Quaternary fatty acid esters as corrosion inhibitors
View Patent ↗Corrosion inhibitor compositions, methods of inhibiting or reducing corrosion, and methods of manufacturing corrosion inhibitor compositions are disclosed herein. In certain methods, the corrosion inhibitor compositions may be added to an aqueous industrial system having at least one surface. The aqueous industrial system may be a water recirculating system, a cooling water system, a boiler water system, a pulp slurry, a papermaking process, a ceramic slurry, a mixed solid/liquid system, or an oil-field system. A method of manufacturing a corrosion inhibitor composition may include reacting an alkanolamine with a fatty acid to form a fatty acid ester reaction product and reacting the fatty acid ester reaction product with an alkyl halide or an acrylate.
1. A corrosion inhibitor composition comprising a corrosion inhibitor having the following general structure:
wherein n is 1 or 2; x is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, or 22; y is an integer corresponding to a number of hydrogen atoms necessary for each carbon of the C x H y group to form four covalent bonds; R is H, a benzyl group, a linear alkyl group, or a branched alkyl group; and X − is an anion.
2. The composition of claim 1 , wherein the C x H y group of the general structure is selected from the group consisting of a linear alkyl group, a branched alkyl group, a cyclic alkyl group, a saturated alkyl group, and an unsaturated alkyl group.
3. The composition of claim 1 , wherein the C x H y group is selected from the group consisting of C 17 H 35 , C 17 H 33 , C 17 H 31 , C 17 H 29 , C 15 H 31 , C 15 H 29 , C 13 H 27 , C 13 H 25 , and C 11 H 23 .
4. The composition of claim 1 , wherein x is 12, 13, 14, 15, 16, 17, or 18.
5. The composition of claim 1 , wherein R is selected from the group consisting of ethyl, n-butyl, ethylacetate, and propanediol.
6. The composition of claim 1 , wherein the corrosion inhibitor is selected from the group consisting of:
and any combination thereof.
7. A method of inhibiting corrosion comprising adding an effective amount of a composition comprising a corrosion inhibitor comprising a hydrolysable functional group to an aqueous industrial system having at least one surface and inhibiting corrosion of the at least one surface.
8. The method of claim 7 , wherein the effective amount is from about 1 ppm to about 200 ppm.
9. The method of claim 7 , wherein the aqueous industrial system is selected from the group consisting of water recirculating systems, cooling water systems, boiler water systems, pulp slurries, papermaking processes, ceramic slurries, mixed solid/liquid systems, and oil-field systems.
10. The method of claim 7 , wherein the surface comprises a member selected from the group consisting of mild steel, galvanized steel, aluminum, aluminum alloys, copper, copper nickel alloys, copper zinc alloys, brass, chrome steels, ferritic alloy steels, austenitic stainless steels, precipitation-hardened stainless steels, high nickel content steels, and any combination thereof.
11. The method of claim 7 , wherein the composition is added to the system manually or automatically.
12. The method of claim 7 , wherein the aqueous industrial system is selected from the group consisting of a three phase production system, a two phase production systems, a produced oil system, a water disposal system, a gas condensate system, a gas compressor system, and a lift well system.
13. The method of claim 7 , wherein the corrosion inhibitor comprises the following general structure:
wherein n is 1 or 2; x is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, or 22; y is an integer corresponding to a number of hydrogen atoms necessary for each carbon of the C x H y group to form four covalent bonds; R is H, a benzyl group, a linear alkyl group, or a branched alkyl group; and X − is an anion.
14. The method of claim 7 , wherein the corrosion inhibitor is selected from the group consisting of:
and any combination thereof.
15. A method of manufacturing a composition comprising a quaternary ammonium corrosion inhibitor comprising:
reacting an alkanolamine with a fatty acid in a reaction vessel to form a fatty acid ester reaction product; and
reacting the fatty acid ester reaction product with an alkyl halide or an acrylate in the reaction vessel, thereby forming the quaternary ammonium corrosion inhibitor.
16. The method of claim 15 , wherein the alkanolamine is selected from the group consisting of 2-[2-(dimethylamino)ethoxy]ethanol, 2-dimethylaminoethanol, and any combination thereof.
17. The method of claim 15 , wherein the fatty acid is selected from the group consisting of tall oil fatty acid, soya fatty acid, oleic acid, linoleic acid, linolenic acid, coco fatty acid, stearic acid, palmitic acid, lauric acid, capric acid, myristic acid, arachidic acid, and any combination thereof.
18. The method of claim 15 , wherein the alkyl halide is selected from the group consisting of benzyl chloride, methyl chloride, ethyl chloride, propyl chloride, butyl chloride, hexyl chloride, chloropropanediol, ethylchloroacetate, and bis(2-chloroethyl)ether.
19. The method of claim 15 , wherein the reaction vessel does not comprise a solvent.
20. The method of claim 15 , further comprising the steps of:
heating the reaction vessel from about 150° C. to about 250° C. for about 3 hours to about 10 hours during the step of reacting the alkanolamine with the fatty acid to form the fatty acid ester reaction product;
cooling the reaction vessel to below about 80° C.;
adding the alkyl halide or acrylate to the fatty acid ester reaction product; and
heating the reaction vessel from about 100° C. to about 150° C. for about 2 hours to about 6 hours.