COATED CALCIUM PARTICULATES FOR USE IN BEVERAGE PRODUCTS
Coated particulate material used to enable the incorporation of calcium materials in a beverage product (especially those having a low pH) preserved with sodium hexametaphosphate (SHMP) are disclosed. The particulates are made up of a substrate material, such as a calcium salt, such as calcium phosphate. The substrate material can, in preferred embodiments, be incorporated into a prill which utilizes a sterol as the prilling material. The substrate material, preferably in the form of a prill, is then coated with a phospholipid coating, such as hydrogenated phosphatidyl choline, such that the final coated particulate product includes from about 70% to about 200% (by weight of the substrate) of the phospholipid coating. Beverage compositions which include these coated particulates are also disclosed.
1 . A coated particulate, having a particle size of from about 4 μm to about 10 μm, comprising a substrate consisting essentially of a material selected from calcium salts, iron salts, and alkali earth metal salts, oxidative labile vitamins, and combinations thereof; and from about 70% to about 200% (by weight of the substrate) of a phospholipid coating.
2 . The particulate according to claim 1 wherein the substrate is in the form of a prill consisting essentially of a sterol and the substrate material selected from calcium salts, iron salts and alkali earth metal salts, oxidative labile vitamins and combination thereof.
3 . The particulate according to claim 2 wherein the sterol material is hydrogenated.
4 . The particulate according to claim 3 wherein the prill consists essentially of from about 50% to about 70% sterol and from about 30% to about 50% of the substrate material.
5 . The particulate according to claim 4 wherein the substrate material is a calcium salt.
6 . The particulate according to claim 5 wherein the sterol is non-polar and is soluble in the prilling solvent.
7 . The particulate according to claim 6 wherein the calcium salt is selected from calcium phosphate, calcium chloride, calcium carbonate, calcium sulfate, calcium hydroxide, calcium hydroxyapatite, calcium salts of long chain polyphosphates, calcium salts of carboxylates, calcium ascorbate, calcium glycerylphosphate, calcium polycarbophil, calcium fructoborate, calcium glucoheptonate, and mixtures thereof.
8 . The particulate according to claim 7 wherein the calcium salt is calcium phosphate.
9 . The particulate according to claim 8 wherein the sterol material is selected from (a) beta sitosterol, (b) campesterol, (c) stigmasterol, and mixtures thereof.
10 . The particulate according to claim 9 wherein the sterol is a mixture of (a), (b) and (c), having a weight ratio (a):(b):(c) of about 2:1:1.
11 . The particulate according to claim 7 wherein the phospholipid is a hydrogenated phospholipid material.
12 . The particulate according to claim 11 wherein the phospholipid is a hydrogenated phosphatidyl choline.
13 . The particulate according to claim 10 wherein the phospholipid material is a hydrogenated phosphatidyl choline.
14 . The particulate according to claim 12 which additionally comprises a nutritionally effective amount of vitamin D.
15 . The particulate according to claim 12 having a density of from about 0.9 to about 1.5 g/mL.
16 . A beverage composition, having a pH of from about 2.9 to about 3.6, comprising from about 0.3 to about 3% of the particulate material according to claim 2 .
17 . A beverage composition, having a pH of from about 2.9 to about 3.6, comprising from about 0.3 to about 3% of a particulate material according to claim 7 .
18 . A beverage composition, having a pH of from about 2.9 to about 3.6, comprising from about 0.3 to about 3% of a particulate material according to claim 10 .
19 . A beverage composition, having a pH of from about 2.9 to about 3.6, comprising from about 0.3 to about 3% of a particulate material according to claim 12 .
20 . A beverage composition according to claim 16 which additionally comprises an effective amount of sodium hexametaphosphate as a preservative.
21 . A beverage composition according to claim 18 which additionally comprises an effective amount of sodium hexametaphosphate as a preservative.