PHOSPHINATE IONIC LIQUID COMPOSITIONS AND METHODS OF USE
The present invention relates to the use of phosphinate ionic liquids as flame retardants and also as a melt reduction agent for polymer processing. The compounds of the invention may be used as flame retardants in various materials without causing damage to the environment and or health of humans or animals. Ionic liquid flame retardants maybe applied alone or in combination with traditional flame retardants. Ionic liquid flame retardants can be applied to finish textile, plastic, leather, paper, rubber or as wild fire flame retardants.
1 . A method for preparing a flame retardant material comprising contacting or formulating the material with a flame retarding composition comprising an ionic liquid compound of the formula 1:
wherein:
Y and Y 1 are each independently selected from O or S;
R 1 and R 2 are each independently selected from the group consisting of hydrogen, (C 1 -C 20 )alkyl, aryl, (C 3 -C 10 )heterocyclyl, (C 3 -C 10 )cycloalkyl, (C 3 -C 10 )heterocyclyl(C 1 -C 8 )alkyl, aryl(C 1 -C 8 )alkyl, heteroaryl and heteroaryl(C 1 -C 8 )alkyl group, each of which may be unsubstituted or substituted with one or two halo, —NO 2 , CF 3 —, CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, —SMe, —SO 3 H, —CH═CH 2 , —CH 2 CH═CH 2 , —P((C 1 -C 5 )alkyl) 2 and —P(O)(OEt) 2 , or mixtures of the substituents;
A + is a cation selected from the group consisting of an ammonium, imidazolium, guanidinium, pyridinium, pyridazinium, 1,2,4-triazolium, triazine, sulfonium, phosphazenium and phosphonium cation; and
optionally, wherein the A + is a cation as defined above that is covalently bonded to a polymer.
2 . The method according to claim 1 , wherein A + is an ammonium cation of the formula 2:
wherein R 3 , R 4 , R 5 and R 6 are each independently a bond or are selected from the group consisting of hydrogen, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , (C 1 -C 20 )alkyl, aryl, (C 3 -C 10 )heterocyclyl, (C 3 -C 10 )cycloalkyl, (C 3 -C 10 )heterocyclyl(C 1 -C 8 )alkyl, aryl(C 1 -C 8 )alkyl, heteroaryl and heteroaryl(C 1 -C 8 )alkyl group, each of which may be unsubstituted or substituted with one or two —Cl, —Br, —I, —NO 2 , CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, —SMe, —SO 3 H, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , —CH═CH, —CH 2 CH═CH, -epoxide, —OC(O)—CH═CH, —NCO, —C(O)Cl, —C(O)Br, —C(O)-imidazolyl, —CO 2 (C 1 -C 3 )alkyl, —P((C 1 -C 5 )alkyl) 2 , —P(O)(OEt) 2 , —OC(O)CH 2 C(O)CH 3 and —CH═CR 10 CO 2 (C 1 -C 3 )alkyl, where R 10 is H or CH 3 , or mixtures of the two substituents.
3 . The method of claim 2 , wherein N + together with R 3 , R 4 , R 5 and R 6 form a cation selected from the group consisting of ammonium, imidazolium, guanidinium, pyridinium, pyridazinium and 1,2,4-triazolium, each of which is unsubstituted or substituted by one or two substituents selected from the group consisting of —Cl, —Br, —I, —NO 2 , CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, —SMe, —SO 3 H, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , —CH═CH, —CH 2 CH═CH, -epoxide, —OC(O)—CH═CH, —NCO, —C(O)Cl, —C(O)Br, —C(O)— imidazolyl, —CO 2 (C 1 -C 3 )alkyl, —P((C 1 -C 5 )alkyl) 2 , —P(O)(OEt) 2 , —OC(O)CH 2 C(O)CH 3 and —CH═CR 10 CO 2 (C 1 -C 3 )alkyl, where R 10 is H or CH 3 , or mixtures of the two substituents.
4 . The method of claim 2 , wherein the compound of the formula 2 is selected from the group consisting of:
wherein:
each R 1 , R 1′ , R 2 , R 2′ , R 3 , R 3′ , R 4 , R 4′ , R 5 , R 5′ , R 6 and R 6′ is independently selected from the group consisting of hydrogen, (C 1 -C 20 )alkyl, aryl, (C 3 -C 10 )heterocyclyl, (C 3 -C 10 )cycloalkyl, (C 3 -C 10 )heterocyclyl(C 1 -C 8 )alkyl, aryl(C 1 -C 8 )alkyl, heteroaryl and heteroaryl(C 1 -C 8 )alkyl group, each of which may be unsubstituted or substituted with one or two halo, —NO 2 , CF 3 —, CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, —SMe, —SO 3 H, —CH═CH 2 , —CH 2 CH═CH 2 , —P((C 1 -C 5 )alkyl) 2 and —P(O)(OEt) 2 , or mixtures of the two substituents.
5 . The method of claim 4 , wherein:
each R 1 , R 1′ , R 2 , R 2′ , R 3 , R 3′ , R 4 , R 4′ , R 5 , R 5′ , R 6 and R 6′ is independently selected from the group consisting of hydrogen, —CH 3 , —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , unsubstituted (C 2 -C 10 )alkyl, —CH 2 phenyl and (C 1 -C 10 )alkyl substituted with one —Cl, —Br, —I, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , —CH═CH, —CH 2 CH═CH, —CH 2 CHCH, -ethylene oxide, —OC(O)—CH═CH, —NCO, —C(O)Cl, —C(O)Br, —C(O)-imidazolyl and —CO 2 (C 1 -C 3 )alkyl.
6 . The method according to claim 1 wherein the compound is of the formula 1a:
wherein:
R 1 and R 2 are each independently selected from the group consisting of (C 1 -C 20 )alkyl, aryl, (C 3 -C 10 )heterocyclyl, (C 3 -C 10 )cycloalkyl, (C 3 -C 10 )heterocyclyl(C 1 -C 8 )alkyl, aryl(C 1 -C 8 )alkyl, heteroaryl and heteroaryl(C 1 -C 8 )alkyl group, each of which may be unsubstituted or substituted with one or two halo, —NO 2 , CF 3 —, CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, —SMe, —SO 3 H, —CH═CH 2 , —CH 2 CH═CH 2 , —P((C 1 -C 5 )alkyl) 2 and —P(O)(OEt) 2 , or mixtures of the substituents; and
wherein R 3 , R 4 , R 5 and R 6 are each independently a bond or are selected from the group consisting of hydrogen, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , (C 1 -C 20 )alkyl, aryl, (C 3 -C 10 )heterocyclyl, (C 3 -C 10 )cycloalkyl, (C 3 -C 10 )heterocyclyl(C 1 -C 8 )alkyl, aryl(C 1 -C 8 )alkyl, heteroaryl and heteroaryl(C 1 -C 8 )alkyl group, each of which may be unsubstituted or substituted with one or two —Cl, —Br, —I, —NO 2 , CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, —SMe, —SO 3 H, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , —CH═CH, —CH 2 CH═CH, -epoxide, —OC(O)—CH═CH, —NCO, —C(O)Cl, —C(O)Br, —C(O)-imidazolyl, —CO 2 (C 1 -C 3 )alkyl, —P((C 1 -C 5 )alkyl) 2 , —P(O)(OEt) 2 , —OC(O)CH 2 C(O)CH 3 and —CH═CR 10 CO 2 (C 1 -C 3 )alkyl, where R 10 is H or CH 3 , or mixtures of the two substituents; or
wherein N + together with R 3 , R 4 , R 5 and R 6 form a cation selected from the group consisting of ammonium, imidazolium, guanidinium, pyridinium, pyridazinium and 1,2,4-triazolium, each of which is unsubstituted or substituted by one or two substituents selected from the group consisting of —Cl, —Br, —I, —NO 2 , CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, —SMe, —SO 3 H, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , —CH═CH, —CH 2 CH═CH, -epoxide, —OC(O)—CH═CH, —NCO, —C(O)Cl, —C(O)Br, —C(O)-imidazolyl, —CO 2 (C 1 -C 3 )alkyl, —P((C 1 -C 5 )alkyl) 2 , —P(O)(OEt) 2 , —OC(O)CH 2 C(O)CH 3 and —CH═CR 10 CO 2 (C 1 -C 3 )alkyl, where R 10 is H or CH 3 , or mixtures of the two substituents.
7 . The method according to claim 1 wherein the compound is of the formula 1a:
wherein at least one of R 1 , R 2 , R 3 , R 4 , R 5 or R 6 is selected from the group consisting of —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , unsubstituted (C 1 -C 10 )alkyl, and (C 1 -C 10 )alkyl substituted with one —Cl, —Br, —I, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , —CH═CH, —CH 2 CH═CH, —CH 2 CHCH, -ethylene oxide, —OC(O)—CH═CH, —NCO, —C(O)Cl, —C(O)Br, —C(O)-imidazolyl, —CO 2 (C 1 -C 3 )alkyl, —OC(O)CH 2 C(O)CH 3 and —CH═CR 10 CO 2 (C 1 -C 3 )alkyl, where R 10 is H or CH 3 .
8 . The method according to claim 1 wherein the compound is of the formula:
9 . The method of claim 1 , wherein the method further comprises contacting or formulating the ionic liquid with a second different ionic liquid.
10 . The method of claim 1 , wherein the method further comprises contacting or formulating the material with an ionic liquid in combination with an agent selected from the group consisting of a mineral flame retardant, a halogenated flame retardant, a phosphorus based flame retardant, a nitrogen based flame retardant, a silicon based flame retardants and nanometric particles, and combinations thereof.
11 . The method of claim 1 , wherein the material is selected from the group consisting of textile, resin, plastic, rubber, leather, paper and wood products.
12 . A flame retardant or flame resistant material comprising an effective amount of a flame retardant composition comprising an ionic liquid compound of the formula 1:
wherein:
R 1 and R 2 are each independently selected from the group consisting of hydrogen, (C 1 -C 20 )alkyl, aryl, (C 3 -C 10 )heterocyclyl, (C 3 -C 10 )cycloalkyl, (C 3 -C 10 )heterocyclyl(C 1 -C 8 )alkyl, aryl(C 1 -C 8 )alkyl, heteroaryl and heteroaryl(C 1 -C 8 )alkyl group, each of which may be unsubstituted or substituted with one or two halo, —NO 2 , CF 3 —, CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, —SMe, —SO 3 H, —CH═CH 2 , —CH 2 CH═CH 2 , —P((C 1 -C 5 )alkyl) 2 and —P(O)(OEt) 2 , or mixtures of the substituents;
A + is a cation selected from the group consisting of an ammonium, imidazolium, guanidinium, pyridinium, pyridazinium, 1,2,4-triazolium, triazine, sulfonium, phosphazenium and phosphonium cation; and
optionally, wherein the A + is a cation as defined above that is covalently bonded to a polymer.
14 . The flame retardant or resistant material of claim 13 , wherein the material is selected from the group consisting of textile, fabric, resin, plastic, rubber, leather, paper and wood products, and surface coating formulations.
15 . The flame retardant or resistant fabric of claim 14 , wherein the fabric comprises natural fibers or synthetic fibers selected from the group consisting of nylon, polyacrylates, polyesters and polyamides and combinations thereof.
16 . The flame retardant or flame resistant material of claim 13 , wherein the material is a polymer selected from the group consisting of a thermoplastic, phenolics, polycarbonates, polyurethanes, polyesters, polyethylene, polypropylene, polyacrylic acid, butadiene/acrylonitrile-acrylonitrile/styrene copolymers, ethylene-vinyl acetate copolymers, polyamides, acrylic resisn and epoxy resins.
17 . A method for reducing the melt viscosity of a polymer during the processing of the polymer comprising adding a composition comprising an ionic liquid compound with the polymer before processing the polymer, wherein:
a) the ionic liquid compound is of the formula 1:
wherein:
R 1 and R 2 are each independently selected from the group consisting of hydrogen, (C 1 -C 20 )alkyl, aryl, (C 3 -C 10 )heterocyclyl, (C 3 -C 10 )cycloalkyl, (C 3 -C 10 )heterocyclyl(C 1 -C 8 )alkyl, aryl(C 1 -C 8 )alkyl, heteroaryl and heteroaryl(C 1 -C 8 )alkyl group, each of which may be unsubstituted or substituted with one or two halo, —NO 2 , CF 3 —, CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, —SMe, —SO 3 H, —CH═CH 2 , —CH 2 CH═CH 2 , —P((C 1 -C 5 )alkyl) 2 and —P(O)(OEt) 2 , or mixtures of the substituents;
A + is a cation selected from the group consisting of an ammonium, imidazolium, guanidinium, pyridinium, pyridazinium, 1,2,4-triazolium, triazine, sulfonium, phosphazenium and phosphonium cation; and
optionally, wherein the A + is a cation as defined above that is covalently bonded to a polymer; or
b) the ionic liquid compound is of the formula 1, wherein:
A + is an ammonium cation of the formula 2:
wherein R 3 , R 4 , R 5 and R 6 are each independently a bond or are selected from the group consisting of hydrogen, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , (C 1 -C 20 )alkyl, aryl, (C 3 -C 10 )heterocyclyl, (C 3 -C 10 )cycloalkyl, (C 3 -C 10 )heterocyclyl(C 1 -C 8 )alkyl, aryl(C 1 -C 8 )alkyl, heteroaryl and heteroaryl(C 1 -C 8 )alkyl group, each of which may be unsubstituted or substituted with one or two —Cl, —Br, —I, —NO 2 , CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, —SMe, —SO 3 H, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , —CH═CH, —CH 2 CH═CH, -epoxide, —OC(O)—CH═CH, —NCO, —C(O)Cl, —C(O)Br, —C(O)-imidazolyl, —CO 2 (C 1 -C 3 )alkyl, —P((C 1 -C 5 )alkyl) 2 , —P(O)(OEt) 2 , —OC(O)CH 2 C(O)CH 3 and —CH═CR 10 CO 2 (C 1 -C 3 )alkyl, where R 10 is H or CH 3 , or mixtures of the two substituents; or
c) the ionic liquid compound is of the formula 2, wherein:
N + together with R 3 , R 4 , R 5 and R 6 form a cation selected from the group consisting of ammonium, imidazolium, guanidinium, pyridinium, pyridazinium and 1,2,4-triazolium, each of which is unsubstituted or substituted by one or two substituents selected from the group consisting of —Cl, —Br, —I, —NO 2 , CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, —SMe, —SO 3 H, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , —CH═CH, —CH 2 CH═CH, -epoxide, —OC(O)—CH═CH, —NCO, —C(O)Cl, —C(O)Br, —C(O)-imidazolyl, —CO 2 (C 1 -C 3 )alkyl, —P((C 1 -C 5 )alkyl) 2 , —P(O)(OEt) 2 , —OC(O)CH 2 C(O)CH 3 and —CH═CR 10 CO 2 (C 1 -C 3 )alkyl, where R 10 is H or CH 3 , or mixtures of the two substituents; or
d) the ionic liquid compound of the formula 2 is selected from the group consisting of:
wherein:
each R 1 , R 1′ , R 2 , R 2′ , R 3 , R 3′ , R 4 , R 4′ , R 5 , R 5′ , R 6 and R 6′ is independently selected from the group consisting of hydrogen, (C 1 -C 20 )alkyl, aryl, (C 3 -C 10 )heterocyclyl, (C 3 -C 10 )cycloalkyl, (C 3 -C 10 )heterocyclyl(C 1 -C 8 )alkyl, aryl(C 1 -C 8 )alkyl, heteroaryl and heteroaryl(C 1 -C 8 )alkyl group, each of which may be unsubstituted or substituted with one or two halo, —NO 2 , CF 3 —, CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, —SMe, —SO 3 H, —CH═CH 2 , —CH 2 CH═CH 2 , —P((C 1 -C 5 )alkyl) 2 and —P(O)(OEt) 2 , or mixtures of the two substituents; or
e) wherein each R 1 , R 1′ , R 2 , R 2′ , R 3 , R 3′ , R 4 , R 4′ , R 5 , R 5′ , R 6 and R 6′ is independently selected from the group consisting of hydrogen, —CH 3 , —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , unsubstituted (C 2 -C 10 )alkyl, —CH 2 phenyl and (C 1 -C 10 )alkyl substituted with one —Cl, —Br, —I, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , —CH═CH, —CH 2 CH═CH, —CH 2 CHCH, -ethylene oxide, —OC(O)—CH═CH, —NCO, —C(O)Cl, —C(O)Br, —C(O)-imidazolyl and —CO 2 (C 1 -C 3 )alkyl; or
f) wherein the compound is of the formula 1a:
wherein:
R 1 and R 2 are each independently selected from the group consisting of (C 1 -C 20 )alkyl, aryl, (C 3 -C 10 )heterocyclyl, (C 3 -C 10 )cycloalkyl, (C 3 -C 10 )heterocyclyl(C 1 -C 8 )alkyl, aryl(C 1 -C 8 )alkyl, heteroaryl and heteroaryl(C 1 -C 8 )alkyl group, each of which may be unsubstituted or substituted with one or two halo, —NO 2 , CF 3 —, CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, -SMe, —SO 3 H, —CH═CH 2 , —CH 2 CH═CH 2 , —P((C 1 -C 5 )alkyl) 2 and —P(O)(OEt) 2 , or mixtures of the substituents; and
wherein R 3 , R 4 , R 5 and R 6 are each independently a bond or are selected from the group consisting of hydrogen, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 49 , (C 1 -C 20 )alkyl, aryl, (C 3 -C 10 )heterocyclyl, (C 3 -C 10 )cycloalkyl, (C 3 -C 10 )heterocyclyl(C 1 -C 8 )alkyl, aryl(C 1 -C 8 )alkyl, heteroaryl and heteroaryl(C 1 -C 8 )alkyl group, each of which may be unsubstituted or substituted with one or two —Cl, —Br, —I, —NO 2 , CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, —SMe, —SO 3 H, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , —CH═CH, —CH 2 CH═CH, -epoxide, —OC(O)—CH═CH, —NCO, —C(O)Cl, —C(O)Br, —C(O)-imidazolyl, —CO 2 (C 1 -C 3 )alkyl, —P((C 1 -C 5 )alkyl) 2 , —P(O)(OEt) 2 , —OC(O)CH 2 C(O)CH 3 and —CH═CR 10 CO 2 (C 1 -C 3 )alkyl, where R 10 is H or CH 3 , or mixtures of the two substituents; or
wherein N + together with R 3 , R 4 , R 5 and R 6 form a cation selected from the group consisting of ammonium, imidazolium, guanidinium, pyridinium, pyridazinium and 1,2,4-triazolium, each of which is unsubstituted or substituted by one or two substituents selected from the group consisting of —Cl, —Br, —I, —NO 2 , CF 3 O—, CH 3 O—, —CO 2 H, —NH 2 , —OH, —SH, —NHCH 3 , —N(CH 3 ) 2 , —CN, —SMe, —SO 3 H, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , —CH═CH, —CH 2 CH═CH, -epoxide, —OC(O)—CH═CH, —NCO, —C(O)Cl, —C(O)Br, —C(O)-imidazolyl, —CO 2 (C 1 -C 3 )alkyl, —P((C 1 —O 5 )alkyl) 2 , —P(O)(OEt) 2 , —OC(O)CH 2 C(O)CH 3 and —CH═CR 10 CO 2 (C 1 -C 3 )alkyl, where R 10 is H or CH 3 , or mixtures of the two substituents; or
g) wherein the compound is of the formula 1a:
wherein at least one of R 1 , R 2 , R 3 , R 4 , R 5 or R 6 is selected from the group consisting of —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , unsubstituted (C 1 -C 10 )alkyl, and (C 1 -C 10 )alkyl substituted with one —Cl, —Br, —I, —CF 3 , —C 2 F 5 , —C 3 F 7 , —C 4 F 9 , —CH═CH, —CH 2 CH═CH, —CH 2 CHCH, -ethylene oxide, —OC(O)—CH═CH, —NCO, —C(O)Cl, —C(O)Br, —C(O)-imidazolyl, —CO 2 (C 1 -C 3 )alkyl, —OC(O)CH 2 C(O)CH 3 and —CH═CR 10 CO 2 (C 1 -C 3 )alkyl, where R 10 is H or CH 3 ; or
h) wherein the compound is of the formula:
18 . The method of claim 17 , wherein the polymer is selected from the group consisting of polypropylene, polystyrene, polyethyleneterephthalate (PET), polycarbonate, thermoplastic, phenolics, polycarbonates, polyurethanes, polyesters, polyethylene, polypropylene, polyacrylic acid, butadiene/acrylonitrile-acrylonitrile/styrene copolymers, ethylene-vinyl acetate copolymers, polyamides, acrylic resins and epoxy resins.
19 . The method of claim 17 , wherein the ionic liquid compound comprises 0.01% wt/wt, 0.02% wt/wt, 0.03% wt/wt, 0.05% wt/wt, 0.1% wt/wt, 0.5% wt/wt, 1.0% wt/wt, 1.5% wt/wt, 2.0% wt/wt, 2.5% wt/wt, 3% wt/wt, 5% wt/wt, 10% wt/wt, 20% wt/wt, 30% wt/wt, 40% wt/wt, 50% wt/wt or more of the polymer.
20 . The method of claim 17 , wherein the processing of the polymer is selected from the group consisting of injection molding, extrusion, compression molding and thermomolding.