Phosphor particle group and light emitting apparatus using the same
View Patent ↗Provided is a phosphor particle group of divalent europium-activated oxynitride green light emitting phosphor particles each of which is a β-type SiAlON substantially represented by a general formula: EuaSibAlcOdNe, where 0.005≦a≦0.4, b+c=12, d+e=16, wherein 60% or more of the phosphor particle group is composed of the phosphor particles in which a value obtained by dividing a longer particle diameter by a shorter particle diameter is greater than 1.0 and not greater than 3.0. A high-efficiency and stable light emitting apparatus using a β-type SiAlON, which includes a light converter using the phosphor particle group, and a phosphor particle group therefor are also provided.
1. A white light emitting apparatus comprising:
a light emitting element of a gallium nitride-based semiconductor emitting primary light having a peak wavelength of 440-470 nm; and
a light converter absorbing a part of said primary light to emit secondary light having a wavelength longer than a wavelength of said primary light,
said light converter including a phosphor particle group of divalent europium-activated oxynitride green light emitting phosphor which is a β-type SiAlON substantially represented by a general formula:
Eu a Si b Al c O d N e ,
where 0.005≦a≦0.2, b+c=12, d+e=16,
said phosphor particle group of divalent europium-activated oxynitride green light consisting of a columnar particle in which a value obtained by dividing a longer particle diameter by a shorter particle diameter is greater than 1.0 and not greater than 3.0, and
the light converter further comprising phosphor particles of a red light emitting phosphor.
2. The white light emitting apparatus of claim 1 , wherein the red light emitting phosphor particles are particles of a divalent europium-activated nitride red light emitting phosphor expressed by a general formula (MI 1-f Eu f )MIISiN 3 , wherein MI is an alkaline-earth metal selected from the groups consisting of Mg, Ca, Sr and Ba; and MII is a trivalent metallic element selected from the group consisting of Al, Ga, In, Sc, Y, La, Gd and Lu; and 0.001<f<0.10.
3. The white light emitting apparatus of claim 1 , wherein a median diameter of the phosphor particle group of divalent europium-activated oxynitride green light is in a range of 6-20 μm.
4. The white light emitting apparatus of claim 1 , wherein a median diameter of the phosphor particle group of divalent europium-activated oxynitride green light is in a range of 6-20 μm.
5. A white light emitting apparatus comprising:
a light emitting element of a gallium nitride-based semiconductor emitting primary light having a peak wavelength of 440-470 nm; and
a light converter absorbing a part of said primary light to emit secondary light having a wavelength longer than a wavelength of said primary light,
said light converter including a phosphor particle group of divalent europium-activated oxynitride green light emitting phosphor which is a β-type SiAION substantially represented by a general formula:
Eu a Si b Al c O d N e ,
where 0.005≦a≦0.2, b+c=12, d+e=16,
wherein 60% or more of the phosphor particle group of divalent europium-activated oxynitride green light is composed of columnar phosphor particles in which a value obtained by dividing a longer particle diameter by a shorter particle diameter is greater than 1.0 and not greater than 3.0, and
the light converter further comprising phosphor particles of a red light emitting phosphor.
6. The white light emitting apparatus of claim 5 , wherein the red light emitting phosphor particles are particles of a divalent europium-activated nitride red light emitting phosphor expressed by a general formula (MI 1-f Eu f )MIISiN 3 , wherein MI is an alkaline-earth metal selected from the groups consisting of Mg, Ca, Sr and Ba; and MII is a trivalent metallic element selected from the group consisting of Al, Ga, In, Sc, Y, La, Gd and Lu; and 0.001<f<0.10.
7. The white light emitting apparatus of claim 6 , wherein 80% or more of the phosphor particle group of divalent europium-activated oxynitride green light is composed of the phosphor particles in which a value obtained by dividing a longer particle diameter by a shorter particle diameter is greater than 1.0 and not greater than 3.0.
8. The white light emitting apparatus of claim 7 , wherein a median diameter of the phosphor particle group of divalent europium-activated oxynitride green light is in a range of 6-20 μm.
9. The white light emitting apparatus of claim 6 , wherein a median diameter of the phosphor particle group of divalent europium-activated oxynitride green light is in a range of 6-20 μm.
10. The white light emitting apparatus of claim 5 , wherein 80% or more of the phosphor particle group of divalent europium-activated oxynitride green light is composed of the phosphor particles in which a value obtained by dividing a longer particle diameter by a shorter particle diameter is greater than 1.0 and not greater than 3.0.
11. The white light emitting apparatus of claim 10 , wherein a median diameter of the phosphor particle group of divalent europium-activated oxynitride green light is in a range of 6-20 μm.
12. The white light emitting apparatus of claim 5 , wherein a median diameter of the phosphor particle group of divalent europium-activated oxynitride green light is in a range of 6-20 μm.