Well treatment methods and fluids
View Patent ↗A method includes forming a well treatment fluid by combining an aqueous fluid, a viscosifying agent, a crosslinker, and a rheology modifier containing an aldehyde. The viscosifying agent is crosslinked, increasing viscosity of the fluid. The method includes treating a well with the fluid exhibiting the increased viscosity, chemically changing the aldehyde after the crosslinking and thereby forming an acid, and decreasing viscosity of the crosslinked fluid as a result of forming the acid. The aldehyde may be glyoxal which forms oxalic acid, breaking a crosslink. A well treatment fluid is formulated with ingredients including an aqueous fluid and a viscosifying agent and a crosslinker configured to crosslink the viscosifying agent. The fluid includes a rheology modifier containing an aldehyde. The fluid may lack an aldehyde crosslinking delay additive.
1. A well treatment method comprising:
forming a well treatment fluid by combining ingredients including an aqueous fluid, a viscosifying agent, a crosslinker, and a rheology modifier containing glyoxal;
crosslinking the viscosifying agent in the aqueous fluid using the crosslinker, the glyoxal not delaying the crosslinking and the crosslinking increasing viscosity of the well treatment fluid to a first viscosity;
treating a well with the well treatment fluid exhibiting the first viscosity;
chemically changing the glyoxal after the crosslinking and thereby forming oxalic acid, the glyoxal not being substantially chemically changed before the crosslinking; and
after treating the well, decreasing viscosity of the crosslinked well treatment fluid to a second viscosity less than the first viscosity as a result of forming the oxalic acid.
2. The method of claim 1 , wherein the viscosifying agent comprises a polymer and the crosslinker comprises a metal cation or borate, the method further comprising breaking a crosslink formed by the metal cation or borate to effect the viscosity decrease.
3. The method of claim 2 wherein decreasing viscosity occurs by a stepwise process including chemically changing the glyoxal, forming the oxalic acid, and the oxalic acid breaking the crosslink formed by the metal cation or borate.
4. The method of claim 1 wherein the viscosity decreases at a faster rate compared to the well treatment fluid without the rheology modifier.
5. The method of claim 1 wherein the aqueous fluid is produced water and the ingredients further include a zirconium salt.
6. The method of claim 5 wherein the zirconium salt is selected from the group consisting of zirconium hydroxide, zirconium dioxide, and combinations thereof.
7. The method of claim 5 wherein the produced water contains more than 100,000 ppm total dissolved solids.
8. The method of claim 7 wherein the zirconium salt comprises zirconium hydroxide.
9. The method of claim 8 wherein the well treatment fluid ingredients contain 0.01 to 20 wt % zirconium hydroxide.
10. The method of claim 7 wherein the well treatment fluid exhibits a pH below 7 at least during the crosslinking.
11. The method of claim 7 wherein the well treatment fluid exhibits a pH between about 6 and about 5 at least during the crosslinking and the treating.
12. A well treatment method comprising:
forming a well treatment fluid by combining ingredients including an aqueous fluid, a viscosifying agent, a crosslinker containing zirconium, and a rheology modifier containing glyoxal;
crosslinking the viscosifying agent in the aqueous fluid using the crosslinker, the glyoxal not delaying the crosslinking and the crosslinking increasing viscosity of the well treatment fluid;
treating a well with the well treatment fluid exhibiting the increased viscosity;
chemically changing the glyoxal after the crosslinking and thereby forming oxalic acid;
the oxalic acid breaking a crosslink formed by the zirconium and decreasing viscosity of the crosslinked well treatment fluid using the oxalic acid.
13. The method of claim 12 wherein the viscosity decreases at a faster rate compared to the well treatment fluid without the rheology modifier.
14. The method of claim 12 wherein the aqueous fluid is produced water and the ingredients further include a zirconium salt selected from the group consisting of zirconium hydroxide, zirconium dioxide, and combinations thereof.
15. A well treatment method comprising:
forming a well treatment fluid by combining ingredients including produced water, a viscosifying agent, a crosslinker containing a metal cation, a rheology modifier containing glyoxal, and a zirconium salt, the produced water containing more than 1,000 ppm total dissolved solids;
dissolving at least a portion of the zirconium salt in the well treatment fluid;
crosslinking the viscosifying agent in the aqueous fluid using the crosslinker and the dissolved zirconium from the zirconium salt, the glyoxal not delaying the crosslinking and the crosslinking increasing viscosity of the well treatment fluid compared to the well treatment fluid without the zirconium salt;
treating a well with the well treatment fluid exhibiting the increased viscosity, acid hydrolysis of the crosslinked viscosifying agent occurring in the well;
stabilizing pH of the well treatment fluid with the zirconium salt during the acid hydrolysis of the viscosifying agent in the well;
chemically changing the glyoxal after the crosslinking and thereby forming oxalic acid;
decreasing pH and chelating the metal cation and the dissolved zirconium with the oxalic acid, thus breaking the crosslinked well treatment fluid and, using the oxalic acid, decreasing viscosity of the crosslinked well treatment fluid compared to the crosslinked well treatment fluid without the rheology modifier.
16. The method of claim 15 wherein the zirconium salt is selected from the group consisting of zirconium hydroxide, zirconium dioxide, and combinations thereof.