of the overcoat layer using the method of the present invention gives rise to the good wear rates while allowing rapid transport of the electrical charge and thus fast discharge properties of the photoconductor drum.
1. A photoconductor drum, comprising:
a support element;
a charge generation layer disposed over the support element;
a charge transport layer disposed over the charge generation layer; and
an overcoat layer, disposed over the charge transport layer, comprising a curable polymerizable arylamine material, wherein the polymerizable arylamine material includes at least one pendant acrylate, methacrylate, vinyl, or styrenyl group, and wherein the overcoat layer has a biphasic overcoat structured comprised of a highly cured crosslinked phase and a second phase having an amount of uncured uncrosslinked material, between about 20% to about 40 wt %.
2. The photoconductor drum of claim 1 , further comprising of at least one of wetting agents, fillers, and leveling agents.
3. The photoconductor drum of claim 1 , wherein the polymerizable arylamine material, with at least one or more pendant acrylate, methacrylate, vinyl, or styrenyl group, comprises arylamines of one or more partial structures (I-VI):