IP Library Granted Patent US 10,029,416
Granted Patent B2
US 10,029,416 · App. 14/166,834 · Granted Jul 24, 2018

Polymer spray deposition methods and systems

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Quick Facts
Patent No.
US 10,029,416
App. No.
14/166,834
Granted
Jul 24, 2018
Kind
B2
Abstract

Polymer spray deposition systems and methods are disclosed that can be used with a wide range of thermoplastic materials to produce high resolution objects having the complexity and structural integrity typically only achieved using more traditional manufacturing techniques, like injection molding processes. The polymeric spray deposition systems and methods use a spray generator that stretches the fluid between two diverging surfaces, such as two rollers or between two pistons. The stretched fluid breaks apart into a plurality of droplets and is guided through a delivery system, that can include an optional droplet size selector, and into a multi-nozzle array. The multi-nozzle array is controlled and directs the spray onto a target surface, thereby creating a three-dimensional object. The disclosed polymer spray deposition systems and methods can be used in three-dimensional print heads and printing techniques.

Claims (27)

1. A polymer spray deposition system, comprising:

a spray generator that receives a fluid from a fluid source and generates a plurality of fluid droplets by stretching the fluid between two diverging surfaces into a fluid filament until the fluid filament breaks into the plurality of droplets that form a spray;

a carrier gas flow to carry the spray from the spray generator and entrains the spray in a first direction;

a harvesting element that receives the spray from the spray;

a multi-nozzle array that receives the carrier gas flow with the entrained spray and generates a cross flow of air that pneumatically directs the carrier gas flow perpendicular to the first direction toward a target surface and causes at least some droplets of the entrained spray to reach the target surface while excess droplets are recycled back to the fluid source; and

an object production stage that controls the multi-nozzle array to repeatedly apply the carrier gas flow to the target surface to form a three-dimensional object on the target surface.

2. The polymer spray deposition system of claim 1 , wherein the fluid is a solution of high molecular weight polymeric fluid.

3. The polymer spray deposition system of claim 1 , wherein the spray generator includes two rollers that draw the fluid into an upstream side of a nip defined between the two rollers and cause the fluid to stretch between the respective diverging surfaces of the two rollers on a downstream side of the nip.

4. The polymer spray deposition system of claim 1 , wherein the spray generator is a first spray generator that generates a plurality of first fluid droplets by stretching the fluid between the two diverging surfaces into a first fluid filament until the first fluid filaments breaks into the plurality of first droplets and further comprising a second spray generator that receives the fluid from the fluid source and generates a plurality of second fluid droplets by stretching the fluid between the two diverging surfaces into a second fluid filament until the second fluid filament breaks into the plurality of second fluid droplets, the plurality of first fluid droplets and the plurality of second fluid droplets forming the spray.

5. The polymer spray deposition system of claim 1 , wherein the fluid is a thermoplastic having a melting point, and wherein the harvesting element maintains the thermoplastic in the carrier gas flow at a temperature above the melting point.

6. The polymer spray deposition system of claim 1 , wherein the harvesting element includes a droplet size selector that selects a predetermined size of droplets from the spray that is in the carrier gas flow.

7. The polymer spray deposition system of claim 1 , wherein the harvesting element includes a layer of air that radially surrounds the carrier gas flow and a heating element that radially surrounds the air layer.

8. The polymer spray deposition system of claim 7 , wherein the harvesting element further comprises insulation that radially surrounds the heating element.

9. The polymer spray deposition system of claim 1 , wherein the multi-nozzle array includes a plurality of nozzles, and further comprising a sheath gas source that emits a sheath gas to circulate around the nozzles in a direction perpendicular to the nozzles.

10. The polymer spray deposition system of claim 1 , wherein the multi-nozzle array includes a continuous inkjet gating mechanism that directs the carrier gas flow toward the target surface.

11. The polymer spray deposition system of claim 1 , wherein the object production stage is enclosed in a temperature-controlled housing that maintains the carrier gas flow above a freezing temperature of the spray and the stage below a glass transition temperature of the three-dimensional object.

12. The polymer spray deposition system of claim 1 , wherein the object production stage translates with respect to the multi-nozzle array in a direction perpendicular to the target surface to form the three-dimensional object.

13. A polymer spray deposition system, comprising:

a spray generator that receives fluid from a fluid source and generates a plurality of fluid droplets, the fluid droplets generated by stretching the fluid between two, diverging roller surfaces unt the stretched fluid exceeds a capillary break-up point of the fluid and breaks into the plurality of fluid droplets;

a carrier gas flow to transport the fluid droplets;

a transport channel that receives the plurality of fluid droplets from the spray generator and entrains the plurality of fluid droplets into the carrier gas flow, the transport channel having:

a tube within which the carrier gas flow travels;

an air stream radially surrounding the carrier gas flow within the tube; and

a heating element radially surrounding and external to the tube;

a multi-nozzle array having a plurality of nozzles each having an orifice, the multi-nozzle array receiving the carrier gas flow from the transport channel and pneumatically directing the carrier gas flow through the orifices of the nozzles in a direction perpendicular to the carrier gas flow; and

an object production stage that controls the position of the multi-nozzle array with respect to a target surface to which the carrier gas flow is directed through the nozzles.

14. The polymer spray deposition system of claim 13 , wherein the fluid is a solution of high molecular weight polymeric fluid.

Assignments (10)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 6, 2025
From: XEROX CORPORATION
To: GENESEE VALLEY INNOVATIONS, LLC
Reel/Frame 073842/0479 →
SECOND LIEN NOTES PATENT SECURITY AGREEMENT Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT RF 064760/0389 Recorded Feb 13, 2024
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: XEROX CORPORATION
Reel/Frame 068261/0001 →
SECURITY INTEREST Recorded Feb 13, 2024
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066741/0001 →
SECURITY INTEREST Recorded Nov 20, 2023
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 065628/0019 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVAL OF US PATENTS 9356603, 10026651, 10626048 AND INCLUSION OF US PATENT 7167871 PREVIOUSLY RECORDED ON REEL 064038 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 28, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064161/0001 →
SECURITY INTEREST Recorded Jun 22, 2023
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 064760/0389 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 20, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064038/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 4, 2014
From: JOHNSON, DAVID MATHEW; VOLKEL, ARMIN R.; BECK, VICTOR; PASCHKEWITZ, JOHN STEPHEN
To: PALO ALTO RESEARCH CENTER INCORPORATED
Reel/Frame 034096/0322 →