CATHODE ACTIVE MATERIAL COATING
Embodiments of the present disclosure relate to apparatus and methods for forming particles of cathode active materials with a thin protective coating layer. The thin protective coating layer improves cycle and safety performance of the cathode active material. A coating precursor may be added at various stages during formation of the particles of cathode active materials. The thin layer of chemical may be a complete coating or a partial coating. The coating may include a thin layer of chemicals, such as an oxide, to improve cycle performance and safety performance of the cathode active material.
1 . An apparatus for forming cathode active material by continuous flow, comprising:
a mixing unit that generates a mixture or a solution of precursors;
a synthesizing unit coupled to the mixing unit to generate particles of cathode active material from the mixture or solution of precursors;
a cooling unit coupled to an outlet of the synthesizing unit;
a transferring channel coupled downstream to the cooling unit;
a collecting unit connected to the transferring channel for collecting the particles of cathode active material;
an annealing unit downstream to the collecting unit to anneal the particles of cathode active material; and
a coating source unit that provides a coating precursor for forming a coating on the particles of cathode active material, wherein the coating source unit is disposed at one of the mixing unit, the synthesizing unit, the transferring channel, the collecting unit, the annealing unit, an independent coating unit coupled between the collecting unit and the annealing unit, or a standalone coating unit.
2 . The apparatus of claim 1 , wherein the coating source unit is coupled to a mixer of the mixing unit, the mixing unit that generates a mixture or a solution comprising the coating precursor, and the synthesizing unit that forms particles of cathode active material having a coating formed thereon.
3 . The apparatus of claim 1 , wherein the coating source unit is coupled to the transferring channel, and the coating source unit that sprays a coating liquid or a coating gas to the flow of particles of cathode active material in the transferring channel.
4 . The apparatus of claim 1 , wherein the coating source unit is coupled to the collecting unit to form a layer of coating material on an inner surface of the collecting unit, and the particles of cathode active material is coated by the coating material while contacting the inner surface of the collecting unit.
5 . The apparatus of claim 1 , wherein the coating source unit is coupled to the annealing unit, and the coating source unit that sprays a coating liquid or a coating gas to the particles of cathode active material in the annealing unit during annealing.
6 . The apparatus of claim 1 , wherein the coating source unit is coupled to the independent coating station that carries out coating reactions to form a coating over the particles of cathode active material.
7 . The apparatus of claim 1 , wherein the coating source unit is coupled to the standalone coating station to carry out coating reactions to form a coating over the particles of cathode active material.
8 . The apparatus of claim 1 , wherein the synthesizing unit comprising a droplet generator, a dryer and a reactor.
9 . The apparatus of claim 8 , wherein the droplet generator is disposed in an inner volume of the dryer.
10 . The apparatus of claim 9 , wherein the dryer and the reactor form a tower with the dryer above the reactor.
11 . A method for forming cathode active material, comprising:
forming a mixture or solution of precursors comprising metal ions;
synthesizing the mixture or solution of precursors to form particles of cathode active material;
cooling and transferring the particles of cathode active material to a collecting unit;
collecting the particles of cathode active material in the collecting unit;
annealing the collected particles of cathode active material; and
adding a coating precursor to form a coating over the particles of cathode active material, wherein adding the coating precursor is performed during one of the following: forming the mixture or solution of precursors, cooling and transferring the particles of cathode active material, collecting the particles of cathode active material, after collecting and before annealing the particles of cathode active material, annealing the particles of cathode active material, and after annealing the particles of cathode active material.
12 . The method of claim 11 , wherein adding the coating precursor comprises introducing a suitable amount of the coating precursor so that the coated cathode active material comprises less than about 3% in weight of coating.
13 . The method of claim 11 , wherein the coating comprises one of Al 2 O 3 , AIF 3 , LiAlO 2 , AIPO 4 , ZrO 2 , ZrF 4 , SiO 2 , SnO 2 , MgO, or combinations thereof.
14 . The method of claim 13 , wherein the coating comprises Al 2 O 3 , and the coating precursor comprises Al(NO 3 ) 3 or aluminum alkyl.
15 . The method of claim 11 , wherein adding the coating precursor comprises introducing the coating precursor to the mixture or solution of precursors during forming the mixture or solution of precursors, and synthesizing the mixture or solution of precursors forms at least partially coated particles of cathode active material precursor.
16 . The method of claim 11 , wherein adding the coating precursor comprises spraying a coating liquid or a coating gas to the particles of cathode active material while transferring the powder of cathode active material.
17 . The method of claim 11 , wherein adding the coating precursor comprises spraying a coating liquid or a coating gas to the particles of cathode active material while annealing the powder of cathode active material.
18 . The method of claim 11 , wherein adding the coating precursor comprises adding the coating precursor to an independent coating station to carry out precipitation reactions to form a coating on the particles of cathode active material.
19 . The method of claim 18 , wherein adding the coating precursor is performed after collecting and before annealing.
20 . The method of claim 18 , wherein adding the coating precursor is performed after annealing.