Polycrystalline diamond compacts and related methods
Embodiments of the invention relate to polycrystalline diamond compacts (“PDCs”) and methods of fabricating polycrystalline diamond tables and PDCs in a manner that facilitates removal of metal-solvent catalyst used in the manufacture of polycrystalline diamond tables of such PDCs.
1. A polycrystalline diamond compact, comprising:
a substrate; and
a polycrystalline diamond table including a working surface and an opposing interfacial surface directly bonded to the substrate, the polycrystalline diamond table including bonded diamond grains defining a plurality of interstitial regions, the polycrystalline diamond table further including:
a first volume of the polycrystalline diamond table including the bonded diamond grains extending inwardly from the working surface;
a second volume of the polycrystalline diamond table including the bonded diamond grains extending inwardly from the interfacial surface;
a metal-solvent catalyst and at least one sacrificial material disposed in at least a portion of the plurality of interstitial regions;
wherein the at least one sacrificial material comprises a material different than that of the metal-solvent catalyst, the at least one sacrificial material including a plurality of sacrificial particles, at least one reaction product of the plurality of diamond grains and the plurality of sacrificial particles, or combinations thereof;
wherein the at least one sacrificial material is present in the first volume and the second volume of the polycrystalline diamond table in a pre-leaching concentration of greater than 0 weight % to about 5 weight % of the first volume and the second volume prior to leaching the first volume;
wherein the at least one sacrificial material is present in the first volume in a concentration such that the first volume exhibits a post-leaching concentration of the metal-solvent catalyst of less than 0.85 weight % of the first volume, and the second volume includes the pre-leaching concentration of the at least one sacrificial material, after leaching the first volume.
2. The polycrystalline diamond compact of claim 1 wherein the post-leaching concentration of the metal-solvent catalyst in the first volume is about 0.20 weight % to about 0.50 weight % after leaching.
3. The polycrystalline diamond compact of claim 1 wherein the post-leaching concentration of the metal-solvent catalyst in the first volume is about 0.50 weight % to about 0.78 weight %.
4. The polycrystalline diamond compact of claim 1 wherein the metal-solvent catalyst includes at least one member selected from the group consisting of iron, nickel, and cobalt.
5. The polycrystalline diamond compact of claim 1 wherein the at least one sacrificial material includes tungsten carbide.
6. The polycrystalline diamond compact of claim 1 wherein the pre-leaching concentration of the at least one sacrificial material is about 1 weight % to about 5 weight %.
7. The polycrystalline diamond compact of claim 1 wherein the pre-leaching concentration of the at least one sacrificial material is about 1.5 weight % to about 2.5 weight %.
8. The polycrystalline diamond compact of claim 1 wherein the first volume extends to a depth of about 50 μm to about 500 μm from the working surface.
9. The polycrystalline diamond compact of claim 1 wherein the first volume extends to a depth of at least about 200 μm from the working surface.