Lithium-sulphur battery with high specific energy
View Patent ↗The invention provides for a method of discharging a chemical source of electric energy in two stages. The chemical source of electric energy comprises a positive electrode (cathode) including sulphur or sulphur-based organic compounds, sulphur-based polymeric compounds or sulphur-based inorganic compounds as a depolarizer, a negative electrode (anode) made of metallic lithium or lithium-containing alloys, and an electrolyte comprising a solution of at least one salt in at least one aprotic solvent. The method comprises the steps of configuring the chemical source of electric energy to generate soluble polysulphides in the electrolyte during a first stage of a two stage discharge process, and selecting the quantity of sulphur in the depolarizer and the volume of electrolyte in a way that after the first stage discharge of the cathode, the concentration of the soluble polysulphides in the electrolyte is at least seventy percent (70%) of a saturation concentration of the polysulphides in the electrolyte.
1. A chemical source of electric energy comprising a positive electrode (cathode) including sulphur or sulphur-based organic compounds, sulphur-based polymeric compounds or sulphur-based inorganic compounds as a depolarizer, a negative electrode (anode) made of metallic lithium or lithium-containing alloys, and an electrolyte comprising a solution of at least one salt in at least one aprotic solvent,
wherein the chemical source of electric energy is configured to generate soluble polysulphides in the electrolyte during a first stage of a two stage discharge process; and
wherein the quantity of sulphur in the depolariser and the volume of electrolyte are selected in a way that, after the first stage discharge of the cathode, the concentration of the soluble polysulphides in the electrolyte is seventy percent (70%) to ninety percent (90%) of a saturation concentration of the polysulphides in the electrolyte so as to enhance the specific energy characteristics of the chemical source of electric energy.
2. The chemical source of electric energy of claim 1 wherein the depolarizer includes sulphur, carbon black and polyethylene oxide.
3. The chemical source of electric energy of claim 1 wherein the electrolyte comprises a solution of one or more lithium salts selected form the group consisting of lithium trifluoromethanesulphonate, lithium perchlorate, lithium trifluoromethanesulfonimide, lithium hexafluorophosphate, lithium hexafluoroarsenate, lithium tetracholoroaluminate, tetraalkylammonium salt, lithium chloride, lithium bromide and lithium iodide; in one or more solvents selected from the group consisting of dioxolane, tetrahydrofuran, dimethoxyethane, diglyme, triglyme, tetraglyme, dialkyl carbonates, sulfolane and butyrolactone.
4. The chemical source of electric energy of claim 3 wherein the electrolyte comprises a solution of one or more lithium salts selected from the group consisting of lithium trifluoromethanesulphonate, lithium perchlorate, lithium trifluoromethanesulfonimide, lithium hexafluorophosphate, lithium hexafluoroarsenate, lithium tetracholoroaluminate, tetraalkylammonium salt, lithium chloride, lithium bromide and lithium iodide; in a solvent comprising sulfolane.
5. The chemical source of electric energy of claim 1 , wherein the electrolyte comprises a sulfone.
6. The chemical source of electric energy of claim 5 , wherein the electrolyte comprises sulfolane.