Photoconductor overcoat having tetrafunctional radical polymerizable charge transport molecule
View Patent ↗An improved overcoat layer for an organic photoconductor drum of an electrophotographic image forming device is provided. The overcoat layer is prepared from a curable composition including a charge transport molecule containing four radical polymerizable functional groups of the general structure exemplified below: where R 1 and R 2 contain a spacer group and a radical polymerizable functional group, R 3 and R 4 are selected from the group consisting of a radical polymerizable functional group, a non-radical polymerizable functional group, and one each of a radical polymerizable functional group and a non-radial polymerizable functional group, and R 5 and R 6 contain a spacer group and a radical polymerizable functional group. The curable composition also contains at least one curing agent. The curing agent comprises a urethane resin containing six radical polymerizable functional groups. This overcoat layer improves wear resistance of the organic photoconductor drum without negatively altering the electrophotographic properties, thus protecting the organic photoconductor drum from damage and extending its service life.
1. An overcoat layer for an organic photoconductor drum, comprising a curable composition including:
about 20 to about 80 percent by weight of a charge transport molecule containing four radical polymerizable functional groups as exemplified below:
where R 1 and R 2 contain a spacer group and a radical polymerizable functional group, R 3 and R 4 are selected from the group consisting of a radical polymerizable functional group, a non-radical polymerizable functional group, and one each of a radical polymerizable functional group and a non-radial polymerizable functional group, and R 5 and R 6 contain a spacer group and a radical polymerizable functional group; and
about 20 to about 80 percent by weight of a curing agent having a urethane resin containing six radical polymerizable functional groups, wherein the radical polymerizable functional group of R 1 and R 2 is an acrylate group.
2. The overcoat layer of claim 1 , wherein the curable composition includes:
about 40 to about 60 percent by weight of a charge transport molecule containing four radical polymerizable functional groups; and
about 40 to about 60 percent by weight of the curing agent having a urethane resin containing six radical polymerizable functional groups.
3. The overcoat layer of claim 1 , wherein the spacer group of R 1 and R 2 is an unbranched alkyl group containing between 1 and about 6 carbon atoms.
4. The overcoat layer of claim 1 , wherein R 3 and R 4 are hydrogen atoms.
5. The overcoat layer of claim 1 , wherein the spacer group of R 5 and R 6 is an unbranched alkyl group containing between 1 and about 6 carbon atoms.
6. An overcoat for an organic photoconductor drum, comprising a curable composition including:
about 20 to about 80 percent by weight of a charge transport molecule containing four radical polymerizable functional groups as exemplified below:
where R 1 and R 2 contain a spacer group and a radical polymerizable functional group, R 3 and R 4 are selected from the group consisting of a radical polymerizable functional group, a non-radical polymerizable functional group, and one each of a radical polymerizable functional group and a non-radial polymerizable functional group, and R 5 and R 6 contain a spacer group and a radical polymerizable functional group; and
about 20 to about 80 percent by weight of a curing agent having a urethane resin containing six radical polymerizable functional groups, wherein the radical polymerizable functional group or R 5 and R 6 is an acrylate group.
7. The overcoat layer of claim 1 , wherein the radical polymerizable functional group of the urethane resin containing six radical polymerizable functional groups is selected from the group consisting of acrylate group, methacrylate group, styrenic group, allylic group, vinylic group, glycidyl ether group and epoxy group.
8. The overcoat layer of claim 7 , wherein the radical polymerizable functional group of the urethane resin containing six radical polymerizable functional groups is an acrylate group.
9. An organic photoconductor drum comprising:
a support element;
a charge generation layer disposed over the support element;
a charge transport layer disposed over the charge generation layer; and
an overcoat layer for an organic photoconductor drum, comprising a curable composition including a charge transport molecule containing four radical polymerizable functional groups as exemplified below:
where R 1 and R 2 contain a spacer group and a radical polymerizable functional group, R 3 and R 4 are selected from the group consisting of a radical polymerizable functional group, a non-radical polymerizable functional group, and one each of a radical polymerizable functional group and a non-radial polymerizable functional group, and R 5 and R 6 contain a spacer group and a radical polymerizable functional group wherein the spacer group of R 1 , R 2 , R 5 and R 6 is an ethyl group and the radical polymerizable functional group of R 1 , R 2 , R 5 and R 6 is an acrylate group.
10. The overcoat layer of claim 9 , wherein R 3 and R 4 are hydrogen atoms.