Golf balls having at least two core layers formed from HNP compositions
View Patent ↗The present invention is directed to golf balls consisting of a multi-layer core and a cover. The multi-layer core includes at least one layer formed from a relatively soft or low modulus HNP composition and at least one layer formed from a relatively hard or high modulus HNP composition.
1. A golf ball comprising a core and a cover, wherein the core has an overall diameter of from 1.40 inches to 1.60 inches and consists of:
(a) a center having a diameter of from 0.50 inches to 1.50 inches and a center hardness (H) of from 20 Shore C to 90 Shore C;
(b) an intermediate core layer having a surface hardness (I) of 40 Shore C or greater and formed from a first highly neutralized polymer composition; and
(c) an outer core layer having a surface hardness (S) of from 20 Shore C to 90 Shore C and formed from a second highly neutralized polymer composition;
wherein H<I and S<I;
wherein H<S, and wherein S−H=D, wherein D is an integer from 1 to 22;
wherein the material hardness of the second highly neutralized polymer composition is less than the material hardness of the first highly neutralized polymer composition; and
wherein at least one of the first highly neutralized polymer composition and the second highly neutralized polymer composition comprises:
an acid copolymer of ethylene and an α,β-unsaturated carboxylic acid, optionally including a softening monomer selected from the group consisting of alkyl acrylates and methacrylates;
a non-acid polymer selected from the group consisting of polyolefins, polyamides, polyesters, polyethers, polyurethanes, metallocene-catalyzed polymers, single-site catalyst polymerized polymers, ethylene propylene rubber, ethylene propylene diene rubber, styrenic block copolymer rubbers, alkyl acrylate rubbers, and functionalized derivatives thereof;
an organic acid or salt thereof; and
a cation source present in an amount sufficient to neutralize greater than 80% of all acid groups present in the composition.
2. A golf ball comprising a core and a cover, wherein the core has an overall diameter of from 1.40 inches to 1.60 inches and consists of:
(a) a center having a diameter of from 0.50 inches to 1.50 inches and a center hardness (H) of from 20 Shore C to 90 Shore C;
(b) an intermediate core layer having a surface hardness (I) of 40 Shore C or greater and formed from a first highly neutralized polymer composition; and
(c) an outer core layer having a surface hardness (S) of from 20 Shore C to 90 Shore C and formed from a second highly neutralized polymer composition;
wherein H<I and S<I;
wherein the material hardness of the second highly neutralized polymer composition is less than the material hardness of the first highly neutralized polymer composition; and
wherein at least one of the first highly neutralized polymer composition and the second highly neutralized polymer composition comprises:
an acid copolymer of ethylene and an α,β-unsaturated carboxylic acid, wherein the acid copolymer does not include a softening monomer selected from alkyl acrylates and methacrylates;
an alkyl acrylate rubber selected from ethylene-alkyl acrylates and ethylene-alkyl methacrylates;
magnesium oleate present in an amount of 20 parts or greater per 100 parts of acid copolymer and alkyl acrylate rubber combined; and
a cation source present in an amount sufficient to neutralize 110% or greater of all acid groups present in the composition.