Porous composite and manufacturing method thereof
View Patent ↗Provided are a porous composite expressed by Chemical Formula 1 and having a porosity of 5% to 90%, and a method of preparing the same: MO x <Chemical Formula 1> where M and x are the same as described in the specification. According to the present invention, since a molar ratio (x) of oxygen to a molar ratio of (semi) metal in the porous composite is controlled, an initial efficiency of a secondary battery may be increased. Also, since the porous composite satisfies the above porosity, a thickness change rate of an electrode generated during charge and discharge of the secondary battery may be decreased and lifetime characteristics may be improved.
1. A porous composite expressed by Chemical Formula 1 and having a porosity of 5% to 90%:
MO x <Chemical Formula 1>
where M is at least one element selected from the group consisting of silicon (Si), tin (Sn), aluminum (Al), antimony (Sb), bismuth (Bi), arsenic (As), germanium (Ge), lead (Pb), zinc (Zn), cadmium (Cd), indium (In), titanium (Ti), and gallium (Ga), and 0.5<x<1,
wherein the porous composite comprises (semi) metal particles and oxide particles of (semi) metal,
wherein the (semi) metal particles are surrounded by the oxide particles of the (semi) metal,
wherein pores are formed on a surface or the surface and inside of the porous composite and
wherein the pores are a porous structure having a honeycomb shape.
2. The porous composite of claim 1 , wherein a porosity of the porous composite is in a range of 20% to 80%.
3. The porous composite of claim 1 , wherein x in Chemical Formula 1 is measured by an amount of oxygen that is included in a gas generated by heating the porous composite.
4. The porous composite of claim 1 , wherein the porous composite comprises (semi) metal and oxide of the (semi) metal,
wherein the (semi) metal is selected from the group consisting of Si, Sn, Al, Sb, Bi, As, Ge, Pb, Zn, Cd, In, Ti, Ga, and an alloy thereof.
5. The porous composite of claim 4 , wherein the (semi) metal is Si, the (semi) metal oxide is SiO 2 , and M is Si.
6. The porous composite of claim 4 , wherein the (semi) metal and the (semi) metal oxide are in a form of nanocrystals.
7. The porous composite of claim 6 , wherein a diameter of the nanocrystals is in a range of 0.1 nm to 100 nm.
8. The porous composite of claim 1 , wherein a diameter of the pore on the surface of the porous composite is in a range of 10 nm to 1,000 nm.
9. The porous composite of claim 1 , wherein a Brunauer-Emmett-Teller (BET) specific surface area of the porous composite is in a range of 2 m 2 /g to 100 m 2 /g.
10. The porous composite of claim 1 , further comprising a carbon coating layer on the porous composite.
11. An anode active material comprising the porous composite of claim 1 .
12. An anode comprising the anode active material of claim 11 .
13. A lithium secondary battery comprising the anode of claim 12 .