Cathode active material composition and lithium secondary battery including the same
Provided are a cathode active material composition including an xLi 2 MO 3 .(1−x)LiMeO 2 composite (where 0<x<1, and M and Me represent metal ions and may be the same or different from each other) and a conductive polymer material, and a secondary battery including the cathode active material composition in a cathode. Since the conductivity of the secondary battery of the present invention may be improved, the cathode active material composition may improve life characteristics, output characteristics, and rate capability of the secondary battery.
1. A lithium secondary battery comprising a cathode active material composition comprising:
i) a composite of Chemical Formula 1,
x Li 2 MO 3 .(1− x )LiMeO 2 <Chemical Formula 1>
where 0.1<x<0.5, 0<a, b, c<1 and a+b+c=1;
ii) a conductive polymer material being poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)(PEDOT:PSS);
iii) a binder; and
iv) a conductive agent,
wherein the conductive polymer material is present in an amount of 0.9 wt % to 3 wt % based on a total weight of the cathode active material composition,
wherein the composite of Chemical Formula 1 is present in an amount of 90 wt % to 95 wt % based on a total weight of the cathode active material composition, and
wherein the conductive agent is carbon black.
2. The lithium secondary battery of claim 1 , wherein the binder is one or more selected from the group consisting of polyvinylidene fluoride-hexafluoropropylene copolymer (PVDF-co-HEP), polyvinylidene fluoride, polyacrylonitrile, polymethylmethacrylate, polyvinyl alcohol, carboxymethyl cellulose (CMC), starch, hydroxypropyl cellulose, regenerated cellulose, polyvinylpyrrolidone, tetrafluoroethylene, polyethylene, polypropylene, polyacrylate, an ethylene-propylene-diene monomer (EPDM), a sulfonated EPDM, a styrene-butadiene rubber (SBR), and a fluorine rubber.
3. A lithium secondary battery comprising a cathode including a cathode active material composition, an anode including an anode active material composition, and a separator provided between the cathode and anode,
wherein the cathode active material composition comprises:
i) a composite of Chemical Formula 1,
x Li 2 MO 3 .(1− x )LiMeO 2 <Chemical Formula 1>
where 0.1≦x≦0.5, 0<a, b, c<1 and a+b+c=1;
ii) a conductive polymer material being poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)(PEDOT:PSS);
iii) a binder being one or more selected from the group consisting of a polyvinylidene fluoride-hexafluoropropylene copolymer (PVDF-co-HEP), polyvinylidene fluoride, polyacrylonitrile, polymethylmethacrylate, polyvinyl alcohol, carboxymethyl cellulose (CMC), starch, hydroxypropyl cellulose, regenerated cellulose, polyvinylpyrrolidone, tetrafluoroethylene, polyethylene, polypropylene, polyacrylate, an ethylene-propylene-diene monomer (EPDM), a sulfonated EPDM, a styrene-butadiene rubber (SBR), and a fluorine rubber; and
iv) a conductive agent being carbon black,
wherein the composite of Chemical Formula 1 is present in an amount of 90 wt % to 95 wt % based on a total weight of the cathode active material composition, and
the conductive polymer material is present in an amount of 0.9 wt % to 3 wt % based on a total weight of the cathode active material composition.
4. The lithium secondary battery of claim 1 , wherein the lithium secondary battery has a charge voltage of 4.35 V or more.