Process to make 1,1,2,3-tetrachloropropene from 1,1,3-trichloropropene and/or 3,3,3-trichloropropene
View Patent ↗Disclosed is a process for the synthesis of 1,1,2,3-tetrachloropropene (HCC-1230xa) using 1,1,3-trichloropropene (HCC-1240za) and/or 3,3,3-trichloropropene (HCC-1240zf) and Cl 2 gas as the reactants, wherein the process takes place in a single reactor system. Before this invention, HCC-1230xa was made in a two-step process using HCC-1240za/HCC-1240zf and Cl 2 gas, and the processing was conducted using two separate reactors.
1. A process for the synthesis of 1,1,2,3-tetrachloropropene (HCC-1230xa) using an organic starting material selected from 1,1,3-trichloropropene (HCC-1240za), 3,3,3-trichloropropene (HCC-1240zf), or mixtures thereof, and Cl 2 gas as the reactants, with a dehydrochlorination catalyst, wherein the process takes place in a single reactor system.
2. The process of claim 1 , wherein the dehydrochlorination catalyst comprises one ore more iron halide compounds.
3. The process of claim 2 , wherein the iron halide compounds comprise one or more chloride compounds.
4. The process of claim 3 , wherein the catalyst comprises FeCl 3 .
5. The process of claim 1 , wherein the single reactor system comprises a CSTR equipped with a total condenser, a reaction column and a total condenser.
6. The process of claim 5 , wherein the reaction column can be separated into four zones comprising (a) a Cl 2 feed zone, (b) a reaction zone, (c) an organic feed zone and (d) a clean-up zone.
7. The process of claim 6 , wherein the starting material containing 1,1,3-trichloropropene (HCC-1240za) or 3,3,3-trichloropropene (HCC-1240zf) or a mixture thereof, is fed into the reaction column via the organic feed zone.
8. The process of claim 6 , wherein the Cl 2 gas is fed into the reaction column via the Cl 2 feed zone.
9. The process of claim 6 , wherein the reaction column can be empty.
10. The process of claim 6 , wherein the reaction column can be packed with chlorine-resistant material or equipped with trays/plates or stirring device to enhance gas/liquid contact.