Water-based compositions that resist dirt pick-up
View Patent ↗Water-based compositions containing a low VOC coalescent, a latex or water-dispersible polymer, and a water-insoluble ultraviolet absorber.
1. A method of preparing a water-based composition, the method comprising:
providing an aqueous polymer comprising a latex or water-dispersible polymer in water;
providing an additive package comprising at least one of a pigment, a thickener, a mildewcide, a biocide, a defoamer, a surfactant, a dispersant, a filler, and combinations thereof;
providing one or more water-insoluble ultraviolet absorbers capable of absorbing UV radiation within a range of 240-400 nm;
providing one or more low VOC coalescents having a volatile organic content of 30% or less;
dissolving the one or more water-insoluble ultraviolet absorbers in the one or more low VOC coalescents to form a UV-absorber-coalescent solution;
mixing the aqueous polymer with the additive package; and
before and/or after mixing the aqueous polymer with the additive package, the UV-absorber-coalescent solution is mixed with the aqueous polymer, the additive package, or both to form a water-based coating.
2. The method of claim 1 wherein mixing the UV-absorber-coalescent solution with the aqueous polymer, additive package, or both occurs before mixing the aqueous polymer with the additive package.
3. The method of claim 1 wherein the method comprises mixing the UV-absorber-coalescent solution with the aqueous polymer, and subsequently mixing the aqueous polymer having the UV-absorber-coalescent therein with the additive package.
4. The method of claim 1 wherein the water-based composition comprises an amount of the one or more coalescents effective to facilitate coalescence of the aqueous polymer.
5. The method of claim 1 wherein the water-based composition comprises an amount of the one or more water-insoluble ultraviolet absorbers effective to improve dirt pick-up resistance of the water-based composition by at least 10%, relative to the same water-based composition without the ultraviolet absorber, based on a change in ΔE values.
6. The method of claim 5 wherein the water-based composition comprises an amount of the one or more water-insoluble ultraviolet absorbers effective to improve dirt pick-up resistance by at least 50%, relative to the same water-based composition without the ultraviolet absorber, based on a change in ΔE values.
7. The method of claim 1 wherein the water-based composition comprises at least 0.1 wt-% of the one or more ultraviolet absorbers, based on the weight of the polymer solids.
8. The method of claim 1 wherein the water-based composition comprises up to 5.0 wt-% of the one or more ultraviolet absorbers, based on the weight of the polymer solids.
9. The method of claim 1 wherein the one or more water-insoluble ultraviolet absorbers are capable of absorbing UV radiation within a range of 315-375 nm.
10. The method of claim 1 wherein the one or more water-insoluble ultraviolet absorbers is selected from the group of benzophenone, polymeric benzophenone, phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide, ethyl-2,4,6-trimethylbenzoylphenylphosphinate, 2,4,6-trimethylbenzophenone, 4-methylbenzophenone, 2,2-dimethoxy-1,2-diphenylethanone, 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-propanone, isopropylthioxanthone, methyl-o-benzoyl-benzoate, methylbenzoylformate, benzoin ethyl ether, 4′-ethoxyacetophenone, and combinations thereof.
11. The method of claim 10 wherein the one or more water-insoluble photoinitators is benzophenone.
12. The method of claim 1 wherein the water-based composition is a paint, a sealer, a caulk, or a sealant.
13. The method of claim 1 wherein the aqueous polymer comprises a latex polymer having at least one Tg within a range of −20° C. to 70° C.
14. The method of claim 13 wherein the latex polymer comprises the polymerization product of ethylenically unsaturated monomers selected from the group of alkyl acrylates, alkoxy acrylates, alkyl methacrylates, alkoxy methacrylates, vinyl esters of saturated carboxylic acids, monoolefins, conjugated dienes, styrene, and vinyl chloride.
15. The method of claim 14 wherein the latex polymer comprises a surfactant and polymer particles comprising a homopolymer or copolymer including at least one of an acrylate or a methacrylate.
16. The method of claim 1 wherein the one or more coalescents are present in an amount effective to facilitate the formation of a polymer film of a latex polymer at a temperature of less than 25° C.
17. The method of claim 1 wherein the one or more coalescents has a volatile organic content of 15% or less.
18. The method of claim 1 wherein at least one coalescent is selected from the group of bis(2-ethylhexyl) maleate, bis(2-ethylhexyl) adipate, bis(2-ethylhexyl) azelate, isodecyl benzoate, tri(ethylene glycol)bis(2-ethylhexanoate), tetra(ethylene glycol)bis(2-ethylhexanoate), tributyl citrate, octyl benzoate, di(ethylene glycol)dibenzoate, octadecenoic acid methyl ester, and oleic acid, monoester of propylene glycol.
19. A method of preparing a water-based composition, the method comprising:
providing an aqueous polymer comprising a latex polymer in water;
providing an additive package comprising at least one of a pigment, a thickener, a mildewcide, a biocide, a defoamer, a surfactant, a dispersant, a filler, and combinations thereof;
providing one or more water-insoluble ultraviolet absorbers capable of absorbing UV radiation within a range of 240-400 nm;
providing one or more low VOC coalescents having a volatile organic content of 30% or less;
dissolving the one or more water-insoluble ultraviolet absorbers in the one or more low VOC coalescents to form a UV-absorber-coalescent solution;
mixing the UV-absorber-coalescent solution with the aqueous polymer; and
subsequently mixing the aqueous polymer having the UV-absorber-coalescent therein with the additive package.
20. A water-based composition prepared by a method of claim 1 or claim 19 .