IP Library Granted Patent US 9,504,985
Granted Patent B2
US 9,504,985 · App. 14/176,335 · Granted Nov 29, 2016

Apparatus and methods for producing chlorine dioxide

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Quick Facts
Patent No.
US 9,504,985
App. No.
14/176,335
Granted
Nov 29, 2016
Kind
B2
Abstract

Chlorine dioxide (ClO 2 ) is produced by apparatus and methods wherein a ClO 2 gas produced in the apparatus is quickly introduced into a fluid stream to be treated with said gas. To this end, the apparatus has an interior chemical reaction chamber which houses an internal fluid flow tube having a fluid impervious upper section and a porous lower section that respectively define two zones within the interior chemical reaction chamber.

Claims (12)

1. An apparatus for producing chlorine dioxide, said apparatus comprising:

(1) a chemical reactor having:

(a) an upper mixing and/or reaction zone for carrying out a first mixing/chemical reaction operation,

(b) a lower distribution and reaction zone for carrying out a chlorine dioxide gas producing chemical reaction,

(c) a first chemical precursor entry port that leads into an internal fluid flow tube housed in the chemical reactor,

(d) a second chemical precursor entry port that leads into the upper mixing and/or reaction zone,

(e) a third chemical precursor entry port that also leads into the upper mixing and/or reaction zone, and

(f) an exit port for discharging fluid from the lower distribution and reaction zone into a fluid flow device;

(2) an internal fluid flow tube having a fluid impervious upper section and a fluid porous lower section, said tube serving to: (a) receive a first chemical precursor, (b) transport that first chemical precursor through the fluid impervious upper section of the internal fluid flow tube and (c) deliver the first chemical precursor into the porous lower section of said internal fluid flow tube whereupon said first chemical precursor is forced through a porous wall region of the porous lower section and into the lower distribution and reaction zone; and

(3) a fluid flow device that conducts a portion of a fluid passing through said device into and out of the exit port of the chemical reactor in a manner such that any chlorine dioxide gas produced in the lower distribution and reaction zone is dissolved into said portion of the fluid that enters and leaves the lower distribution and reaction zone.

2. The apparatus of claim 1 wherein the internal fluid flow tube is comprised of a fluid impervious upper section and a porous lower section connected to each other by a tube coupling device.

3. The apparatus of claim 1 wherein the internal fluid flow tube is a single piece whose lower region is provided with an array of openings in order to render said lower region porous with respect to the first chemical precursor.

Assignments (16)
PATENT SECURITY AGREEMENT Recorded Jan 29, 2025
From: SELECT WATER SOLUTIONS, LLC; SELECT AGUA LIBRE MIDSTREAM, LLC; SELECT CHEMISTRY, LLC
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 070048/0356 →
RELEASE OF SECURITY INTEREST Recorded Jan 25, 2025
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
To: SELECT AGUA LIBRE MIDSTREAM, LLC
Reel/Frame 070006/0242 →
RELEASE OF SECURITY INTEREST Recorded Jan 22, 2025
From: UMB BANK, N.A.
To: BASIC ENERGY SERVICES, L.P.; MAVERICK STIMULATION COMPANY, LLC
Reel/Frame 069959/0884 →
RELEASE OF SECURITY INTEREST Recorded Jan 8, 2025
From: U.S. BANK NATIONAL ASSOCIATION
To: BASIC ENERGY SERVICES, L.P.
Reel/Frame 069781/0578 →
SECURITY INTEREST Recorded Mar 17, 2022
From: SELECT AGUA LIBRE MIDSTREAM, LLC
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 059298/0855 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 14, 2022
From: BASIC ENERGY SERVICES, L.P.; AGUA LIBRE MIDSTREAM LLC
To: SELECT AGUA LIBRE MIDSTREAM, LLC
Reel/Frame 059258/0665 →
RELEASE OF PATENT SECURITY INTEREST Recorded Oct 6, 2021
From: GUGGENHEIM CREDIT SERVICES, LLC, AS AGENT
To: BASIC ENERGY SERVICES, L.P.; C&J WELL SERVICES, INC.
Reel/Frame 057726/0183 →
SECURITY INTEREST Recorded Aug 23, 2021
From: BASIC ENERGY SERVICES, L.P.; C&J WELL SERVICES, INC.
To: GUGGENHEIM CREDIT SERVICES, LLC, AS AGENT
Reel/Frame 057258/0085 →
RELEASE OF PATENT SECURITY INTEREST Recorded Aug 18, 2021
From: CANTOR FITZGERALD SECURITIES, AS ADMINISTRATIVE AGENT
To: BASIC ENERGY SERVICES, L.P.; C&J WELL SERVICES, INC.
Reel/Frame 057222/0302 →
SECURITY INTEREST Recorded May 4, 2021
From: BASIC ENERGY SERVICES, L.P.; C&J WELL SERVICES, INC.
To: CANTOR FITZGERALD SECURITIES
Reel/Frame 056131/0262 →
SECURITY INTEREST Recorded Oct 2, 2018
From: BASIC ENERGY SERVICES, L.P.
To: UMB BANK, N.A.
Reel/Frame 047042/0606 →
RELEASE OF SECURITY INTEREST Recorded Oct 2, 2018
From: U.S. BANK NATIONAL ASSOCIATION
To: BASIC ENERGY SERVICES, L.P.
Reel/Frame 047042/0191 →
SECURITY INTEREST Recorded Dec 27, 2016
From: BASIC ENERGY SERVICES, L.P.
To: U.S. BANK NATIONAL ASSOCIATION
Reel/Frame 040773/0292 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 26, 2016
From: GRIMLAND, KRISTIAN E.; SOKOL, JOHN CHARLES
To: MAVERICK SOLUTIONS, LLC
Reel/Frame 040142/0066 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 26, 2016
From: MAVERICK SOLUTIONS, LLC
To: BASIC ENERGY SERVICES, L.P.
Reel/Frame 040497/0505 →
PATENT SECURITY AGREEMENT SUPPLEMENT Recorded Mar 1, 2016
From: BASIC ENERGY SERVICES, L.P.
To: U.S. BANK NATIONAL ASSOCIATION
Reel/Frame 037960/0141 →