FOAM MOLDED BODY
An object of the present invention is to provide a molded body that is easy to produce and obtained by foaming a polycarbonate copolymer containing, as a raw material, isosorbide that is lightweight and excellent in mechanical properties and like. The present invention relates to a foam-molded body containing a polycarbonate copolymer having a structural unit derived from a dihydroxy compound represented by the following formula (1): and a structural unit derived from other dihydroxy compounds, and having a glass transition temperature (Tg) of less than 145° C.
1 . A foam-molded body containing a polycarbonate copolymer having a structural unit derived from a dihydroxy compound represented by the following formula (1):
and a structural unit derived from other dihydroxy compounds, and having a glass transition temperature (Tg) of less than 145° C.
2 . The foam-molded body according to claim 1 , wherein the structural unit derived from other dihydroxy compounds is at least one structural unit selected from the group consisting of a structural unit derived from a dihydroxy compound represented by the following formula (2):
HO—R 1 −OH (2)
wherein R’ represents a substituted or unsubstituted cycloalkylene group having a carbon number of 4 to 20,
a structural unit derived from a dihydroxy compound represented by the following formula (3):
HO—CH 2 —R 2 —CH 2 —OH (3)
wherein R 2 represents a substituted or unsubstituted cycloalkylene group having a carbon
number of 4 to 20,
a structural unit derived from a dihydroxy compound represented by the following formula (4):
H—(O—R 3 )p-OH (4)
wherein R 3 represents a substituted or unsubstituted alkylene group having a carbon number of 2 to 10, and p is an integer of 2 to 50, and
a structural unit derived from a dihydroxy compound represented by the following formula (5):
HO—R 4 —OH (5)
wherein R 4 represents a substituted or unsubstituted alkylene group having a carbon number of 2 to 20 or a group containing a substituted or unsubstituted acetal ring.
3 . The foam-molded body according to claim 1 , wherein the structural unit derived from other dihydroxy compounds is at least one structural unit selected from the group consisting of cyclohexanedimethanols, tricyclodecanedimethanols and hexanediols.
4 . The foam-molded body according to claim 1 , wherein the ratio of the structural unit derived from a dihydroxy compound represented by formula (1) to the structural units derived from all dihydroxy compounds contained in the polycarbonate copolymer is from 30 to 99 mol %.
5 . The foam-molded body according to claim 1 , which is obtained by foam-molding a resin composition satisfying the following condition (1):
(1) a resin composition where the Henry's constant of carbon dioxide at 200° C. for the resin composition is from 2.5×10 −3 to 4.0×10 −3 g (carbon dioxide)/g (resin composition)·MPa.
6 . The foam-molded body according to claim 1 , wherein the expansion ratio is from 1.1 to 100 times.
7 . The foam-molded body according to claim 5 , which is obtained by foam-molding said resin composition by means of injection foaming involving expansion of a cavity using a foaming agent.
8 . The foam-molded body according to claim 7 , wherein the foaming agent is an inorganic gas.
9 . The foam-molded body according to claim 8 , wherein the inorganic gas is a nitrogen gas or a carbon dioxide gas.
10 . The foam-molded body according to claim 7 , wherein the cavity volume after expansion of the cavity is from more than 1.1 times to 20 times of the cavity volume at the completion of filling with the resin composition.