Lithium ion secondary battery without internal short
View Patent ↗A lithium ion secondary battery including a compound containing at least one thiol group (—SH) in a molecule in a unit cell of the battery is provided. By including the compound containing thiol group (—SH) having good reactivity with copper or copper ions, the formation of dendrite through the reduction of copper ions present in the inner portion of the battery or produced during operating the battery at the surface of an anode may be prevented. The internal short between two electrodes due to the dendrite may be also prevented.
1. A lithium ion secondary battery comprising a compound containing at least one thiol group (—SH) in a molecule in an electrode of a battery,
wherein the electrode includes the compound containing at least one thiol group (—SH) in a molecule as a constituent component in the electrode, or as a coating component of the electrode,
the compound containing at least one thiol group (—SH) in a molecule is an aliphatic thiol selected from the group consisting of methanethiol, ethanethiol, and a mixture thereof,
the compound containing at least one thiol group (—SH) in a molecule reacts with copper ions being oxidized from copper foreign materials and being generated during operation of the battery to prevent forming dendrite due to reduction of the copper ions at a surface of an anode,
the copper foreign materials comprise a copper component or an alloy component including copper, and
an amount of the compound containing at least one thiol group (—SH) in a molecule may be 0.01 to 10 parts by weight based on 100 parts by weight of the electrode material.
2. A battery module comprising the lithium ion secondary battery according to claim 1 as a unit battery.