Secondary battery and method for manufacturing the same
View Patent ↗Provided is a secondary battery with improved safety through filling a polymer in a hardened state, and a method of manufacturing the same. The method of manufacturing a secondary battery according to the present disclosure includes preparing a polymer slurry by adding a polymer particle to an electrolyte solution, injecting the polymer slurry to a battery casing in which an electrode assembly is received, changing the polymer slurry to a polymer solution by heating the battery casing, and hardening the polymer solution by cooling the battery casing.
1. A method of manufacturing a secondary battery, comprising:
preparing a polymer slurry by adding a polymer particle to an electrolyte solution;
injecting the polymer slurry to a battery casing in which an electrode assembly is received, so that the electrolyte solution penetrates into the electrode assembly and the polymer particle is disposed between the electrode assembly and the battery casing, wherein the polymer particle does not penetrate into the electrode assembly;
changing the polymer slurry to a polymer solution by heating the battery casing; and
hardening the polymer solution by cooling the battery casing.
2. The method according to claim 1 , wherein heating and cooling of the battery casing is performed in such a state that a predetermined pressure is applied to the battery casing.
3. The method according to claim 2 , wherein applying the predetermined pressure is performed to dispose at least a portion of the polymer solution in a protruding portion of an electrode tab of the electrode assembly within the battery casing.
4. The method according to claim 1 , wherein heating of the battery casing is performed to change the polymer slurry to a polymer solution in a sol state.
5. The method according to claim 1 , wherein cooling of the battery casing is performed to change the polymer solution to a gel state.
6. The method according to claim 1 , wherein the polymer particle is a binder polymer particle.
7. The method according to claim 1 , wherein the polymer particle includes at least one of polyvinylidene fluoride, polyvinylidene fluoride-co-hexafluoropropylene (PVDF-co-HFP), polyvinylidene fluoride-co-tricholroethylene, polyacrylonitrile, polymethylmethacrylate, styrene butadiene rubber (SBR), and carboxymethyl cellulose (CMC).
8. The method according to claim 1 , wherein the battery casing is a pouch-shaped battery casing.
9. The method according to claim 1 , wherein the diameter of the polymer particle is in a range of 60 μm to 230 μm.