Conductive material and process

1. A method for making a conductive network of sintered silver in an organic matrix comprising:

(a) depositing an ink consisting essentially of a silver compound, a reducing agent, an organic binder and an optional solvent,

wherein the silver compound is silver oxalate and is present in an amount of about 18% by weight, based on the total weight of the ink;

wherein the reducing agent comprises isopropanolamine in an amount of about 36% by weight, octylamine in an amount of about 9% by weight, and ethanol in an amount of about 36% by weight, each based on the total weight of the conductive ink composition;

wherein the organic binder includes polyvinylpyrrolidone and is present in the amount of about 0.1-30% by weight of the total ink and forms into the organic matrix; on a substrate and applying an external energy source to dry the deposited ink; and

(b) applying an additional external energy source to the dried ink to decompose the silver compound to elemental silver and to sinter the elemental silver into a conductive network in the organic matrix,

wherein the additional external energy source comprises pulsed UV irradiation, and

wherein the organic matrix remains substantially intact following pulse UV irradiation.

2. The method according to claim 1 , in which the silver compound is a combination of silver formate and silver oxalate.

3. The method according to claim 1 in which the reducing agent further comprises methanol, isopropanol, terpineol, t-butanol, ethylene glycol, diethylene glycol, triethylene glycol, ethylene glycol diacetate, formaldehyde, octanal, decanal, dodecanal, or dimethylformamide.

4. The method according to claim 1 in which the external energy source to dry the ink is heat at a temperature or within a temperature range from 25° to 200° C.

5. The method of claim 1 , wherein the reducing agent further includes an oxime, guanidine, carbazone, a further alcohol, polyol, hydrazine, hydrazine, hydrazide, aldehyde, or amide.

6. The method of claim 1 , wherein after applying pulsed UV irradiation, resistance drops by at least eight orders of magnitude.

7. A method for making a conductive network of sintered silver in an organic matrix comprising:

(a) depositing an ink consisting of a silver compound, a reducing agent, an organic binder, and an optional solvent,

wherein the silver compound is silver oxalate;

wherein the silver compound is about 18% by weight of the total conductive ink composition;

wherein the reducing agent comprises isopropanolamine in an amount of about 36% by weight, octylamine in an amount of about 9% by weight, and ethanol in an amount of about 36% by weight, each based on the total weight of the conductive ink composition;

wherein the organic binder includes polyvinylpyrrolidone and is present in the amount of about 0.1-30% by weight of the total ink and forms into the organic matrix on a substrate and applying an external energy source to dry the deposited ink; and

(b) applying an additional external energy source to the dried ink to decompose the silver compound to elemental silver and to sinter the elemental silver into a conductive network in the organic matrix,

wherein the additional external energy source comprises pulsed UV irradiation and

wherein the organic matrix remains substantially intact following pulse UV irradiation.

8. The method of claim 7 , wherein the reducing agent further includes an oxime, guanidine, carbazone, a further alcohol, polyol, hydrazine, hydrazine, hydrazide, aldehyde, or an amide.

9. The method of claim 7 , wherein after applying pulsed UV irradiation, resistance drops by at least eight orders of magnitude.